Creep resistant titanium alloys

Patent metadata

Field	Value
Publication number	US-11268179-B2
Application number	US-201816114405-A
Country	US
Kind code	B2
Filing date	Aug 28, 2018
Priority date	Aug 28, 2018
Publication date	Mar 8, 2022
Grant date	Mar 8, 2022

Abstract

A non-limiting embodiment of a titanium alloy comprises, in weight percentages based on total alloy weight: 5.5 to 6.5 aluminum; 1.5 to 2.5 tin; 1.3 to 2.3 molybdenum; 0.1 to 10.0 zirconium; 0.01 to 0.30 silicon; 0.1 to 2.0 germanium; titanium; and impurities. A non-limiting embodiment of the titanium alloy comprises a zirconium-silicon-germanium intermetallic precipitate, and exhibits a steady-state creep rate less than 8×10−4 (24 hrs)−1 at a temperature of at least 890° F. under a load of 52 ksi.

First claim

We claim:

1. A titanium alloy comprising, in weight percentages based on total alloy weight:
5.5 to 6.5 aluminum;
1.5 to 2.5 tin;
1.3 to 2.3 molybdenum;
0.1 to 10.0 zirconium;
0.01 to 0.30 silicon;
0.1 to 2.0 germanium;
titanium; and
impurities;
wherein the titanium alloy comprises an intermetallic precipitate comprising zirconium, silicon, and germanium.

2. The titanium alloy of claim 1 comprising, in weight percentages based on total alloy weight:
5.5 to 6.5 aluminum;
1.7 to 2.1 tin;
1.7 to 2.1 molybdenum;
3.4 to 4.4 zirconium;
0.03 to 0.11 silicon;
0.1 to 0.4 germanium;
titanium; and
impurities.

3. The titanium alloy of claim 1 comprising, in weight percentages based on total alloy weight:
5.9 to 6.0 aluminum;
1.9 to 2.0 tin;
1.8 to 1.9 molybdenum;
3.5 to 4.3 zirconium;
0.06 to 0.11 silicon;
0.1 to 0.4 germanium;
titanium; and
impurities.

4. The titanium alloy of claim 1 further comprising, in weight percentages based on total alloy weight:
0 to 0.15 oxygen;
0 to 0.30 iron;
0 to 0.05 nitrogen;
0 to 0.05 carbon;
0 to 0.015 hydrogen; and
0 to 0.1 each of niobium, tungsten, hafnium, nickel, gallium, antimony, vanadium, tantalum, manganese, cobalt, and copper.

5. The titanium alloy of claim 1 , wherein the titanium alloy exhibits a steady-state creep rate less than 7.97×10 −4 (24 hrs) −1 at a temperature of at least 475° C. under a load of 52 ksi.

6. The titanium alloy of claim 1 , wherein the titanium alloy exhibits an ultimate tensile strength of at least 130 ksi at 482° C.

7. A titanium alloy consisting essentially of, in weight percentages based on total alloy weight:
5.5 to 6.5 aluminum;
1.5 to 2.5 tin;
1.3 to 2.3 molybdenum;
0.1 to 10.0 zirconium;
0.01 to 0.30 silicon;
0.1 to 2.0 germanium;
0 to 0.15 oxygen;
0 to 0.30 iron;
0 to 0.05 nitrogen;
0 to 0.05 carbon;
0 to 0.015 hydrogen;
0 to 0.1 of each of niobium, tungsten; hafnium, nickel, gallium, antimony, vanadium, tantalum, manganese, cobalt; and copper;
titanium; and
impurities,
wherein the titanium alloy comprises an intermetallic precipitate comprising zirconium, silicon, and germanium.

8. The titanium alloy of claim 7 , wherein an aluminum content in the alloy is, in weight percentages based on total alloy weight, 5.9 to 6.0.

9. The titanium alloy of claim 7 , wherein a tin content in the alloy is, in weight percentages based on total alloy weight, 1.7 to 2.1.

