Process for separating an organic isocyanate

Patent metadata

Field	Value
Publication number	US-11279670-B2
Application number	US-202117146628-A
Country	US
Kind code	B2
Filing date	Jan 12, 2021
Priority date	Apr 3, 2017
Publication date	Mar 22, 2022
Grant date	Mar 22, 2022

Abstract

Provided is a process for separating an organic isocyanate prepared by reacting an organic amine with a stoichiometric excess of phosgene in the gas phase from the gaseous crude product obtained in the reaction, the process comprising the steps of (i) at least partially condensing the crude product stream containing at least the isocyanate, hydrogen chloride and unconverted phosgene by contacting with at least one liquid stream containing at least one quench liquid in a first separation apparatus to obtain a liquid stream containing at least some of the quench liquid and some of the isocyanate and a gas stream containing at least hydrogen chloride, evaporated quench liquid and phosgene, (ii) discharging the liquid stream obtained in step (i) via a first liquid outlet and of the gas stream obtained in (i) via a first gas conduit and (iii) at least partially condensing and/or absorbing the gas stream discharged in step (ii) through the first gas conduit, wherein that the at least partial condensation and/or absorption is effected in step (iii) by direct introduction of at least one cooling fluid, wherein the cooling fluid is introduced directly into the first gas conduit via at least one addition unit assigned to the first gas conduit.

First claim

The invention claimed is:

1. A process for separating an organic isocyanate prepared by reacting an organic amine with a stoichiometric excess of phosgene in the gas phase from the gaseous crude product obtained in the reaction, the process comprising the steps of
(i) at least partially condensing the crude product stream containing at least the isocyanate, hydrogen chloride and unconverted phosgene by contacting with at least one liquid stream containing at least one quench liquid in a first separation apparatus to obtain
a liquid stream containing at least some of the quench liquid and some of the isocyanate and
a gas stream containing at least hydrogen chloride, evaporated quench liquid and phosgene,

(ii) discharging the liquid stream obtained in step (i) via a first liquid outlet and of the gas stream obtained in (i) via a first gas conduit and
(iii) at least partially condensing and/or absorbing the gas stream discharged in step (ii) through the first gas conduit,

wherein at least partial condensation and/or absorption is effected in step (iii) by direct introduction of at least one cooling fluid, wherein the cooling fluid is introduced directly into the first gas conduit via at least one addition unit assigned to the first gas conduit.

2. The process as claimed in claim 1 , wherein the weight ratio of the cooling fluid introduced to the gas stream conducted through the first gas conduit is 1:100 to 10:1.

3. The process as claimed in claim 1 , wherein the cooling fluid is selected to correspond to the solvent used as quench liquid in step (i).

4. The process as claimed claim 1 , further including the steps of
(iv) separating the gas stream from the first gas conduit in a second separation unit into a liquid stream and a gas stream and
(v) recycling the liquid stream obtained in step (iv) as quench liquid via a second liquid conduit into the first separation unit.

5. The process as claimed in claim 1 , wherein the cooling fluid is selected from the group consisting of chlorobenzene, o-di chlorobenzene, p-dichlorobenzene, trichlorobenzenes, the corresponding chlorotoluenes or chloroxylenes, chloroethylbenzene, monochlorodiphenyl, α- or β-naphthyl chloride, ethyl benzoate, dialkyl phthalates, diisodiethyl phthalate, toluene and/or xylene, preferably chlorobenzene, o-dichlorobenzene and p.

6. The process as claimed in claim 1 , wherein the addition unit establishes a lowering of the temperature in the gas stream by 0.5 to 50 K.

Assignees

• Covestro Deutschland Ag

Inventors

• Kobylka Manfred
• Merkel Michael
• Duerig Dominik
• Seidel Bernhard

Classifications

• B01D5/0027

  by direct contact between vapours or gases and the cooling medium · CPC title

• C07C263/20 Primary

  Separation; Purification · CPC title

• B01D53/1487

  Removing organic compounds · CPC title

• B01D5/0087

  Recirculating of the cooling medium · CPC title

• B01D53/18

  Absorbing units; Liquid distributors therefor (B01D3/16, B01D3/26, B01D3/30 take precedence; packing elements B01J19/30, B01J19/32) · CPC title