Glass-resin multicomposite reinforcement with improved properties
US-2018009264-A1 · Jan 11, 2018 · US
US11267287B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11267287-B2 |
| Application number | US-201716337106-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 25, 2017 |
| Priority date | Sep 27, 2016 |
| Publication date | Mar 8, 2022 |
| Grant date | Mar 8, 2022 |
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A non-pneumatic elastic wheel (30) defining three perpendicular directions, circumferential (X), axial (Y) and radial (Z), comprises at least: —a hub (31), for example made of metal; an annular band referred to as a shear band (32) oriented in the circumferential direction (X), surmounted by a tread (33); and a plurality of support elements (34) connecting the hub (31) to the annular shear band (32). The annular shear band (32) is formed by a laminate comprising at least one layer of silicone rubber, in particular of the high temperature crosslinking type, such as, for example, a silicone rubber of VMQ or PVMQ grade, the said layer being sandwiched between two layers of fibre-resin composite comprising filaments of an inorganic substance, in particular glass, embedded in a thermoset resin such as, for example, a vinyl ester resin.
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The invention claimed is: 1. A non-pneumatic elastic wheel defining three perpendicular directions, the perpendicular directions being circumferential X, axial Y and radial Z, the wheel comprising: a hub; an annular shear band oriented in the circumferential direction X, surmounted by a tread; and a plurality of support elements connecting the hub to the annular shear band, wherein the annular shear band is formed by a laminate comprising at least one silicone rubber layer sandwiched between two fiber-resin composite layers comprising glass filaments embedded in a thermoset resin, and wherein the silicone rubber layer and the fiber-resin composite layers are joined together by at least one adhesion primer. 2. The non-pneumatic elastic wheel according to claim 1 , wherein the silicone rubber layer has a thickness T 1 which is greater than the thickness T 2 of each fiber-resin composite layer. 3. The non-pneumatic elastic wheel according to claim 2 , wherein the silicone rubber layer has a thickness T 1 of between 1.5 and 3 times the thickness T 2 of each fiber-resin composite layer. 4. The non-pneumatic elastic wheel according to claim 1 , wherein T 1 is between 1 and 3 mm. 5. The non-pneumatic elastic wheel according to claim 4 , wherein T 1 is between 1.5 and 2.5 mm. 6. The non-pneumatic elastic wheel according to claim 1 , wherein T 2 is between 0.25 and 2 mm. 7. The non-pneumatic elastic wheel according to claim 6 , wherein T 2 is between 0.5 and 1.5 mm. 8. The non-pneumatic elastic wheel according to claim 1 comprising at least two layers of silicone rubber and three layers of fiber-resin composite. 9. The non-pneumatic elastic wheel according to claim 1 , wherein the adhesion primer is based on an organosilane or organopolysiloxane. 10. The non-pneumatic elastic wheel according to claim 1 , wherein the silicone rubber exhibits an apparent secant tensile modulus, at 10% elongation, measured at 20° C., which is less than 5 MPa. 11. The non-pneumatic elastic wheel according to claim 10 , wherein the silicone rubber exhibits an apparent secant tensile modulus, at 10% elongation, measured at 20° C., which is between 1 and 5 MPa. 12. The non-pneumatic elastic wheel according to claim 11 , wherein the silicone rubber exhibits an apparent secant tensile modulus, at 10% elongation, measured at 20° C., which is between 1 and 3 MPa. 13. The non-pneumatic elastic wheel according to claim 1 , wherein the silicone rubber exhibits a tensile elongation at break, measured at 20° C., which is greater than 350%. 14. The non-pneumatic elastic wheel according to claim 13 , wherein the silicone rubber exhibits a tensile elongation at break, measured at 20° C., which is greater than 400%. 15. The non-pneumatic elastic wheel according to claim 14 , wherein the silicone rubber exhibits a tensile elongation at break, measured at 20° C., which is greater than 450%. 16. The non-pneumatic elastic wheel according to claim 1 , wherein the silicone rubber is of the high temperature crosslinking type. 17. The non-pneumatic elastic wheel according to claim 1 , wherein the silicone rubber is of a grade selected from the group consisting of MQ, FMQ, PMQ, VMQ, PVMQ and FVMQ. 18. The non-pneumatic elastic wheel according to claim 17 , wherein the silicone rubber is of VMQ or PVMQ grade. 19. The non-pneumatic elastic wheel according to claim 18 , wherein the silicone rubber is of PVMQ grade. 20. The non-pneumatic elastic wheel according to claim 1 , wherein the silicone rubber exhibits a glass transition temperature Tg 1 which is less than −100° C. 21. The non-pneumatic elastic wheel according to claim 20 , wherein the silicone rubber exhibits a glass transition temperature Tg 1 which is less than −110° C. 22. The non-pneumatic elastic wheel according to claim 20 , wherein the silicone rubber exhibits an apparent secant tensile modulus, at 10% elongation ASM10, measured at −100° C., which is less than 30 MPa. 23. The non-pneumatic elastic wheel according to claim 22 , wherein the silicone rubber exhibits an apparent secant tensile modulus, at 10% elongation ASM10, measured at −100° C., which is less than 20 MPa. 24. The non-pneumatic elastic wheel according to claim 20 , wherein the silicone rubber exhibits an elongation at break Et, measured at −100° C., which is greater than 100%. 25. The non-pneumatic elastic wheel according to claim 24 , wherein the silicone rubber exhibits an elongation at break Et, measured at −100° C., which is greater than 150%. 26. The non-pneumatic elastic wheel according to claim 1 , wherein the silicone rubber is a composition based on silicone rubber and on at least one additive. 27. The non-pneumatic elastic wheel according to claim 26 , wherein the additive is a crosslinking agent. 28. The non-pneumatic elastic wheel according to claim 27 , wherein the additive is an organic peroxide type crosslinking agent. 29. The non-pneumatic elastic wheel according to claim 26 , wherein the additive is a filler. 30. The non-pneumatic elastic wheel according to claim 29 , wherein the additive is a silica type filler. 31. The non-pneumatic elastic wheel according to claim 1 , wherein the glass transition temperature Tg 2 of the thermoset resin is greater than 30° C. 32. The non-pneumatic elastic wheel according to claim 31 , wherein the glass transition temperature Tg 2 of the thermoset resin is greater than 70° C. 33. The non-pneumatic elastic wheel according to claim 1 , wherein the silicone rubber layer comprises 100 phr of silicone elastomer.
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