Air filters comprising polymeric sorbents for aldehydes

Patent metadata

Field	Value
Publication number	US-11278832-B2
Application number	US-201816622661-A
Country	US
Kind code	B2
Filing date	Jun 6, 2018
Priority date	Jun 16, 2017
Publication date	Mar 22, 2022
Grant date	Mar 22, 2022

Abstract

An air filter including a filter support that supports polymeric sorbent particles. The polymeric sorbent particles are the reaction product of a hydrolyzed divinylbenzene/maleic anhydride precursor polymeric material with a nitrogen-containing compound, with the nitrogen-containing compound being ionically attached to the hydrolyzed divinylbenzene/maleic anhydride.

First claim

What is claimed is:

1. An air filter comprising a filter support that supports polymeric sorbent particles, wherein the polymeric sorbent comprises a reaction product of:
a) a hydrolyzed divinylbenzene/maleic anhydride polymeric material having carboxylic acid groups; and
b) a nitrogen-containing compound having at least two amino groups of formula —NHR

wherein R is hydrogen or alkyl and wherein the nitrogen-containing compound is attached to the hydrolyzed divinylbenzene/maleic anhydride polymeric material with an ionic bond;
and wherein the polymeric sorbent is present in the form of porous particles.

2. The air filter of claim 1 wherein the filter support comprises a substrate with at least one major surface with at least some polymeric sorbent particles disposed thereon.

3. The air filter of claim 1 wherein the filter support comprises a porous, air-permeable material with polymeric sorbent particles disposed on a major surface thereof and/or with polymeric sorbent particles disposed within the interior of the material at least in a location proximate the major surface of the material.

4. The air filter of claim 1 wherein the filter support comprises a fibrous web that exhibits an interior and wherein the polymeric sorbent particles are disposed within at least portions of the interior of the web.

5. The air filter of claim 4 wherein the polymeric sorbent particles are disposed throughout an interior of the fibrous web.

6. The air filter of claim 4 wherein the web is a nonwoven fibrous web.

7. The air filter of claim 4 wherein at least some fibers of the fibrous web are each bonded to at least one polymeric sorbent particle.

8. The air filter of claim 1 wherein the filter support is one layer of a multilayer, air-permeable assembly.

9. The air filter of claim 1 wherein the filter support is pleated.

10. The air filter of claim 1 wherein the air filter is a framed air filter that is configured to be inserted into an air filter receptacle of an air-handling apparatus chosen from the group consisting of a forced air heating unit, a forced air cooling unit, a forced-air heating/cooling unit, a room air purifier, and a cabin air filtration unit for a motor vehicle.

11. The air filter of claim 1 wherein the filter support provides a layer of a filtering face-piece respirator.

12. The air filter of claim 1 wherein the filter support comprises a container with an interior within which polymeric sorbent particles are disposed, and with at least one air inlet and at least one air outlet.

13. The air filter of claim 12 wherein the filter support comprises a filter cartridge.

14. The air filter of claim 1 wherein the polymeric sorbent particles are present in granules that further comprise at least one binder.

15. A method of capturing at least some of an aldehyde from air, the method comprising:
positioning the air filter of claim 1 so that the polymeric sorbent particles of the air filter are exposed to the air, and,
sorbing at least some of the aldehyde that is present in the air, onto the polymeric sorbent particles
wherein the aldehyde is of Formula (I)
R 2 —(CO)—H   (I)

wherein R 2 is hydrogen, alkyl, vinyl, or aryl and wherein the molecular weight of the aldehyde of Formula (I) is no greater than 200 grams/mole.

16. The method of claim 15 , wherein the filter support exhibits a major surface and wherein the air is present in the form of an airstream moving in a direction that is at least generally aligned with a plane of the major surface of the filter support.

17. The method of claim 15 wherein the filter support allows airflow therethrough and wherein the air is present in the form of an airstream that passes through at least a portion the filter support in a direction at least generally perpendicular to a major surface of the filter support.

18. A method of making an air filter comprising a filter support that comprises polymeric sorbent particles, the method comprising:
(a) providing a divinylbenzene/maleic anhydride precursor polymeric material;
(b) hydrolyzing the divinylbenzene/maleic anhydride precursor polymeric material to form a hydrolyzed divinylbenzene/maleic anhydride polymeric material having carboxylic acid groups; and
c) reacting the hydrolyzed divinylbenzene/maleic anhydride polymeric material with a nitrogen-containing compound having at least two amino groups of formula NHR where R is hydrogen or alkyl to form the porous polymeric sorbent particles, wherein the polymeric sorbent has an ionically attached nitrogen-containing group and wherein the polymeric sorbent particles are porous;
and,
(d) supporting the polymeric sorbent particles on the filter support.

Assignees

• 3M Innovative Properties Co

Inventors

• Jasuja Himanshu
• Kobe Michael W
• Wendland Michael S

Classifications

• B01D2257/708

  Volatile organic compounds V.O.C.'s · CPC title

• A62B23/025

  the filter having substantially the shape of a mask (surgical face masks A41D13/11) · CPC title

• B01D2239/0407

  comprising particulate additives, e.g. adsorbents · CPC title

• B01D39/1623 Primary

  of synthetic origin · CPC title

• A41D13/11

  Protective face masks, e.g. for surgical use, or for use in foul atmospheres (eye-masks A61F9/04 {; hoods affording protection against heat or harmful chemical agents A62B17/04}) · CPC title