Flow velocity distribution measuring method and particle size measuring method

Patent metadata

Field	Value
Publication number	US-11280652-B2
Application number	US-201716466696-A
Country	US
Kind code	B2
Filing date	Dec 5, 2017
Priority date	Dec 6, 2016
Publication date	Mar 22, 2022
Grant date	Mar 22, 2022

Abstract

A measuring method enabling simple and accurate measurement of a flow velocity distribution in a flow field inside a flow passage of an optical cell and a particle size-measuring method using the measuring method are provided. Providing a tracer particle of a smaller size than wavelength λ of laser light into the flow passage and capturing a bright spot attributed to light scattering from tracer particles by camera, and obtaining the flow velocity distribution by the analysis unit by obtaining an amount of movement of each tracer particle from movement of the bright spot and correcting a Brownian motion component from a correlation between an average value of variations of the amount of movement and Brownian motion are performed.

First claim

The invention claimed is:

1. A particle size-measuring method for a measurement targeted Brownian particles in a flow field inside a flow passage of an optical cell, comprising:
in a device including a laser light irradiation unit irradiating laser light at a wavelength λ into the flow passage, a camera capturing an inside of the flow passage to which the laser light is irradiated, and an analysis unit obtaining a flow velocity distribution in the flow field from at least a plurality of images captured in a light exposure time τ at each time interval Δt and obtaining particle size of the measurement target particle,
providing a tracer particle of a smaller size than the wavelength λ of the laser light into the flow passage, capturing a bright spot attributed to the light scattering from tracer particles by the camera, and obtaining the flow velocity distribution in the analysis unit by obtaining an amount of movement of each tracer particle from movement of the bright spot and correcting a Brownian motion component from a correlation between an average value of variations of the amount of movement and Brownian motion; and
providing the measurement target particle into the flow passage, capturing the measurement target particle by the camera, and obtaining the particle size of the measurement target particle in the analysis unit by correcting an average value MSD of a square of distance of displacement of the measurement target particle using the square of the flow velocity, wherein a particle size of the tracer particle is from 10 nm to 100 nm.

2. The particle size-measuring method according to claim 1 ,
wherein the tracer particle and the measurement target particle are the same and are captured in a single step.

3. The particle size-measuring method according to claim 1 ,
wherein the particle size is calculated from a relationship in which an average value of a square of the corrected displacement of the measurement target particle is proportional to k B t/3πηd, where d is the particle size of the measurement target particle, k B is a Boltzmann constant, T is an absolute temperature, and η is a viscosity coefficient in a dispersion medium of the flow field.

4. The particle size-measuring method according to claim 3 ,
wherein a light exposure time for capturing the measurement target particle is changed based on a measured particle size range of the measurement target particle.

5. The particle size-measuring method according to claim 1 , wherein

MSD
=

4
⁢

⁢

k
B

⁢
T

3
⁢

⁢
π
⁢

⁢
η
⁢

⁢
d

⁢

(

Δ
⁢

⁢
t

-

τ
3

)

+

2
⁢

⁢

ɛ
2

ε represents uncertainty of coordinate positions,
τ represents light exposure time,
Δt represents capturing interval,
d represents particle size,
k B is Boltzmann's constant,
T is absolute temperature, and
η represents a viscosity coefficient of the flow field in the dispersion medium, and wherein MSD is corrected by removing K 2 v 2 τ 2 , which corresponds to 2ε 2 .

Assignees

• Aist

Inventors

• Kato Haruhisa
• Matsuura Yusuke
• Nakamura Ayako

Classifications

• G01N15/02

  Investigating particle size or size distribution (by measuring osmotic pressure G01N7/10; investigating sedimentation of particle suspensions G01N15/04; investigating individual particles G01N15/10) · CPC title

• G01P5/20 Primary

  using particles entrained by a fluid stream (G01P5/22 takes precedence) · CPC title

• G01F1/7086 Primary

  using optical detecting arrangements · CPC title

• G01F1/74

  Devices for measuring flow of a fluid or flow of a fluent solid material in suspension in another fluid · CPC title

• G01F1/712

  using auto-correlation or cross-correlation detection means · CPC title