Polymerization using a spiral heat exchanger

Patent metadata

Field	Value
Publication number	US-11279775-B2
Application number	US-201615759002-A
Country	US
Kind code	B2
Filing date	Aug 19, 2016
Priority date	Sep 29, 2015
Publication date	Mar 22, 2022
Grant date	Mar 22, 2022

Abstract

This invention relates to a polymerization process for forming polymer comprising: contacting (typically in a solution or slurry phase), a monomer and a catalyst system in a reaction zone comprising at least one spiral heat exchanger and recovering polymer, wherein the monomer, the catalyst system and the polymer flow through the at least one spiral heat exchanger in a cross-flow direction relative to spirals of the at least one spiral heat exchanger.

First claim

What is claimed is:

1. A polymerization process for forming polymer comprising:
contacting a monomer and a catalyst system in a reaction zone, the reaction zone is disposed within at least one spiral heat exchanger; and
recovering polymer from the spiral heat exchanger,
wherein the monomer, the catalyst system and polymer flow through the at least one spiral heat exchanger, in fluid contact with spirals of the at least one spiral heat exchanger, in a cross-flow direction relative to the spirals of the at least one spiral heat exchanger, wherein the spirals of the spiral heat exchanger are formed by at least one spiral sheet wound to form spirals arranged radially around an axis of the spiral heat exchanger.

2. The polymerization process of claim 1 , wherein the catalyst system comprises a catalyst compound and an activator.

3. The polymerization process of claim 2 , wherein the catalyst compound is elected from the group consisting of a pyridyldiamido compound and a metallocene compound.

4. The polymerization process of claim 1 , further comprising contacting a scavenger with the monomer and the catalyst system in the reaction zone.

5. The polymerization process of claim 4 , wherein the scavenger is present at a molar ratio of scavenger metal to catalyst transition metal of less than 10:1.

6. The polymerization process of claim 1 , wherein no scavenger is used in the process.

7. The polymerization process of claim 4 , wherein the scavenger is water.

8. The polymerization process of claim 1 , wherein polymer is produced at a rate of at least about 600 grams per hour per liter of reactor volume.

9. The polymerization process of claim 1 , wherein the polymerization process is conducted at a temperature from about 50° C. to about 220° C.

10. The polymerization process of claim 1 , wherein the at least one spiral heat exchanger removes heat at a rate of about 7450 W/·cubic meters·° C.

11. A polymerization process for forming polymer comprising:
contacting a monomer and a catalyst system in a reaction zone comprising at least one spiral heat exchanger and recovering polymer,
wherein the monomer, the catalyst system and polymer flow through the at least one spiral heat exchanger in a cross-flow direction relative to spirals of the at least one spiral heat exchanger,
wherein the spirals of the spiral heat exchanger are formed by at least one spiral sheet wound to form spirals arranged radially around an axis of the spiral heat exchanger; and
recycling at least a portion of the monomer, the catalyst system and polymer exiting the at least one spiral heat exchanger back through a spiral heat exchanger, which may be the same or different spiral heat exchanger.

12. The polymerization process of claim 11 , wherein the process is a solution phase process.

13. The polymerization process of claim 11 , wherein polymer is produced with a recycle ratio of at least about 5, wherein the recycle ratio is the ratio between a flow rate of the recycled portion just prior to entry into the same or different spiral heat exchanger divided by a flow rate of fresh feed to the spiral heat exchanger.

14. The polymerization process of claim 11 , wherein the monomer comprises C2 to C40 olefin selected from at least one of the group consisting of ethylene, propylene, butene, pentene, hexene, heptene, octene, nonene, decene, undecene, dodecene, and mixtures thereof.

15. The polymerization process of claim 11 , wherein polymer is an ethylene polymer or a propylene polymer.

16. The polymerization process of claim 15 , wherein polymer further comprises C2 to C20 comonomer selected from the group consisting of ethylene, propylene, butene, pentene, hexene, heptene, octene, nonene, decene, undecene, dodecene, and a mixture thereof.

17. A polymerization system, comprising:
a first reactor comprising a first reaction zone, the first reaction zone is disposed within a first spiral heat exchanger, wherein the first spiral heat exchanger comprises at least one spiral sheet spiraling radially around an axis of the spiral heat exchanger, wherein the first spiral heat exchanger comprises at least one channel formed in between adjacent spiralings of the at least one spiral sheet, and wherein the first spiral heat exchanger is oriented to allow a process solution to flow through the first spiral heat exchanger, in fluid contact with the spirals of the first spiral heat exchanger, in a cross-flow direction relative to the spirals of the first spiral heat exchanger, wherein the process solution comprises at least one monomer, catalyst system and polymer.

18. The polymerization system of claim 17 , further comprising a second reactor comprising a second reaction zone, the second reaction zone is disposed within a second spiral heat exchanger oriented to allow the process solution to flow through the second spiral heat exchanger, in fluid contact with the spirals of the second spiral heat exchanger, in a cross-flow direction relative to the spirals of the second spiral heat exchanger.

19. The polymerization system of claim 17 , wherein the first reaction zone is further disposed within a second spiral heat exchanger connected in series to the first spiral heat exchanger, wherein the second spiral heat exchanger is oriented to allow the process solution to flow through the second spiral heat exchanger, in fluid contact with the spirals of the second spiral heat exchanger, in a cross-flow direction relative to the spirals of the second spiral heat exchanger.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Reimers Jay L
• Lawson Kevin W
• Jiang Peijun
• Kiss Gabor

Classifications

• B01J8/1836

  Heating and cooling the reactor (B01J8/42 takes precedence) · CPC title

• F25B13/00

  Compression machines, plants or systems, with reversible cycle (defrosting cycles F25B47/02) · CPC title

• C08F4/6428

  with an aluminoxane, i.e. a compound containing an Al-O-Al- group · CPC title

• B01J8/0015

  Feeding of the particles in the reactor; Evacuation of the particles out of the reactor · CPC title

• C08F2/01 Primary

  characterised by special features of the polymerisation apparatus used · CPC title