Xylylene diisocyanate composition, polymerizable composition, resin, molded article, optical element, and lens
US-2024263008-A1 · Aug 8, 2024 · US
US11279673B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11279673-B2 |
| Application number | US-201716317408-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 6, 2017 |
| Priority date | Jul 14, 2016 |
| Publication date | Mar 22, 2022 |
| Grant date | Mar 22, 2022 |
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An embodiment relates to an aromatic polythiol compound for optical materials, and the aromatic polythiol compound according to the embodiment contains a phenyl group and a large number of sulfur atoms in its polythiol structure so that a polymerizable composition and an optical material obtained therefrom have excellent optical properties such as high refractive index and low specific gravity, as well as excellent mechanical properties such as low cure shrinkage; thus, they can be advantageously used for producing various plastic optical lenses such as eyeglass lenses and camera lenses.
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The invention claimed is: 1. An aromatic polythiol compound prepared by reacting a divinylbenzene compound represented by Formula 1 below and a bi- or higher-functional aliphatic polythiol, wherein the bi- or higher-functional aliphatic polythiol is at least one selected from the group consisting of ethoxylated trimethylolpropane tri(3-mercaptopropionate), tris[2-(3-mercaptopropionyloxy)ethyl]isocyanurate, dipentaerythritol hexa(3-mercaptopropionate), and 5,9-dimercaptomethyl-1,13-dimercapto-3,7,11-trithiatridecane, and wherein the molar ratio of the divinylbenzene compound to the bi- or higher-functional aliphatic polythiol is 1:2 to 1:10: 2. An aromatic polythiol compound prepared by reacting a divinylbenzene compound represented by Formula 1 below and a bi- or higher-functional aliphatic polythiol, wherein the aromatic polythiol compound has a number average molecular weight of 500 to 3,000, and wherein the bi- or higher-functional aliphatic polythiol is at least one selected from the group consisting of ethoxylated trimethylolpropane tri(3-mercaptopropionate), tris[2-(3-mercaptopropionyloxy)ethyl]isocyanurate, dipentaerythritol hexa(3-mercaptopropionate), and 5,9-dimercaptomethyl-1,13-dimercapto-3,7,11-trithiatridecane:
containing at least two isocyanate or isothiocyanate groups linked to the aromatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate groups, e.g. xylylene diisocyanate or homologues substituted on the aromatic ring · CPC title
being toluene diisocyanate including isomer mixtures · CPC title
containing at least two isocyanate or isothiocyanate groups linked to the cycloaliphatic ring by means of an aliphatic group · CPC title
containing mercapto groups · CPC title
organometallic compounds containing tin-carbon bonds · CPC title
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