10. The titanium ahoy of claim 7 ; wherein a tin content in the alloy is, in weight percentages based on total alloy weight, 1.9 to 2.0.

11. The titanium alloy of claim 7 , wherein a molybdenum content in the alloy is, in weight percentages based on total alloy weight, 1.7 to 2.1.

12. The titanium alloy of claim 7 , wherein a molybdenum content in the alloy is, in weight percentages based on total alloy weight, 1.8 to 1.9.

13. The titanium alloy of claim 7 , wherein a zirconium content in the alloy is, in weight percentages based on total alloy weight, 3.4 to 4.4.

14. The titanium alloy of claim 7 , wherein a zirconium content in the alloy is, in weight percentages based on total alloy weight, 3.5 to 4.3.

15. The titanium alloy of claim 7 , wherein a silicon content in the alloy is, in weight percentages based on total alloy weight, 0.03 to 0.11.

16. The titanium alloy of claim 7 , wherein a silicon content in the alloy is, in weight percentages based on total alloy weight, 0.06 to 0.11.

17. The titanium alloy of claim 7 , wherein a germanium content n the alloy is, in weight percentages based on total alloy weight, 0.1 to 0.4.

18. The titanium alloy of claim 7 ; wherein in the titanium alloy;
an oxygen content is 0 to 0.15;
an iron content is 0 to 0.30;
a nitrogen content is 0 to 0.05;
a carbon content is 0 to 0.05;
a hydrogen content is 0 to 0.015; and
a content of each of niobium, tungsten, hafnium, nickel, gallium, antimony, vanadium, tantalum, manganese, cobalt, and copper is 0 to 0.1,
all in weight percentages based on total weight of the titanium alloy.

19. The titanium alloy of claim 7 , wherein the titanium alloy exhibits a steady-state creep rate less than 7.97×10 −4 (24 hrs) −1 at a temperature of at least 475° C. under a load of 52 ksi.

20. The titanium alloy of claim 7 , wherein the titanium alloy exhibits an ultimate tensile strength of at least 130 ksi at 482° C.

21. A titanium alloy comprising, in weight percentages based on total alloy weight:
2 to 7 aluminum;
0 to 5 tin;
0 to 5 molybdenum;
0.1 to 10.0 zirconium;
0.01 to 0.30 silicon;
0.05 to 2.0 germanium;
0 to 0.30 oxygen;
0 to 0.30 iron;
0 to 0.05 nitrogen;
0 to 0.05 carbon;
0 to 0.015 hydrogen;
titanium; and
impurities;
wherein the titanium ahoy comprises an intermetallic precipitate comprising zirconium, silicon, and germanium.

22. The titanium alloy of claim 21 , wherein the titanium alloy exhibits a steady-state creep rate less than 8×10 −4 (24 hrs) −1 at a temperature of at least 890° F. under a load of 52 ksi.

23. The titanium alloy of claim 21 further comprising, in weight percentages based on total alloy weight:
0 to 5 chromium.

24. The titanium alloy of claim 21 further comprising, in weight percentages based on total alloy weight:
0 to 6.0 each of niobium, tungsten, vanadium, tantalum, manganese, nickel, hafnium, gallium, antimony, cobalt, and copper.

25. The titanium alloy of claim 24 , wherein the titanium alloy exhibits a steady-state creep rate less than 8×10 −4 (24 hrs) −1 at a temperature of at least 890° F. under a load of 52 ksi.

26. The titanium alloy of claim 24 further comprising, in weight percentages based on total alloy weight:
0 to 5 chromium.

Assignees

• Ati Properties Llc

Inventors

• Mantione John V
• Bryan David J
• Garcia-Avila Matias

Classifications

• C22F1/183 Primary

  of titanium or alloys based thereon · CPC title

• C22C14/00 Primary

  Alloys based on titanium · CPC title