Exhaust gas treatment system with upstream SCR catalyst

Patent metadata

Field	Value
Publication number	US-11268420-B2
Application number	US-201916971236-A
Country	US
Kind code	B2
Filing date	Feb 18, 2019
Priority date	Feb 19, 2018
Publication date	Mar 8, 2022
Grant date	Mar 8, 2022

Abstract

A system for treatment of an exhaust gas stream from an engine is provided, containing an upstream selective catalytic reduction (SCR) catalyst, which receives the exhaust gas stream without any intervening catalyst, a diesel oxidation catalyst (DOC) positioned downstream thereof; a catalyzed soot filter (CSF) downstream of the diesel oxidation catalyst; a second SCR catalyst positioned downstream of the catalyzed soot filter; and an ammonia oxidation (AMOx) catalyst. The application also describes use of such systems to reduce nitrogen oxides (NOx) and hydrocarbons (HC) in an exhaust gas stream.

First claim

What is claimed is:

1. A system for treatment of an exhaust gas stream from an engine, the system comprising:
a first selective catalytic reduction (SCR) catalyst that is in fluid communication with the exhaust gas stream, wherein the first SCR catalyst receives the exhaust gas stream without any intervening catalyst;
a diesel oxidation catalyst (DOC) in fluid communication with the first SCR catalyst, wherein the diesel oxidation catalyst is positioned downstream of the first SCR catalyst;
a catalyzed soot filter (CSF) in fluid communication with the diesel oxidation catalyst, wherein the catalyzed soot filter is positioned downstream of the diesel oxidation catalyst;
a second SCR catalyst in fluid communication with the catalyzed soot filter, wherein the second SCR catalyst is positioned downstream of the catalyzed soot filter; and
a first AMOx catalyst that is either integrated with the second SCR catalyst or in fluid communication with and downstream of the second SCR catalyst.

2. The system of claim 1 , wherein the first SCR catalyst is in a close-coupled position.

3. The system of claim 1 , where the first SCR catalyst is in an underfloor position.

4. The system of claim 1 , further comprising a second AMOx catalyst integrated with the first SCR catalyst, in the form of an SCR/AMOx catalyst.

5. The system of claim 4 , wherein the second AMOx catalyst comprises platinum.

6. The system of claim 4 , wherein the SCR/AMOx catalyst is in the form of two or more washcoats on a flow-through substrate, wherein the flow-through substrate has an upstream inlet end and a downstream outlet end, and wherein the second AMOx catalyst comprises platinum and is at the outlet end and extends less than a full length of the SCR/AMOx catalyst.

7. The system of claim 6 , wherein the SCR/AMOx catalyst comprises: a bottom washcoat comprising the second AMOx catalyst in direct contact with the flow through substrate, wherein the second AMOx catalyst extends less than the full length of the SCR/AMOx catalyst; and a top washcoat comprising the SCR catalyst extending the full length of the SCR/AMOx catalyst.

8. The system of claim 1 , wherein the first SCR catalyst comprises a vanadium component.

9. The system of claim 1 , wherein the first SCR catalyst comprises copper-promoted molecular sieves.

10. The system of claim 1 , wherein the first SCR catalyst comprises Cu-CHA.

11. The system of claim 1 , further comprising a dual injector system, comprising a first injector adapted for the addition of a first reductant to the exhaust gas stream upstream of the first SCR catalyst and a second injector adapted for the addition of a second reductant to the exhaust gas stream upstream of the second SCR catalyst.

12. The system of claim 11 , wherein the first and second reductants comprise ammonia or an ammonia precursor.

13. The system of any of claim 1 , wherein the CSF comprises one or more washcoats on a wall flow filter, and wherein the one or more washcoats comprise platinum and palladium.

14. The system of claim 13 , wherein the platinum and palladium in the one or more washcoats of the CSF are supported on alumina and are present in a ratio of about 4:1 Pt:Pd.

15. The system of claim 1 , wherein the DOC comprises one or more washcoats on a flow-through substrate having an upstream inlet end and a downstream outlet end, and wherein the one or more washcoats comprise platinum and palladium on alumina.

16. The system of claim 15 , wherein the DOC comprises:
a first washcoat coated from the upstream inlet end comprising platinum and palladium on alumina, extending less than a full length of the flow-through substrate, with a platinum:palladium ratio of about 1:1; and
a second washcoat coated from the downstream outlet end comprising platinum and palladium on alumina, extending less than the full length of the flow-through substrate, with a platinum:palladium ratio of greater than 2:1.

17. The system of claim 1 , wherein the DOC is associated with the CSF, in the form of a zoned DOC/CSF having an upstream inlet end and a downstream outlet end, wherein the DOC is at the upstream inlet end and extends less than a full length of the CSF.

18. The system of claim 17 , wherein the zoned DOC/CSF is in the form of two or more washcoats on a wall flow filter, comprising:
a first washcoat extending a full length of the wall flow filter comprising platinum and palladium on alumina, with a platinum:palladium ratio of greater than 5:1, and
a second washcoat extending from the upstream inlet end less than the full length of the wall flow filter, comprising platinum and palladium on alumina, with a platinum:palladium ratio of greater than 5:1 and a loading of about 50 g/ft 3 or greater.

19. The system of claim 1 , wherein the first AMOx catalyst is in fluid communication with and downstream of the second SCR catalyst, and wherein the first AMOx catalyst is integrated with a third SCR catalyst.

20. The system of claim 1 , wherein the second SCR catalyst has an upstream inlet end and a downstream outlet end, and comprises an iron-promoted molecular sieve extending from the inlet end to less than a full length of the SCR catalyst and comprises a copper-promoted molecular sieve extending from the outlet end to less than the full length of the SCR catalyst.

21. The system of claim 20 , wherein the iron-promoted molecular sieve is Fe-CHA and the copper-promoted molecular sieve is Cu-CHA.

22. The system of claim 1 , wherein the engine is a lean burn engine.

23. The system of claim 1 , wherein the engine is a diesel engine.

24. A method of treating an exhaust gas stream, comprising contacting the exhaust gas stream with the system of claim 1 such that nitrogen oxides (NOx) in the exhaust gas stream are reduced.

Assignees

• Basf Corp

Inventors

• Voss Kenneth E
• Hallstrom Kevin A
• Shah Sandip D
• Youngren David M
• Thoms Andrew
• Kazi M Shahjahan
• Dorner Robert

Classifications

• Y02T10/12

  Improving ICE efficiencies · CPC title

• Y02A50/20

  Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters · CPC title

• F01N3/035 Primary

  with catalytic reactors · CPC title

• F01N3/2066 Primary

  Selective catalytic reduction [SCR] · CPC title

• F01N2250/12

  absorption or adsorption, and catalytic conversion · CPC title