Photocatalyst, photocatalyst carrier, method for producing photocatalyst, and method for producing photocatalyst carrier

Patent metadata

Field	Value
Publication number	US-11278877-B2
Application number	US-201816629186-A
Country	US
Kind code	B2
Filing date	May 28, 2018
Priority date	Aug 22, 2017
Publication date	Mar 22, 2022
Grant date	Mar 22, 2022

Abstract

In a photocatalyst and a photocatalyst carrier, tungsten oxide microcrystals that have a crystal grain size of 10 nm or less and oxidizes a gaseous chemical substance and titanium oxide microcrystals that have a crystal grain size of 10 nm or less and oxidizes the gaseous chemical substance are irregularly arranged to form a solid.

First claim

The invention claimed is:

1. A photocatalyst comprising plural tungsten oxide microcrystals and plural anatase-type titanium oxide microcrystals and being capable of causing a photocatalytic reaction by photoirradiation, wherein
the plural tungsten oxide microcrystals are tungsten oxide microcrystals each have a crystal grain size of 10 nm or less and being able to oxidize a gaseous chemical substance,
the plural anatase-type titanium oxide crystals are anatase-type titanium oxide microcrystals each having a crystal grain size of 10 nm or less and being able to oxidize a gaseous chemical substance,
the photocatalyst further comprising, between the plural tungsten oxide microcrystals and the plural anatase-type titanium oxide microcrystals, a metal that can cause multielectron reduction and promote transfer of electrons and holes generated from the plural tungsten oxide microcrystals or the plural anatase-type titanium oxide microcrystals by the photoirradiation, and
tungsten oxide microcrystals are irregularly arranged with the plural anatase-type titanium oxide microcrystals.

2. The photocatalyst of claim 1 , wherein the metal that can cause the multielectron reduction is platinum.

3. A photocatalyst carrier comprising:
the photocatalyst of claim 1 ; and
a carrier base carrying the photocatalyst.

4. The photocatalyst carrier of claim 3 , wherein the carrier base is a ceramic foam, a nonwoven fabric, or a ceramic honeycomb.

5. The photocatalyst carrier of claim 3 , wherein the carrier base has an organic substance content of 50% or less by mass.

6. A method for producing a photocatalyst comprising plural tungsten oxide microcrystals and plural anatase-type titanium oxide crystals and being capable of causing a photocatalytic reaction by photoirradiation, wherein
the plural tungsten oxide microcrystals are anatase-type tungsten oxide microcrystals each having a crystal grain size of 10 nm or less and being able to oxidize a gaseous chemical substance and,
the plural anatase-type titanium oxide microcrystals are anatase-type titanium oxide microcrystals each having a crystal grain size of 10 nm or less and being able to oxidize the gaseous chemical substance, and
the photocatalyst further comprising, between the plural tungsten oxide microcrystals and the plural anatase-type titanium oxide microcrystals, a metal that can cause multielectron reduction and promote transfer of electrons and holes generated from the plural tungsten oxide microcrystals or the plural anatase-type titanium oxide microcrystals by the photoirradiation, and
tungsten oxide microcrystals are irregularly arranged with the plural anatase-type titanium oxide microcrystals, the method comprising:
preparing a dispersion liquid comprising a precursor of the tungsten oxide microcrystals, a precursor of the titanium oxide microcrystals and the metal that can cause the multielectron reduction, and
firing the dispersion liquid.

7. The method of claim 6 , wherein the precursor of the tungsten oxide microcrystals is ammonium metatungstate, ammonium paratungstate, tungstic acid, tungsten chloride, or tungsten alkoxide, and
the precursor of the titanium oxide microcrystals is titanium lactate, titanium trichloride, titanium tetrachloride, titanium sulfate, titanium oxysulfate, titanium oxychloride, or titanium tetraisopropoxide.

8. A method for producing a photocatalyst carrier including a photocatalyst comprising plural tungsten oxide microcrystals and plural anatase-type titanium oxide crystals and being capable of causing a photocatalytic reaction by photoirradiation, wherein
the plural tungsten oxide microcrystals are tungsten oxide microcrystals each having a crystal grain size of 10 nm or less and being able to oxidize a gaseous chemical substance,
the plural anatase-type titanium oxide microcrystals are anatase-type titanium oxide microcrystals each having a crystal grain size of 10 nm or less and being able to oxidize the gaseous chemical substance, and
the tungsten oxide microcrystals are irregularly arranged with by the plural anatase-type titanium oxide microcrystals, the method comprising:
applying a dispersion liquid comprising a precursor of the tungsten oxide microcrystals, a precursor of the titanium oxide microcrystals and the metal that can cause the multielectron reduction, to the carrier base, to obtain an applied dispersion liquid, and
firing the applied dispersion liquid to form a photocatalyst layer.

Assignees

• Mitsubishi Electric Corp

Inventors

• Katsumata Noriaki
• Matsuura Yoko
• Wada Noboru
• Abe Ryu
• Tomita Osamu
• Shigemitsu Masaya

Classifications

• B01J35/70

  characterised by their crystalline properties, e.g. semi-crystalline (catalysts comprising carbon B01J21/18; molecular sieves B01J29/00) · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J2235/15

  X-ray diffraction · CPC title