Bioriented polyethylene film

Patent metadata

Field	Value
Publication number	US-11273592-B2
Application number	US-201916435935-A
Country	US
Kind code	B2
Filing date	Jun 10, 2019
Priority date	Aug 26, 2011
Publication date	Mar 15, 2022
Grant date	Mar 15, 2022

Abstract

The present invention discloses a process for forming a biaxially oriented film. The process includes first selecting a polyolefin resin wherein said polyolefin resin comprises a linear low density polyethylene resin characterized by having from 9 to 35 weight percent of the total weight of linear low density polyethylene resin eluting from a CEF at a temperature greater than 97.0° C.; and further characterized by having a CDR of from 33 to 80 and a Mw Ratio of from 0.15 to 0.45. Next a film is formed from the polyolefin resin selected in the first step. Finally the film formed in the second step is oriented in a sequential manner. The films produced by this process are characterized by having an ultimate elongation at least 1.5 times greater in the MD as compared to the CD and the 2% secant modulus is a least 1.25 times greater in the CD as compared to the MD. The films are further characterized by having free residual shrinkage of less than 10% in the MD and less than 10% in the CD when exposed to a temperature of 90° C. for 10 minutes.

First claim

What is claimed is:

1. A biaxially oriented film comprising: a polyolefin resin wherein said polyolefin resin comprises a linear low density polyethylene resin characterized by having from 9 to 35 weight percent of the total weight of the linear low density polyethylene resin eluting from a crystallization elution fractionation (CEF) at a temperature greater than 97° C.; and further characterized by having a comonorner distribution ratio (CDR) of from 33 to 80 and a molecular weight ratio (Mw Ratio) of from 0.15 to 0.45; wherein said film is surface treated to exhibit a surface tension of greater than or equal to 38 dyne/cm surface tension; wherein the film is characterized by having an ultimate elongation at least 1.5 times greater in the machine direction (MD) as compared to the cross direction (CD) and the 2% secant modulus is at least 1.25 times greater in the CD as compared to the MD; and wherein the film is characterized by having free residual shrinkage of less than 10% in the MD and less than 10% in the CD when exposed to a temperature of 90° C. for 10 minutes.

2. The film of claim 1 , wherein the film has a thickness of from 20 to 50 microns.

3. The film of claim 1 , in which the film is a mono layer film.

4. The film of claim 1 , in which the film is a multilayer film.

5. The film of claim 4 , wherein the film comprises one or more core layers and two skin layers and wherein at least one core layer has a higher density than at least one of the skin layers.

6. A laminated film structure comprising a substrate with the film of claim 5 laminated thereto.

7. The laminated film structure of claim 6 wherein the substrate is selected from the group consisting of one or more of the following: bi-oriented polypropylene film, oriented polyethylene terephthalate film, oriented polyamide film, blown or cast PE film, aluminum foil and paper.

Assignees

• Dow Global Technologies Llc

Inventors

• Yun Xiao Bing
• Cong Rongjuan
• Pan Jianping
• Karjala Teresa P

Classifications

• B32B7/02

  Physical, chemical or physicochemical properties · CPC title

• C08L23/10

  Homopolymers or copolymers of propene · CPC title

• B29C48/0018

  combined with shaping by orienting, stretching or shrinking, e.g. film blowing (B29C48/0017 takes precedence) · CPC title

• B32B27/08

  of synthetic resin · CPC title

• Y10T428/24992

  Density or compression of components · CPC title