Process for the preparation of dry chlorinated polyvinyl chloride

Patent metadata

Field	Value
Publication number	US-11267915-B2
Application number	US-201816480520-A
Country	US
Kind code	B2
Filing date	Jan 19, 2018
Priority date	Jan 25, 2017
Publication date	Mar 8, 2022
Grant date	Mar 8, 2022

Abstract

The present disclosure provides an effective and efficient process for the preparation of a dry chlorinated polyvinyl chloride (CPVC), comprising introducing chlorine gas into slurry of polyvinyl chloride in water to obtain a reaction mixture; irradiating the reaction mixture to obtain a product mixture comprising CPVC and water solution including unreacted chlorine gas and hydrogen chloride; filtering the product mixture to obtain a first mass; adding water to the first mass for extracting unreacted chlorine gas and hydrogen chloride to obtain an aqueous suspension, and filtering the aqueous suspension to obtain a second mass; passing nitrogen through the second mass to extract residual water solution to leave behind a third mass; and agitating the third mass in a high-speed mixer together with a neutralizing agent, and optionally with a stabilizer and a processing additive to obtain dry thermally stable CPVC with thermal stability in the range of 1000 seconds to 1500 seconds.

First claim

The invention claimed is:

1. A process for the preparation of dry thermally stable chlorinated polyvinyl chloride, said process comprising:
i. introducing polyvinyl chloride and water in an air tight vessel to form a slurry;
ii. introducing chlorine gas into said air tight vessel till a chlorine pressure in the range of 1 kg/cm 2 to 5 kg/cm 2 is attained, and stirring the slurry and chlorine gas to obtain a reaction mixture;
iii. irradiating said reaction mixture using radiation having a wavelength in the range of 390 nm to 730 nm, while heating at a temperature in the range of 50° C. to 90° C. to obtain a product mixture comprising chlorinated polyvinyl chloride and water solution including dissolved unreacted chlorine gas and hydrogen chloride;
iv. filtering said product mixture to obtain a first mass comprising chlorinated polyvinyl chloride, and a first residuary water solution;
v. adding water to said first mass under stirring for extracting unreacted chlorine gas and hydrogen chloride to obtain an aqueous suspension, followed by pressure filtering said aqueous suspension to obtain a second mass comprising chlorinated polyvinyl chloride, and a second residuary water solution;
vi. passing nitrogen through said second mass at a temperature in the range of 50° C. to 85° C. to extract away said second residual water solution to leave behind a third mass having water solution content less than 0.5 wt %; and
vii. agitating said third mass in a high-speed mixer together with a neutralizing agent, and optionally with a stabilizer and a processing additive to obtain dry thermally stable chlorinated polyvinyl chloride having thermal stability in the range of 1000 seconds to 1500 seconds.

2. The process as claimed in claim 1 , wherein said process step (vii) of agitating said third mass with a neutralizing agent, and optionally with a stabilizer and a processing additive causes the residual chlorine gas and residual hydrogen chloride to be released from said third mass.

3. The process as claimed in claim 1 , wherein said process further comprises the step of removing air from the air tight vessel before the step of introducing the chlorine gas.

4. The process as claimed in claim 1 , wherein the step of introducing the chlorine gas is carried out at a mass flow rate in the range of 0.05 kg/hour to 0.4 kg/hour.

5. The process as claimed in claim 1 , wherein said step of irradiation is carried out using a source of irradiation having output in the range of 1 watt/kg to 6 watt/kg of polyvinyl chloride.

6. The process as claimed in claim 1 , wherein said reaction mixture is irradiated using LED as a source of irradiation.

7. The process as claimed in claim 1 , wherein the amount of water present in said first mass is in the range of 10% to 60% by weight.

8. The process as claimed in claim 1 , wherein:
said neutralizing agent is calcium hydroxide,
said stabilizer is synthetic hydrotalcite; and
said processing additive is a copolymer with acidic groups.

9. The process as claimed in claim 1 , wherein:
the amount of said neutralizing agent is in the range of 1000 ppm to 6000 ppm,
the amount of said stabilizer is in the range of 1000 ppm to 2000 ppm; and
the amount of said processing additive is in the range of 500 ppm to 1000 ppm.

10. The process as claimed in claim 1 , wherein said dry chlorinated polyvinyl chloride is characterized with chlorine content in the range of 65 wt % to 70 wt %.

11. An article prepared from said dry chlorinated polyvinyl chloride as claimed in claim 1 .

Assignees

• Reliance Industries Ltd

Inventors

• Munshi Pradip
• Ingle Ninad Deepak
• Agrawal Santosh
• Maity Uttam
• Jasra Rakshvir
• Peter Sunil
• Singh Vriti
• Shah Vishal Bhupendrakumar
• Goyal Gordhan Das

Classifications

• C08F6/02

  Neutralisation of the polymerisation mass, e.g. killing the catalyst (short-stopping C08F2/42 ){also removal of catalyst residues} · CPC title

• C08L101/08

  Carboxyl groups · CPC title

• C08K2003/2206

  of calcium, strontium or barium · CPC title

• C08L27/24

  halogenated · CPC title

• C08F114/06 Primary

  Vinyl chloride · CPC title