Method for the production of a metal strip coated with a coating of chromium and chromium oxide using an electrolyte solution with a trivalent chromium compound

Patent metadata

Field	Value
Publication number	US-11274373-B2
Application number	US-201916711859-A
Country	US
Kind code	B2
Filing date	Dec 12, 2019
Priority date	Dec 13, 2018
Publication date	Mar 15, 2022
Grant date	Mar 15, 2022

Abstract

A method for producing a metal strip coated with a coating that contains chromium metal and chromium oxide and is electrolytically deposited from an electrolyte solution that contains a trivalent chromium compound onto the metal strip by bringing the metal strip, which is connected as the cathode, into contact with the electrolyte solution. An efficient deposition of coating with a high proportion of chromium oxide is obtained by successively passing the metal strip through a plurality of electrolysis tanks. The electrolyte solution in at least the last electrolysis tank, as viewed in the strip travel direction, or in a rear group of electrolysis tanks has an average temperature of at most 40° C., and the electrolysis time, during which the metal strip is in electrolytically effective contact with the electrolyte solution in the last electrolysis tank or in the rear group of electrolysis tanks is less than 2.0 seconds.

First claim

What is claimed is:

1. A method for producing a metal strip coated with a coating containing chromium metal and chromium oxide, the method comprising:
connecting the metal strip as a cathode and passing the metal strip at a predefined strip speed through a plurality of electrolysis tanks successively arranged in a strip travel direction and filled with electrolyte solution containing a trivalent chromium compound, the plurality of electrolysis tanks including at least a first electrolysis tank or a front group of electrolysis tanks and a last electrolysis tank or a rear group of electrolysis tanks;
wherein the electrolyte solution in the first electrolysis tank or in the front group of electrolysis tanks has a first temperature averaged across a volume of an electrolysis tank and the electrolyte solution in the last electrolysis tank or in the rear group of electrolysis tanks has a second temperature, averaged across a volume of an electrolysis tank, less than 40° C. and lower than the first temperature; and
bringing the metal strip into contact with the electrolyte solution during an electrolysis time to electrolytically deposit the coating onto the metal strip, the coating having at least two layers with different compositions, the at least two layers including a lower layer facing the metal strip and having a first proportion by weight of chromium oxide, and an upper layer having a second proportion by weight of chromium oxide, the second proportion by weight of chromium oxide being higher than the first proportion by weight of chromium oxide;
wherein the electrolysis time, during which the metal strip is in contact with the electrolyte solution in the last electrolysis tank or in the rear group of electrolysis tanks, is less than 2.0 seconds.

2. The method as in claim 1 , wherein the electrolysis time, during which the metal strip is in electrolytic contact with the electrolyte solution in each electrolysis tank of the plurality of electrolysis tanks, is less than 2.0 seconds.

3. The method as in claim 1 , wherein the electrolysis time, during which the metal strip is in electrolytic contact with the electrolyte solution in each electrolysis tank of the plurality of electrolysis tanks, is between 0.3 and 2.0 seconds.

4. The method as in claim 1 , wherein a total electrolysis time, during which the metal strip is in electrolytic contact with the electrolyte solution in the plurality of electrolysis tanks is between 2 and 16 seconds.

5. The method as in claim 1 , wherein a mean second temperature of the electrolyte solution in the last electrolysis tank or in the rear group of electrolysis tanks is between 25° C. and 38° C.

6. The method as in claim 1 , wherein a mean first temperature of the electrolyte solution in the first electrolysis tank or in the front group of electrolysis tanks is greater than 40° C.

7. The method as in claim 1 , wherein a temperature of the electrolyte solution, averaged across the volume of the electrolysis tank, in each electrolysis tank of the plurality of electrolysis tanks is between 20° C. and 40° C.

8. The method as in claim 7 , wherein the temperature of the electrolyte solution, averaged across the volume of the electrolysis tank, in each electrolysis tank of the plurality of electrolysis tanks is between 25° C. and 38° C.

9. The method as in claim 1 , wherein a mean first temperature of the electrolyte solution in the first electrolysis tank or in the front group of electrolysis tanks is higher than a mean second temperature of the electrolyte solution in the last electrolysis tank or the rear group of electrolysis tanks.

10. The method as in claim 9 , wherein the plurality of electrolysis tanks further includes a second electrolysis tank or a middle group of electrolysis tanks arranged following the first electrolysis tank or the front group of electrolysis tanks and before the last electrolysis tank or the rear group of electrolysis tanks; and wherein the first electrolysis tank or the front group of electrolysis tanks has a low current density (j 1 ), the second electrolysis tank or the middle group of electrolysis tanks has a medium current density (j 2 ), and the last electrolysis tank or the rear group of electrolysis tanks has a high current density (j 3 ), wherein the low current density (j 1 ) is greater than 20 A/dm 2 and the high current density (j 3 ) is higher than the low current density (j 1 ) and the medium current density (j 2 ).

11. The method as in claim 1 , wherein the trivalent chromium compound comprises basic Cr(III) sulfate (Cr 2 (SO 4 ) 3 ).

12. The method as in claim 1 , wherein the electrolyte solution 12 further comprises at least one complexing agent and an alkali metal sulfate.

13. The method as in claim 12 , wherein the alkali metal sulfate is potassium sulfate or sodium sulfate and the electrolyte solution is at least one of free of halides and free of a buffering agent.

14. The method as in claim 1 , wherein the trivalent chromium compound in the electrolyte solution has a concentration of at least 10 g/L.

15. The method as in claim 1 , wherein a pH value of the electrolyte solution, measured at a temperature of 20° C. is between 2.0 and 3.0.

16. The method as in claim 1 , wherein the predefined strip speed is at least 100 m/min.

17. The method as in claim 1 , wherein the coating has a total coating weight of chromium of at least 40 mg/m 2 , wherein a proportion of chromium oxide contained in the total coating weight is at least 5%.

18. The method as in claim 1 , wherein the coating has a chromium oxide content with a coating weight of chromium bound as chromium oxide of at least 5 mg of Cr per m 2 .

19. The method as in claim 1 , wherein the lower layer has a first proportion by weight of chromium oxide in a range from 10% to 15% and the upper layer has second a proportion by weight of chromium oxide of more than 30%.

20. The method as in claim 19 , wherein the coating further comprises a middle layer arranged between the lower and upper layers, the middle layer having a middle proportion by weight of chromium oxide in a range from 2% to 10%.

21. The method as in claim 1 , further comprising, following the electrolytic deposition of the coating, applying a top coat of organic material to the coating.

22. The method as in claim 1 , wherein the metal strip is a tin-free steel strip or a steel strip coated with tin.

Assignees

• Thyssenkrupp Rasselstein Gmbh
• Thyssenkrupp Ag

Inventors

• Marmann Andrea
• Molls Christoph
• Görtz Rainer
• Lenz Thomas

Classifications

• C25D21/02

  Heating or cooling · CPC title

• C25D7/0614

  Strips or foils · CPC title

• C25D21/10

  Agitating of electrolytes; Moving of racks · CPC title

• C25D5/14

  two or more layers being of nickel or chromium, e.g. duplex or triplex layers · CPC title

• C25D21/12

  Process control or regulation (controlling or regulating in general G05) · CPC title