Process for selective production of light olefins and aromatic from cracked light naphtha

Patent metadata

Field	Value
Publication number	US-11274257-B2
Application number	US-201916560531-A
Country	US
Kind code	B2
Filing date	Sep 4, 2019
Priority date	Sep 6, 2018
Publication date	Mar 15, 2022
Grant date	Mar 15, 2022

Abstract

The present invention provides a process for a production of light olefins and aromatics from cracked light naphtha by selective cracking. The present invention thus provides a process for up grading cracked olefinic naphtha to high value petrochemical feed stocks. This process is based on catalytic cracking in which the catalyst activity is optimized by depositing coke for production of light olefins and aromatics. The proposed process has high flexibility and can be operated either in maximizing olefins as reflected from the PIE ratio or in maximizing aromatics (BTX) at different modes of operation depending upon the product requirement.

First claim

The invention claimed is:

1. A process for selective production of light olefins and aromatics, the process comprising:
a) feeding a mixed olefinic cracked naphtha feedstock into a reactor, wherein the mixed olefinic cracked naphtha feedstock is a mixture containing paraffins, iso-paraffins, olefins, naphthenes, and aromatics;
b) catalytically cracking the mixed olefinic cracked naphtha feedstock in the reactor selectively under an olefinic mode or an aromatic mode of operation,
(i) wherein the olefinic mode of operation comprises: contacting the mixed olefinic cracked naphtha feedstock with a zeolite catalyst for a catalyst residence time ranging between 35-65 minutes and at a pressure ranging between 1-2 bar to obtain a cracked product comprising light olefins in the range of 30-50 wt % and obtaining the light olefins as a gaseous product with a propylene to ethylene ratio (P/E) in the range of 1-5;
(ii) wherein the aromatic mode of operation comprises:
adding hydrogen to the mixed olefinic cracked naphtha feedstock to form a mixture; and:
contacting the mixture with a zeolite catalyst for a catalyst residence time ranging between 20-35 minutes and at a pressure ranging between 5-7 bar to obtain a cracked product comprising aromatics in the range of 10-25 wt % and obtaining the aromatics as a liquid product;
wherein the zeolite catalyst in the olefinic mode of operation and in the aromatic mode of operation consists of pentasil type zeolite used either alone or in combination with a Y-type zeolite; wherein the pentasil type zeolite is ZSM-5, and Y-type zeolite is selected from the group consisting of Zeolite-Y (Na-Y). USY and Rare earth exchanged-Y; and

c) recovering spent catalyst from the reactor and feeding the spent catalyst to a regenerator to obtain a regenerated catalyst and recycling the regenerated catalyst to the reactor.

2. The process as claimed in claim 1 , wherein the mixed olefinic cracked naphtha is in the range of C5-220° C.

3. The process as claimed in claim 1 , wherein the catalytic cracking in step (b) is carded out at a space velocity ranging between 10-20 hr −1 and at a temperature of 600° C.

4. The process as claimed in claim 1 , wherein the aromatics comprise of BTX;
wherein BTX is a combination of benzene, toluene and xylene.

5. The process as claimed in claim 1 , wherein in the olefinic mode of operation, the light olefin selectivity is in the range of 30-50 wt % at a colic deposition level ranging from 6 to 8 wt %.

6. The process as claimed in claim 1 , wherein in the aromatic mode of operation, the selectivity for aromatics is in the range of 10-25 wt % in the liquid product and BTX concentration in the aromatics is in the range of 5-13 wt % on addition of hydrogen with the mixed olefinic cracked naphtha feedstock.

7. The process as claimed in claim 1 , wherein the liquid product obtained in step (b) is blended directly into gasoline pool to obtain product gasoline.

Assignees

• Indian Oil Corp Ltd

Inventors

• Saravanan Subramani
• Hari Prasadgupta Bandaru Venkata
• Maji Prosenjit
• Khan Shoeb Hussain
• Dixit Jagdev Kumar
• Singh Shakti
• Manna Reshmi
• Sau Madhusudan
• Bhattacharyya Debasis
• Mazumdar Sanjiv Kumar
• RAMAKUMAR Sankara Sri Venkata

Classifications

• C07C4/06

  Catalytic processes {(C07C4/025 takes precedence)} · CPC title

• C10G11/16 Primary

  according to the "moving bed" method · CPC title

• C10G2300/70

  Catalyst aspects · CPC title

• C07C2529/08

  of the faujasite type, e.g. type X or Y · CPC title

• B01J8/1827

  the fluidising gas being a reactant · CPC title