Electrodialysis cells based on the use of redox mediators

Patent metadata

Field	Value
Publication number	US-11279637-B2
Application number	US-201816182696-A
Country	US
Kind code	B2
Filing date	Nov 7, 2018
Priority date	Nov 7, 2018
Publication date	Mar 22, 2022
Grant date	Mar 22, 2022

Abstract

Electrodialysis cell systems for water deionization is provided. Also provided are methods for using the electrodialysis cell systems. The cells use the forward and reverse reactions of a redox mediator and the combined operations of a deionization cell and an ion-accumulation cell to enable sustainable deionization with a significantly decreased operating voltage, relative to conventional deionization cells. The cells have applications in seawater desalination, water purification, and wastewater treatment.

First claim

What is claimed is:

1. A tandem deionization system comprising:
a deionization cell comprising:
an anolyte in an anode compartment, the anolyte comprising a reduced species and an oxidized species of a dissolved redox couple;
a catholyte in a cathode compartment, the catholyte comprising the reduced species and the oxidized species of the dissolved redox couple;
only a single deionization compartment comprising a solution comprising cations and anions between the anode compartment and the cathode compartment, wherein the deionization compartment is bounded by an anion exchange membrane on an anode side of the deionization compartment and by a cation exchange membrane on a cathode side of the deionization compartment;
an anode in electrical communication with the anolyte in the anode compartment; and
a cathode in electrical communication with the catholyte in the cathode compartment, wherein the deionization cell has no ion-accumulation compartment; and

an ion-accumulation cell comprising:
an anolyte in an anode compartment, the anolyte comprising the reduced species and the oxidized species of the dissolved redox couple;
a catholyte in a cathode compartment, the catholyte comprising the reduced species and the oxidized species of the dissolved redox couple;
only a single ion-accumulation compartment comprising a solution between the anode compartment and the cathode compartment, wherein the ion-accumulation compartment is bounded by a cation exchange membrane on an anode side of the ion-accumulation compartment and by an anion exchange membrane on a cathode side of the ion-accumulation compartment;
an anode in electrical communication with the anolyte in the anode compartment; and
a cathode in electrical communication with the catholyte in the cathode compartment, wherein the ion-accumulation cell has no deionization compartment;

one or more conduits connecting the anode compartment of the deionization cell and the cathode compartment of the ion-accumulation cell, wherein the one or more conduits allow the anolyte from the deionization cell to circulate into the cathode compartment of the ion-accumulation cell and the catholyte from the ion-accumulation cell to circulate into the anode compartment of the deionization cell; and
one or more conduits connecting the cathode compartment of the deionization cell to the anode compartment of the ion-accumulation cell, wherein the one or more conduits allow the catholyte from the deionization cell to circulate into the anode compartment of the ion-accumulation cell and the anolyte from the ion-accumulation cell to circulate into the cathode compartment of the deionization cell.

2. The system of claim 1 , wherein the reduced species is TEMPOL and the oxidized species is TEMPOL + .

3. The system of claim 1 , wherein the anode of the deionization cell and the anode of the ion-accumulation cell are carbon-containing electrodes.

4. The system of claim 1 , wherein the solution in the deionization compartment comprises industrial, commercial, or residential wastewater.

5. The system of claim 1 , wherein at least one of the anode of the deionization cell and the anode of the ion-accumulation cell is a photoanode.

6. The system of claim 5 , wherein at least one of the photoanodes comprises n-type BiVO 4 .

7. The system of claim 1 , wherein at least one of the cathode of the deionization cell and the cathode of the ion-accumulation cell is a photocathode.

8. The system of claim 1 , wherein the anions in the deionization cell comprise chloride anions.

9. The system of claim 1 , wherein the solution in the deionization compartment comprises water from a natural body of water.

10. A method for deionizing an ion-containing solution using a tandem deionization system comprising:
a deionization cell comprising:
an anolyte in an anode compartment, the anolyte comprising a reduced species and an oxidized species of a dissolved redox couple;
a catholyte in a cathode compartment, the catholyte comprising the reduced species and the oxidized species of the dissolved redox couple;
only a single deionization compartment comprising a solution comprising cations and anions between the anode compartment and the cathode compartment, wherein the deionization compartment is bounded by an anion exchange membrane on an anode side of the deionization compartment and by a cation exchange membrane on a cathode side of the deionization compartment;
an anode in electrical communication with the anolyte in the anode compartment; and
a cathode in electrical communication with the catholyte in the cathode compartment, wherein the deionization cell has no ion-accumulation compartment; and

an ion-accumulation cell comprising:
an anolyte in an anode compartment, the anolyte comprising the reduced species and the oxidized species of the dissolved redox couple;
a catholyte in a cathode compartment, the catholyte comprising the reduced species and the oxidized species of the dissolved redox couple;
only a single ion-accumulation compartment comprising a solution between the anode compartment and the cathode compartment, wherein the ion-accumulation compartment is bounded by a cation exchange membrane on an anode side of the ion-accumulation compartment and by an anion exchange membrane on a cathode side of the ion-accumulation compartment;
an anode in electrical communication with the anolyte in the anode compartment; and
a cathode in electrical communication with the catholyte in the cathode compartment, wherein the ion-accumulation cell has no deionization compartment;

one or more conduits connecting the anode compartment of the deionization cell and the cathode compartment of the ion-accumulation cell, wherein the one or more conduits allow the anolyte from the deionization cell to circulate into the cathode compartment of the ion-accumulation cell and the catholyte from the ion-accumulation cell to circulate into the anode compartment of the deionization cell; and
one or more conduits connecting the cathode compartment of the deionization cell to the anode compartment of the ion-accumulation cell, wherein the one or more conduits allow the catholyte from the deionization cell to circulate into the anode compartment of the ion-accumulation cell and the anolyte from the ion-accumulation cell to circulate into the cathode compartment of the deionization cell, the method comprising:
oxidizing the reduced species in the anode compartment of the deionization cell and reducing the oxidized species in the cathode compartment of the deionization cell, causing anions from the solution in the deionization compartment to move from the deionization compartment into the anode compartment of the deionization cell and cations from the solution in the deionization compartment to move from the deionization compartment into the cathode compartment of the deionization cell, thereby deionizing the solution in the deionization compartment;
oxidizing the reduced species in the anode compartment of the ion-accumulation cell and reducing the oxidized species in the cathode compartment of the ion-accumulation cell, causing anions from the anode compartment of the ion-accumulation cell move into the ion-accumulation compartment and cations from the cathode compartment of the ion-accumulation cell to move into the ion-accumulation compartment, thereby ionizing the solution in the ion-accumulation compartment;
circulating the anolyte from the deionization cell into the cathode compartment of the ion-accumulation cell and the catholyte from the ion-accumulation cell into the anode compartment of the deionization cell during the deionization of the solution; and
circulating the catholyte from the deionization cel

Assignees

• Wisconsin Alumni Res Found

Inventors

• Choi Kyoung-Shin
• Nam Dohwan
• Lee Dong Ki

Classifications

• B01D61/422

  Electrodialysis · CPC title

• B01D61/46

  Apparatus therefor · CPC title

• B01D2313/345

  Electrodes · CPC title

• C02F2103/08

  Seawater, e.g. for desalination · CPC title

• C02F2001/46133

  characterised by the material · CPC title