Process for the preparation of catalyst components for the polymerization of olefins

Patent metadata

Field	Value
Publication number	US-11267907-B2
Application number	US-201816647766-A
Country	US
Kind code	B2
Filing date	Sep 7, 2018
Priority date	Sep 15, 2017
Publication date	Mar 8, 2022
Grant date	Mar 8, 2022

Abstract

A process for the preparation of a solid catalyst component for the polymerization of CH2═CHR olefins, wherein R is hydrogen or hydrocarbyl radical with 1-12 carbon atoms, made from or containing a Ti compound on a Mg chloride based support, including the steps of (a) reacting a Mg based compound with a liquid medium made from or containing a Ti compound, at a temperature ranging from 0 to 150° C., thereby yielding solid particles; and (b) suspending the solid particles coming from step (a) in a liquid medium made from or containing hydrocarbons at a temperature ranging from 10 to 100° C., wherein step (a) or (b) is carried out in the presence of 0.2 to 20.0% by weight, with respect to the amount of Mg compound, of particles of a solid compound containing more than 50% by weight of SiO2 units and having average particle size from 1 to 100 μm.

First claim

What is claimed is:

1. A process for the preparation of a solid catalyst component for the homopolymerization or copolymerization of CH 2 ═CHR olefins, wherein R is hydrogen or hydrocarbyl radical with 1-12 carbon atoms, comprising a Ti compound and optionally an electron donor on a Mg chloride based support, comprising the steps of:
(a) reacting a Mg based compound of formula (MgCl m X 2-m )·nLB, wherein m ranges from 0 to 2, n ranges from 0 to 6, X is, independently halogen, R 1 , OR 1 , —OCOR 1 or O—C(O)—OR 1 group, wherein R 1 is a C 1 -C 20 hydrocarbon group, and LB is a Lewis base, with a liquid medium comprising a Ti compound, having at least a Ti—Cl bond, in an amount such that the Ti/Mg molar ratio is greater than 3, carried out at a temperature ranging from 0 to 150° C., thereby yielding solid particles; and
(b) suspending the solid particles coming from step (a) in a liquid medium comprising a hydrocarbon at a temperature ranging from 10 to 100° C.,
wherein step (a) or step (b) is carried out in the presence of 0.2 to 20.0% by weight, with respect to the amount of Mg compound, of particles of a solid compound containing more than 50% by weight of SiO 2 units and having average particle size ranging from 1 to 100 μm.

2. The process of claim 1 , wherein the solid compound containing more than 50% by weight of SiO 2 units has average particle size ranging from 1 to 30 μm.

3. The process of claim 1 , wherein the solid compound containing more than 50% by weight of SiO 2 units is selected from the group consisting of silica, silicates and diatomaceous earth.

4. The process according to claim 1 , wherein the solid compound containing more than 50% by weight of SiO 2 units is diatomaceous earth.

5. The process according to claim 1 , wherein the solid compound containing more than 50% by weight of SiO 2 units is talc.

6. The process according to claim 1 , wherein the amount of solid compound containing more than 50% by weight of SiO 2 units ranges from 0.5 to 10% by weight with respect to the amount of Mg compound in step (a).

7. The process according to claim 1 , wherein the Mg based compound in step (a) is selected among adducts of the formula MgCl 2 .nR 1 OH, where n is a number between 0.1 and 6, and R 1 is a hydrocarbon radical having 1-18 carbon atoms.

8. The process according to claim 7 , wherein n ranges from 1 to 5 and R 1 is ethyl.

9. The process according to claim 1 , wherein the reaction temperature is from 60 to 140° C.

10. The process of claim 1 , wherein the number of steps (a) is between 1 and 4.

11. The process of claim 1 , wherein the solid compound containing more than 50% by weight of SiO 2 units is present in step (a).

12. The process of claim 1 , wherein the components present during reaction step (a) further comprise an internal electron donor compound selected from the group consisting of alkyl and aryl esters of optionally substituted aromatic polycarboxylic acids, esters of malonic acids, esters of glutaric acids, esters of maleic acids, esters of succinic acids, diol derivatives chosen from dicarbamates, monoesters monocarbamates and monoesters monocarbonates, and 1,3-diethers of the formula:

wherein R, R I , R II , R III , R IV and R V are the same or different from each other, and are hydrogen or hydrocarbon radicals having from 1 to 18 carbon atoms, and R VI and R VII are the same or different from each other, and have the same meaning of R-R V except that R VI and R VII are not hydrogen.

13. The process according to claim 12 , wherein the internal donor is introduced to the liquid medium in at least a first step (a).

14. The process according to claim 1 , wherein the solid compound containing more than 50% by weight of SiO 2 units is added in step (b).

15. The process of claim 14 , wherein the solid compound containing more than 50% by weight of SiO 2 units is diatomaceous earth.

16. The process of claim 12 , wherein one or more of the R-R VII groups are linked to form a cycle.

Assignees

• Basell Poliolefine Italia Srl

Inventors

• Brita Diego
• Arich De Finetti Nicolo
• Fusco Ofelia
• Gaddi Benedetta

Classifications

• C08F4/6545

  and metals of C08F4/64 or compounds thereof · CPC title

• C08F4/022

  Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts · CPC title

• C08F110/06 Primary

  Propene · CPC title

• C08F10/06

  Propene · CPC title

• C08F4/025

  Metal oxides · CPC title