Method of preparing a biodegradable film

Patent metadata

Field	Value
Publication number	US-11279063-B2
Application number	US-201916728080-A
Country	US
Kind code	B2
Filing date	Dec 27, 2019
Priority date	Jan 2, 2019
Publication date	Mar 22, 2022
Grant date	Mar 22, 2022

Abstract

Provided is a method of preparing a biodegradable film, which comprises the steps of coating a soluble supporting solution on a substrate, coating a prepolymer solution, pre-drying, crosslinking, and separating. With the technical means, the method can separate the biodegradable film from the substrate smoothly, thereby ensuring the film integrity of the produced biodegradable film.

First claim

What is claimed is:

1. A method of preparing a biodegradable film comprising:
coating a soluble supporting solution on a substrate to form a soluble supporting layer on the substrate, wherein a material of the soluble supporting solution includes glucose, fructose, galactose, saccharose, maltose, lactose, corn syrup, methyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, carboxymethyl hydroxyethylcellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, starch, chitosan, chitin, polyvinyl alcohol or their combinations;
coating a prepolymer solution on the soluble supporting layer to obtain a cross-linkable laminate, the cross-linkable laminate comprising the substrate, the soluble supporting layer and the prepolymer solution in a bottom-up sequence;
pre-drying the cross-linkable laminate to dry the prepolymer solution into a prepolymer layer, so as to obtain a dried cross-linkable laminate, the prepolymer layer containing a prepolymer;
subjecting the prepolymer in the dried cross-linkable laminate to a crosslinking reaction to obtain a cross-linked laminate, wherein the cross-linked laminate contains the substrate, the soluble supporting layer and the biodegradable film, and the biodegradable film is formed by the crosslinking reaction of the prepolymer; and
releasing the biodegradable film from the substrate of the cross-linked laminate by water washing or peeling.

2. The method as claimed in claim 1 , wherein the crosslinking reaction includes photo crosslinking reaction, thermal crosslinking or their combinations.

3. The method as claimed in claim 1 , wherein the crosslinking reaction is performed under an anoxic condition to obtain the cross-linked laminate, and a vacuum degree of the anoxic condition is lower than 1 torr.

4. The method as claimed in claim 1 , wherein the prepolymer is prepared by a mixture containing a polyhydric alcohol and a poly acid, and the polyhydric alcohol is selected from the group consisting of glycerol, ethylene glycol, propylene glycol, butanediol, pentanediol, hexanediol, cyclopentanediol, cyclohexanediol and their combinations, and the poly acid is selected from the group consisting of oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, butenedioic acid, glutaconic acid, citric acid and their combinations.

5. The method as claimed in claim 1 , wherein a temperature for pre-drying the cross-linkable laminate is from 25° C. to 90° C.

6. The method as claimed in claim 1 , wherein a residual solvent contained in the prepolymer layer is less than 40%.

7. The method as claimed in claim 1 , wherein the water washing step includes immersing the cross-linked laminate in water at a temperature between 10° C. and 90° C., so as to release the biodegradable film from the substrate of the cross-linked laminate.

8. The method as claimed in claim 2 , wherein the water washing step includes immersing the cross-linked laminate in water at a temperature between 10° C. and 90° C., so as to release the biodegradable film from the substrate of the cross-linked laminate.

9. The method as claimed in claim 3 , wherein the water washing step includes immersing the cross-linked laminate in water at a temperature between 10° C. and 90° C., so as to release the biodegradable film from the substrate of the cross-linked laminate.

10. The method as claimed in claim 1 , wherein the biodegradable film has Young's modulus ranging from 1 MPa to 2800 MPa, an ultimate tensile strength ranging from 0.25 MPa to 80 MPa, and an elongation at break from 1.5% to 110%.

11. The method as claimed in claim 2 , wherein the biodegradable film has Young's modulus ranging from 1 MPa to 2800 MPa, an ultimate tensile strength ranging from 0.25 MPa to 80 MPa, and an elongation at break from 1.5% to 110%.

12. The method as claimed in claim 3 , wherein the biodegradable film has Young's modulus ranging from 1 MPa to 2800 MPa, an ultimate tensile strength ranging from 0.25 MPa to 80 MPa, and an elongation at break from 1.5% to 110%.

13. The method as claimed in claim 7 , wherein the biodegradable film has Young's modulus ranging from 1 MPa to 2800 MPa, an ultimate tensile strength ranging from 0.25 MPa to 80 MPa, and an elongation at break from 1.5% to 110%.

Assignees

• Univ Nat Tsing Hua

Inventors

• Tsou Erh-Yeh
• Liu Ta-Jo
• Wang Jane

Classifications

• B29C41/42

  Removing articles from moulds, cores or other substrates {(B29C33/444 and B29C37/0017 take precedence)} · CPC title

• B29C41/20

  incorporating preformed parts or layers, e.g. moulding inserts or for coating articles · CPC title

• B29K2801/08

  Cellulose derivatives · CPC title

• B29K2995/006

  Bio-degradable, e.g. bioabsorbable, bioresorbable or bioerodible · CPC title

• B29C41/50

  Shaping under special conditions, e.g. vacuum · CPC title