Organic light-emitting device

Patent metadata

Field	Value
Publication number	US-11264583-B2
Application number	US-202016852171-A
Country	US
Kind code	B2
Filing date	Apr 17, 2020
Priority date	Oct 28, 2015
Publication date	Mar 1, 2022
Grant date	Mar 1, 2022

Abstract

An organic light-emitting device comprising: a first electrode; a second electrode facing the first electrode; a first emission unit, a second emission unit and a third emission unit between the first electrode and the second electrode; a first charge generation layer between the first emission unit and the second emission unit; and a second charge generation layer between the second emission unit and the third emission unit, wherein the first emission unit comprises a first emission layer, the second emission unit comprises a second emission layer, the third emission unit comprises a third emission layer, and at least one of the first emission unit, the second emission unit and the third emission unit comprises an inorganic buffer layer.

First claim

What is claimed is:

1. An organic light-emitting device comprising:
a first electrode;
a second electrode facing the first electrode;
a first emission unit, a second emission unit and a third emission unit between the first electrode and the second electrode;
a first charge generation layer between the first emission unit and the second emission unit; and
a second charge generation layer between the second emission unit and the third emission unit,
wherein the first emission unit comprises a first emission layer,
the second emission unit comprises a second emission layer,
the third emission unit comprises a third emission layer, and
at least one of the first emission unit, the second emission unit and the third emission unit comprises an inorganic buffer layer.

2. The organic light-emitting device of claim 1 , wherein the third emission unit comprises the inorganic buffer layer.

3. The organic light-emitting device of claim 1 , wherein the third emission unit comprises a metal halide.

4. The organic light-emitting device of claim 3 , wherein the metal halide is included in an inorganic buffer layer in the third emission unit.

5. The organic light-emitting device of claim 3 , wherein the metal halide comprises at least one iodide compound selected from the group consisting of an alkali metal iodide, an alkaline earth metal iodide, a transition metal iodide, a post-transition metal iodide, and a lanthanum-based metal iodide.

6. The organic light-emitting device of claim 3 , wherein the metal halide comprises at least one iodide compound selected from the group consisting of a lithium (Li) iodide, a sodium (Na) iodide, a potassium (K) iodide, a rubidium (Rb) iodide, a cesium (Cs) iodide, a beryllium (Be) iodide, a magnesium (Mg) iodide, a calcium (Ca) iodide, a strontium (Sr) iodide, a barium (Ba) iodide, a ytterbium (Yb) iodide, a samarium (Sm) iodide, a copper (Cu) iodide, a thallium (Tl) iodide, a silver (Ag) iodide, a cadmium (Cd) iodide, a mercury (Hg) iodide, a tin (Sn) iodide, a lead (Pb) iodide, a bismuth (Bi) iodide, a zinc (Zn) iodide, a manganese (Mn) iodide, an iron (Fe) iodide, a cobalt (Co) iodide, a nickel (Ni) iodide, an aluminum (Al) iodide, an indium (In) iodide, a gallium (Ga) iodide, a thorium (Th) iodide, and a uranium (U) iodide.

7. The organic light-emitting device of claim 3 , wherein the metal halide comprises at least one iodide compound selected from the group consisting of LiI, NaI, Kl, RbI, CsI, BeI 2 , MgI 2 , CaI 2 , SrI 2 , BaI 2 , YbI, YbI 2 , YbI 3 , SmI 3 , CuI, TlI, AgI, CdI 2 , HgI 2 , SnI 2 , PbI 2 , BiI 3 , ZnI 2 , MnI 2 , FeI 2 , CoI 2 , NiI 2 , AlI 3 , InI 3 , GaI 3 , ThI 4 , and UI 3 .

