Process for reducing the hydrogen sulphide content in non-gaseous sulphur compositions using a zinc-based scavenger

Patent metadata

Field	Value
Publication number	US-11267705-B2
Application number	US-201716319610-A
Country	US
Kind code	B2
Filing date	Jul 20, 2017
Priority date	Jul 22, 2016
Publication date	Mar 8, 2022
Grant date	Mar 8, 2022

Abstract

A process for reducing the hydrogen sulphide content in a composition containing or consisting of hydrogen sulphide and non-gaseous elemental sulphur, comprising contacting the composition with a scavenger, wherein the scavenger is chosen from the group consisting of zinc oxide, zinc carbonate, zinc hydroxy carbonate or a combination of two or more of these.

First claim

That which is claimed is:

1. A process for reducing the hydrogen sulphide content in a composition containing hydrogen sulphide and non-gaseous elemental sulphur, comprising contacting the composition with a scavenger, wherein the scavenger is chosen from the group consisting of zinc oxide, zinc carbonate, zinc hydroxy carbonate or a combination of two or more of these.

2. The process including the step of contacting a composition containing or consisting of hydrogen sulphide and non-gaseous elemental sulphur with one or more scavenger(s), wherein the composition contains more than 10 ppmw and less than 10000 ppmw hydrogen sulphide based on the total weight of the composition, and wherein the one or more scavenger(s) are chosen from the group consisting of zinc carbonate, zinc hydroxy carbonate and mixtures thereof.

3. The process according to claim 1 , wherein the composition containing or consisting of hydrogen sulphide and non-gaseous elemental sulphur is a composition containing or consisting of hydrogen sulphide and liquid elemental sulphur.

4. The process according to claim 3 , wherein the composition contains between equal to or more than 99.000 wt. % and equal to or less than 99.999 wt. % of liquid elemental sulphur and between equal to or more than 10 ppmw and equal to or less than 10000 ppmw of hydrogen sulphide, based on the total weight of the composition.

5. The process according to claim 1 , wherein the scavenger is a zinc hydroxy carbonate.

6. The process according to claim 1 , wherein the scavenger is contacted with the composition in an amount of equal to or more than 0.005 wt. % and equal to or less than 0.5 wt. % scavenger based on the total weight of the composition.

7. The process according to claim 1 , wherein the weight ratio of the scavenger to hydrogen sulphide is equal to or more than 0.01 to 1 (0.01:1) and equal to or less than 100 to 1 (100:1).

8. The process according to claim 1 , wherein the process comprises:
a step comprising mixing the scavenger and a composition containing hydrogen sulphide and solid elemental sulphur to form a mixture containing hydrogen sulphide, solid elemental sulphur and scavenger;
a subsequent step comprising melting the mixture containing hydrogen sulphide, solid elemental sulphur and scavenger to form a mixture containing hydrogen sulphide, liquid elemental sulphur and scavenger.

9. The process according to claim 1 , wherein the process comprises:
a step comprising melting a composition containing hydrogen sulphide and solid elemental sulphur to form a composition containing hydrogen sulphide and liquid elemental sulphur; and
a subsequent step comprising mixing the scavenger and the composition containing hydrogen sulphide and liquid elemental sulphur to form a mixture containing hydrogen sulphide, liquid elemental sulphur and scavenger.

10. The process according to claim 1 , wherein the scavenger is deposited on a solid carrier.

11. The process according to claim 1 , wherein the composition containing or consisting of hydrogen sulphide and non-gaseous elemental sulphur is added to the scavenger and the composition and scavenger are mixed.

12. The process according to claim 1 , wherein the process is a batch-wise or semi-batchwise process and the scavenger is mixed with the composition by means of the agitation associated with transport from a first location to a second location.

13. The process according to claim 1 , thereby forming a product composition.

14. The process according to claim 13 , wherein the product composition is directly or indirectly at least partly solidified into solid elemental sulphur.

15. The mixture comprising non-gaseous elemental sulphur and zinc hydroxy carbonate.

Assignees

• Shell Oil Co

Inventors

• Davies Helen Jayne
• D'Melo Dawid John
• Lambert Reginald

Classifications

• C01B17/0243

  Other after-treatment of sulfur · CPC title

• C01G9/00

  Compounds of zinc · CPC title

• C01G9/08

  Sulfides · CPC title

• C01B17/0232 Primary

  Purification, e.g. degassing · CPC title