Production method for forsterite fine particles

Patent metadata

Field	Value
Publication number	US-11279624-B2
Application number	US-201815962381-A
Country	US
Kind code	B2
Filing date	Apr 25, 2018
Priority date	Mar 25, 2014
Publication date	Mar 22, 2022
Grant date	Mar 22, 2022

Abstract

A method for producing forsterite microparticles having a primary particle size of 1, to 50 nm, as determined through electron microscopy. The method includes spray-drying, in an atmosphere of 50° C. or higher and lower than 300° C., a solution containing a water-soluble magnesium salt and colloidal silica at a mole ratio of magnesium atoms to silicon atoms (Mg/Si) of 2; and subsequently, firing the spray-dried product in air at 800 to 1,000° C.

First claim

The invention claimed is:

1. A method for producing forsterite microparticles having a primary particle size of 1 to 50 nm, as determined through electron microscopy, the method comprising:
dissolving a water-insoluble magnesium salt in an organic acid and acidic colloidal silica dispersion having a primary particle size of 2 to 100 nm at a mole ratio of magnesium atoms to silicon atoms (Mg/Si) of 2, so as to form an aqueous solution containing the water-soluble magnesium salt and colloidal silica in a uniformly mixed state;
spray-drying, in an atmosphere of 50° C. or higher and lower than 300° C., the aqueous solution maintaining the uniformly mixed state; and
subsequently, firing the spray-dried product in air at 800 to 1,000° C.

2. The method according to claim 1 , wherein the magnesium salt solution includes at least one species selected from the group consisting of magnesium citrate, magnesium glycolate, magnesium malate, magnesium tartrate, magnesium lactate, magnesium malonate, magnesium succinate, and magnesium acetate.

3. The method according to claim 1 , wherein the primary particle size of the forsterite microparticles is 30 to 50 nm, as determined through electron microscopy.

4. The method according to claim 1 , wherein the primary particle size of the colloidal silica is 2 to 5 nm, as determined through electron microscopy.

5. The method according to claim 3 , wherein the primary particle size of the colloidal silica is 2 to 5 nm, as determined through electron microscopy.

Assignees

• Nissan Chemical Ind Ltd

Inventors

• Isaji Tadayuki
• Ogihara Takashi
• Kodera Takayuki

Classifications

• C04B35/20 Primary

  rich in magnesium oxide {, e.g. forsterite (C04B35/195 takes precedence)} · CPC title

• C09C1/30

  Silicic acid · CPC title

• C09C1/028

  Compounds containing only magnesium as metal · CPC title

• C01P2004/62

  Submicrometer sized, i.e. from 0.1-1 micrometer · CPC title

• C01P2004/04

  obtained by TEM, STEM, STM or AFM · CPC title