Method and an apparatus for washing a crude lignin, a soluble carbohydrate containing fraction, a solid fraction and their use

Patent metadata

Field	Value
Publication number	US-11267837-B2
Application number	US-201615577481-A
Country	US
Kind code	B2
Filing date	May 26, 2016
Priority date	May 29, 2015
Publication date	Mar 8, 2022
Grant date	Mar 8, 2022

Abstract

The invention relates to a method and an apparatus for washing a crude lignin slurry (5) formed from plant based raw material, wherein the method comprises separating a soluble carbohydrate containing fraction (10) from the crude lignin slurry (5) by using displacement washing in at least one solid-liquid separation stage (6) so that the crude lignin slurry is prepressed, washed and pressed, and recovering a solid fraction (11) and the soluble carbohydrate containing fraction (10). Further, the invention relates to the soluble carbohydrate containing fraction and the solid fraction, and their uses.

First claim

The invention claimed is:

1. A method for washing a crude lignin slurry, wherein the method comprises:
forming a crude lignin slurry by processing lignocellulose material formed from plant based raw material using enzymatic hydrolysis;
feeding the crude lignin slurry to at least one solid-liquid separation stage comprising at least one pressure filtration device;
separating a soluble carbohydrate containing fraction from the crude lignin slurry using displacement washing in the pressure filtration device, the displacement washing including prepressing, washing, and pressing of the crude lignin slurry in connection with the separation of the soluble carbohydrate containing fraction from the crude lignin slurry, the ratio of the washing water to solids in the displacement washing being 0.5:1-6:1 (w/w) and the pressure being kept during the washing; and
recovering a solid fraction and the soluble carbohydrate containing fraction.

2. The method according to claim 1 , wherein the hydrolysis is a cellulose hydrolysis.

3. The method according to claim 1 , wherein the crude lignin slurry has been further processed via an acid treatment.

4. The method according to claim 1 , wherein the soluble carbohydrate containing fraction is separated from the crude lignin slurry using filtration, centrifugal treatment or their combinations.

5. The method according to claim 1 , wherein the solid-liquid separation stage comprises a filtration in which the filtration is carried out by pressure or overpressure.

6. The method according to claim 1 , wherein the pressure is increased step by step or gradually in the feeding to the solid-liquid separation stage.

7. The method according to claim 1 , wherein the prepressing is performed in the presence of pressure which is between 4-10 bar.

8. The method according to claim 1 , wherein the pressure of the prepressing is similar or higher than pressure in the feeding.

9. The method according to claim 1 , wherein the pressure of the pressing is similar or higher than the pressure of the prepressing.

10. The method according to claim 1 , wherein the total soluble concentrate of the soluble carbohydrate containing fraction is between 20 to 280 g/l.

11. The method according to claim 1 , wherein dry matter content of the solid fraction is 30-60% by weight.

12. The method according to claim 1 , wherein the solid-liquid separation stage comprises more than one separation steps.

13. The method according to claim 1 , wherein the plant based raw material is wood based material or a mixture comprising wood based material.

14. The method of claim 1 , wherein a soluble carbohydrate containing fraction is obtained.

15. The method of claim 1 , wherein the solid fraction is obtained.

16. The method of claim 14 , wherein the soluble carbohydrate containing fraction is usable as a source material in fermentation, hydrolysis, catalytic process, polymerization process, enzymatic process, manufacture of binder, manufacture of feed, manufacture of food or their combination.

17. The method of claim 15 , wherein the solid fraction is usable as a source material in hydrolysis, polymerization process, manufacture of a composite material, manufacture of binder, manufacture of feed, manufacture of food, combustion process or their combination.

Assignees

• Upm Kymmene Corp

Inventors

• Turunen Sami
• Tamper Juha

Classifications

• C07G1/00 Primary

  Low-molecular-weight derivatives of lignin (high-molecular-weight derivatives of lignin {C08H6/00}) · CPC title

• D21C11/02

  of {acid, neutral or alkaline} sulfite lye · CPC title

• B01J8/00

  Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes · CPC title

• C07H1/08

  from natural products · CPC title

• C08H6/00

  Macromolecular compounds derived from lignin, e.g. tannins, humic acids · CPC title