8. The organic light-emitting device of claim 1 , wherein the inorganic buffer layer has a thickness of 1 nm to 20 nm.

9. An organic light-emitting device comprising:
a first electrode;
a second electrode facing the first electrode; and
a first emission unit and a second emission unit between the first electrode and the second electrode,
wherein the first emission unit is arranged toward the first electrode,
the second emission unit is arranged toward the second electrode,
the first emission unit comprises a first emission layer,
the second emission unit comprises a second emission layer, and
the first emission unit and the second emission unit each comprise a metal halide.

10. The organic light-emitting device of claim 9 , wherein the metal halide is included in a first inorganic buffer layer in the first emission unit and a second inorganic buffer layer in the second emission unit.

11. The organic light-emitting device of claim 10 , wherein:
the first inorganic buffer layer is included in a first hole transport region between the first emission layer and the first electrode, and
the second inorganic buffer layer is included in a second hole transport region between the second emission layer and the first emission unit.

12. The organic light-emitting device of claim 11 , wherein:
the first inorganic buffer layer is directly in contact with the first emission layer, and
the second inorganic buffer layer is directly in contact with the second emission layer.

13. The organic light-emitting device of claim 10 , wherein the first inorganic buffer layer and the second inorganic buffer layer each further comprise at least one metal.

14. The organic light-emitting device of claim 10 , wherein the first inorganic buffer layer and the second inorganic buffer layer are each formed of the metal halide.

15. The organic light-emitting device of claim 9 , wherein the metal halide comprises at least one iodide compound selected from the group consisting of an alkali metal iodide, an alkaline earth metal iodide, a transition metal iodide, a post-transition metal iodide, and a lanthanum-based metal iodide.

16. The organic light-emitting device of claim 9 , wherein the metal halide comprises at least one iodide compound selected from the group consisting of a lithium (Li) iodide, a sodium (Na) iodide, a potassium (K) iodide, a rubidium (Rb) iodide, a cesium (Cs) iodide, a beryllium (Be) iodide, a magnesium (Mg) iodide, a calcium (Ca) iodide, a strontium (Sr) iodide, a barium (Ba) iodide, a ytterbium (Yb) iodide, a samarium (Sm) iodide, a copper (Cu) iodide, a thallium (Tl) iodide, a silver (Ag) iodide, a cadmium (Cd) iodide, a mercury (Hg) iodide, a tin (Sn) iodide, a lead (Pb) iodide, a bismuth (Bi) iodide, a zinc (Zn) iodide, a manganese (Mn) iodide, an iron (Fe) iodide, a cobalt (Co) iodide, a nickel (Ni) iodide, an aluminum (Al) iodide, an indium (In) iodide, a gallium (Ga) iodide, a thorium (Th) iodide, and a uranium (U) iodide.

17. The organic light-emitting device of claim 9 , wherein the metal halide comprises at least one iodide compound selected from the group consisting of LiI, NaI, Kl, RbI, CsI, BeI 2 , MgI 2 , CaI 2 , SrI 2 , BaI 2 , YbI, YbI 2 , YbI 3 , SmI 3 , CuI, TlI, AgI, CdI 2 , HgI 2 , SnI 2 , PbI 2 , BiI 3 , ZnI 2 , MnI 2 , FeI 2 , CoI 2 , NiI 2 , AlI 3 , InI 3 , GaI 3 , ThI 4 , and UI 3 .

18. The organic light-emitting device of claim 9 , further comprising a third emission unit between the second emission unit and the second electrode,
wherein the third emission unit comprises a third emission layer and a metal halide.

Assignees

• Samsung Display Co Ltd

Inventors

• Seo Dongkyu
• Kim Dongchan
• Kim Wonjong
• Kim Eungdo
• Lee Jihye
• Im Dahea
• Yim Sanghoon
• Cho Yoonhyeung
• Han Wonsuk

Classifications

• H10K50/181

  Electron blocking layers · CPC title

• H10K50/16

  Electron transporting layers · CPC title

• H10K50/17

  Carrier injection layers · CPC title

• H01L51/0071

  Electricity · mapped topic

• H01L51/0074

  Electricity · mapped topic