Alloyed halide double perovskites as solar-cell absorbers

Patent metadata

Field	Value
Publication number	US-11271123-B2
Application number	US-201815937530-A
Country	US
Kind code	B2
Filing date	Mar 27, 2018
Priority date	Mar 27, 2017
Publication date	Mar 8, 2022
Grant date	Mar 8, 2022

Abstract

An alloyed halide double perovskite material, an alloyed halide double perovskite solar-cell absorber and solar cells constructed with such absorbers, the alloyed halide double perovskite material having the formula A2B1-aB′1-bDxX6, where A is an inorganic cation, an organic cation, a mixture of inorganic cations, a mixture of organic cations, or a mixture of one or more inorganic cations and one or more organic cations, where B is a metal, a mixture of metals, a metalloid, a mixture of metalloids, any mixture thereof, or is a vacancy, where B′ is a metal, a mixture of metals, a metalloid, a mixture of metalloids, any mixture thereof, or is a vacancy, where D is a dopant, and where X is a halide, a pseudohalide, a mixture of halides, a mixture of pseudohalides, or a mixture of halides and pseudohalides, and where x=a+b.

First claim

What is claimed is:

1. A solar cell comprising a solar-cell absorber layer comprising a halide double perovskite material having a formula:
A 2 B 1-a B′ 1-b D x X 6

where B and/or B′ is alloyed by D to produce an alloyed halide double perovskite material,
where A is an inorganic cation, an organic cation, a mixture of inorganic cations, a mixture of organic cations, or a mixture of one or more inorganic cations and one or more organic cations,
where D is a dopant, where x=a+b, and where a is not equal to b when D is a single metal or a single metalloid,
where X is a halide, a pseudohalide, a mixture of halides, a mixture of pseudohalides, or a mixture of halides and pseudohalides, and
where B is a metal, a mixture of metals, a metalloid, a mixture of metalloids, or any mixture thereof, and B′ is a metal, a mixture of metals, a metalloid, a mixture of metalloids, or any mixture thereof, or
where B is a metal, a mixture of metals, a metalloid, a mixture of metalloids, or any mixture thereof, and B′ is a vacancy, or
where B′ is a metal, a mixture of metals, a metalloid, a mixture of metalloids, or any mixture thereof, and B is a vacancy.

2. The solar cell of claim 1 , wherein the dopant is Tl, In, Ga, Bi, Sb, As, Se, Te, Pb, Sn, Cu, Au, Zn, Cd, Hg, Sc, Y, Mn, Fe, K, Rb, Cs, Ca, Sr, Ba, La, Ti, Zr, Hf, Ag, Al, Ge, S, V, Nb, or any mixture thereof.

3. The solar cell of claim 1 , wherein the alloyed halide double perovskite material is (MA) 2 (Tl 1-a Bi 1-b )Ag x Br 6 , x=a+b=0.2.

4. The solar cell of claim 1 , wherein the alloyed halide double perovskite material is Cs 2 (Ag 1-a Bi 1-b )Tl x Br 6 (x=a+b=0.003−0.075).

5. A composition comprising a halide double perovskite material having a formula:
A 2 B 1-a B′ 1-b D x X 6

where B and/or B′ is alloyed by D to produce an alloyed halide double perovskite material,
where A is an inorganic cation, an organic cation, a mixture of inorganic cations, a mixture of organic cations, or a mixture of one or more inorganic cations and one or more organic cations,
where D is a dopant, where x=a+b, and where a is not equal to b when D is a single metal or a single metalloid,
where X is a halide, a pseudohalide, a mixture of halides, a mixture of pseudohalides, or a mixture of halides and pseudohalides, and
where B is a metal, a mixture of metals, a metalloid, a mixture of metalloids, or any mixture thereof, and B′ is a metal, a mixture of metals, a metalloid, a mixture of metalloids, or any mixture thereof, or
where B is a metal, a mixture of metals, a metalloid, a mixture of metalloids, or any mixture thereof, and B′ is a vacancy, or
where B′ is a metal, a mixture of metals, a metalloid, a mixture of metalloids, or any mixture thereof, and B is a vacancy.

6. The composition of claim 5 , wherein the dopant is Tl, In, Ga, Bi, Sb, As, Se, Te, Pb, Sn, Cu, Au, Zn, Cd, Hg, Sc, Y, Mn, Fe, K, Rb, Cs, Ca, Sr, Ba, La, Ti, Zr, Hf, Ag, Al, Ge, S, V, Nb, or any mixture thereof.

7. The composition of claim 5 , wherein the alloyed halide double perovskite material is (MA) 2 (Tl 1-a Bi 1-b )Ag x Br 6 , x=a+b=0.2.

8. The composition of claim 5 , wherein the alloyed halide double perovskite material is Cs 2 (Ag 1-a Bi 1-b )Tl x Br 6 (x=a+b=0.003−0.075).

9. A solar absorber for a photovoltaic cell, the solar absorber comprising a halide double perovskite material having a formula:
A 2 B 1-a B′ 1-b D x X 6

where B and/or B′ is alloyed by D to produce an alloyed halide double perovskite material,
where A is an inorganic cation, an organic cation, a mixture of inorganic cations, a mixture of organic cations, or a mixture of one or more inorganic cations and one or more organic cations,
where D is a dopant, where x=a+b, and where a is not equal to b when D is a single metal or a single metalloid,
where X is a halide, a pseudohalide, a mixture of halides, a mixture of pseudohalides, or a mixture of halides and pseudohalides, and
where B is a metal, a mixture of metals, a metalloid, a mixture of metalloids, or any mixture thereof, and B′ is a metal, a mixture of metals, a metalloid, a mixture of metalloids, or any mixture thereof, or
where B is a metal, a mixture of metals, a metalloid, a mixture of metalloids, or any mixture thereof, and B′ is a vacancy, or
where B′ is a metal, a mixture of metals, a metalloid, a mixture of metalloids, or any mixture thereof, and B is a vacancy.

10. The solar absorber of claim 9 , wherein the dopant is Tl, In, Ga, Bi, Sb, As, Se, Te, Pb, Sn, Cu, Au, Zn, Cd, Hg, Sc, Y, Mn, Fe, K, Rb, Cs, Ca, Sr, Ba, La, Ti, Zr, Hf, Ag, Al, Ge, S, V, Nb, or any mixture thereof.

11. The solar absorber of claim 9 , wherein the alloyed halide double perovskite material is (MA) 2 (Tl 1-a Bi 1-b )Ag x Br 6 , x=a+b=0.2.

12. The solar absorber of claim 9 , wherein the alloyed halide double perovskite material is Cs 2 (Ag 1-a Bi 1-b )Tl x Br 6 (x=a+b=0.003−0.075).

Assignees

• Univ Leland Stanford Junior

Inventors

• Karunadasa Hemamala Indivari
• Slavney Adam H

Classifications

• H10K85/50

  Organic perovskites; Hybrid organic-inorganic perovskites [HOIP], e.g. CH3NH3PbI3 · CPC title

• H10K30/211

  comprising multiple junctions, e.g. double heterojunctions · CPC title

• H10K30/50

  Photovoltaic [PV] devices · CPC title

• H10F77/12

  Active materials · CPC title

• H10K85/60 Primary

  Organic compounds having low molecular weight (H10K85/10 - H10K85/50 take precedence) · CPC title