Method for producing carbon nanotube dispersion with improved workability

Patent metadata

Field	Value
Publication number	US-11267710-B2
Application number	US-201816331796-A
Country	US
Kind code	B2
Filing date	Jan 5, 2018
Priority date	Jan 5, 2017
Publication date	Mar 8, 2022
Grant date	Mar 8, 2022

Abstract

In the present invention, by dry pulverizing carbon nanotubes to control wettability index of the carbon nanotubes, the maximum concentration of the carbon nanotubes that can be added to the dispersion solvent can be increased and the workability of the carbon nanotube dispersion can be improved. Further, from this, it is possible to more easily predict the maximum concentration of the carbon nanotubes that can be added to the dispersion solvent.

First claim

What is claimed is:

1. A carbon nanotube dispersion in which dry-pulverized carbon nanotubes having a wettability index of 14 or less as defined by Formula 1 are dispersed in a solvent in an amount of 2 wt % or more based on a total weight of the dispersion:
Wettability index=(mass of absorbed solvent/mass of carbon nanotubes)  [Formula 1]

wherein, the mass of absorbed solvent is a mass of the solvent absorbed to a maximum extent, where the carbon nanotubes no longer absorb the solvent, by the dry-pulverized carbon nanotubes at ambient temperature, and
wherein the dry-pulverized carbon nanotubes have a bulk density of 65.1 kg/m 3 or greater.

2. The carbon nanotube dispersion according to claim 1 , wherein a viscosity of the dispersion is 40,000 cP or less.

3. The carbon nanotube dispersion according to claim 1 , wherein the dispersion comprises one or more dispersion media selected from one or more of: water, methanol, ethanol, propanol, acetone, dimethylformamide (DMF), dimethylacetamide, dimethyl sulfoxide (DMSO) or N-methylpyrrolidone (NMP).

4. A method for producing a carbon nanotube dispersion comprising the steps of:
dry pulverizing carbon nanotubes in a milling apparatus including metal or ceramic balls in order to produce dry-pulverized carbon nanotubes having a wettability index reduced by 3 or more compared to the wettability index of the carbon nanotubes before the dry pulverizing, wherein the wettability index is defined by Formula 1:
Wettability index=(mass of absorbed solvent/mass of carbon nanotubes)  [Formula 1]

wherein, the mass of absorbed solvent is a mass of the solvent absorbed to a maximum extent, where the carbon nanotubes no longer absorb the solvent, by the dry-pulverized carbon nanotubes at ambient temperature; and
dispersing the dry-pulverized carbon nanotubes in a solvent.

5. The method for producing the carbon nanotube dispersion according to claim 4 , wherein the carbon nanotubes have a BET specific surface area of 100 to 300 m 2 /g and a length of 5 to 100 μm before the dry pulverizing.

6. The method for producing the carbon nanotube dispersion according to claim 4 , wherein the carbon nanotubes have a length of 0.2 to 10 μm after the dry pulverizing.

7. The method for producing the carbon nanotube dispersion according to claim 4 , wherein the metal or ceramic balls are one kind of balls having a diameter of 1 mm to 10 mm, or a combination of two or more kinds of balls having different diameters of 1 mm to 10 mm.

8. The method for producing the carbon nanotube dispersion according to claim 4 , wherein the milling apparatus is selected from: a ball mill, a planetary ball mill or an attrition mill.

9. The method for producing the carbon nanotube dispersion according to claim 4 , wherein the length of the carbon nanotubes after the dry pulverizing step is reduced to 1/10 or less.

10. The method for producing the carbon nanotube dispersion according to claim 4 , wherein the specific surface area of the carbon nanotubes after the dry pulverizing step is increased by 5% to 100%.

11. The method for producing the carbon nanotube dispersion according to claim 4 , wherein the bulk density of the carbon nanotubes after the dry pulverizing step is increased by 5% to 1000%.

12. The method for producing the carbon nanotube dispersion according to claim 4 , wherein in the step of dry pulverizing by the milling apparatus, a milling speed is 100 rpm to 1,200 rpm.

13. The method for producing the carbon nanotube dispersion according to claim 4 , wherein the dry pulverizing step is performed for 5 minutes to 24 hours.

14. The method for producing the carbon nanotube dispersion according to claim 4 , wherein the carbon nanotubes have a bulk density of 65.1-119.1 kg/m 3 .

15. The method for producing the carbon nanotube dispersion according to claim 4 , wherein the metal or ceramic balls are one kind of balls having a diameter of 1 mm to 10 mm, or a combination of two or more kinds of balls having different diameters of 1 mm to 10 mm;
wherein the balls and the carbon nanotubes are added to the milling apparatus in a weight ratio of 1:10 to 1:200;
wherein the milling apparatus is operated at 100 to 1,200 rpm; and
wherein the dry pulverizing is performed for 5 minutes to 24 hours.

16. The method for producing the carbon nanotube dispersion according to claim 4 , wherein dry pulverizing is performed in the milling apparatus at 400 to 600 rpm, for 60 to 90 minutes, using balls having a diameter of 1 to 3 mm.

17. The method for producing the carbon nanotube dispersion according to claim 4 , wherein dry pulverizing is performed in the milling apparatus at 200 to 400 rpm, for 90 to 120 minutes, using a combination of balls having a diameter of 1 to 3 mm and balls having a diameter of 4 to 6 mm.

Assignees

• Lg Chemical Ltd

Inventors

• Yoon Jae Keun
• Cho Dong Hyun
• Kim Sung Jin
• Kang Kyung Yeon

Classifications

• C01B32/176

  Cutting · CPC title

• C01B32/158

  Carbon nanotubes · CPC title

• C01B32/174 Primary

  Derivatisation; Solubilisation; Dispersion in solvents · CPC title

• C01B2202/34

  Length · CPC title

• C01B2202/26

  Mechanical properties · CPC title