Ferritic stainless steel
US-2019177824-A1 · Jun 13, 2019 · US
US11261512B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11261512-B2 |
| Application number | US-201716325577-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 25, 2017 |
| Priority date | Sep 2, 2016 |
| Publication date | Mar 1, 2022 |
| Grant date | Mar 1, 2022 |
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Provided is ferritic stainless steel having excellent brazeability and excellent corrosion resistance to condensed water in an environment in which the steel is used for an exhaust heat recovery device or an EGR cooler.A ferritic stainless steel has a chemical composition containing, by mass %, C: 0.025% or less, Si: 0.40% to 2.0%, Mn: 0.05% to 1.5%, P: 0.05% or less, S: 0.01% or less, Cr: 16.0% to 30.0%, Mo: 0.60% to 3.0%, Ni: 0.10% to 2.5%, Nb: 0.20% to 0.80%, Al: 0.001% to 0.15%, N: 0.025% or less, and the balance being Fe and inevitable impurities, in which relational expressions (1) and (2) below are satisfied.C+N≤0.030% (1),2Si+Ni≥1.0% (2),(in relational expressions (1) and (2), C, N, Si, and Ni each denote the contents (mass %) of the corresponding elements).
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The invention claimed is: 1. A ferritic stainless steel having a chemical composition consisting of, by mass %, C: 0.025% or less, Si: 0.40% to 2.0%, Mn: 0.05% to 1.5%, P: 0.05% or less, S: 0.01% or less, Cr: 16.0% to 30.0%, Mo: 0.60% to 3.0%, Ni: 0.10% to 2.5%, Nb: 0.20% to 0.80%, Al: 0.001% to 0.025%, N: 0.025% or less, optionally, one, two, or more selected from: Cu: 0.01% to 1.0%, W: 0.01% to 1.0%, Co: 0.01% to 1.0%, Ti: 0.01% to 0.10%, V: 0.01% to 0.50%, Zr: 0.01% to 0.30%, B: 0.0003% to 0.005%, Ca: 0.0003% to 0.003%, Mg: 0.0003% to 0.003%, one or more REMs (rare earth metals): 0.001% to 0.10%, and the balance being Fe and inevitable impurities, wherein relational expressions (1) and (2) below are satisfied: C+N≤0.030% (1), 2Si+Ni≥1.0% (2), wherein in relational expressions (1) and (2), C, N, Si, and Ni each denote the contents by mass % of the corresponding elements, wherein when a brazing treatment is performed by applying 1.2 g of a brazing filler metal BNi-5 having a composition Ni-19Cr-10Si to one end surface of two overlapped steel sheets of the ferritic stainless steel and by heating the two overlapped steel sheets at a temperature of 1170° C. for 600 seconds in a vacuum environment of 10 −2 Pa, a penetration distance of the brazing filler metal is 50% or more of a lapping length of the two overlapped steel sheets, and wherein when a unit test cycle in which a whole test piece is subjected to full immersion in a solution containing 200 ppm Cl − +600 ppm SO 4 2− and having a pH of 8.0, holding at a temperature of 80° C., immersion for 24 hours while the solution is vaporized in 24 hours, and being held in a furnace at a temperature of 250° C. for 24 hours, is performed four times, a maximum corrosion depth is less than 100 μm. 2. The ferritic stainless steel according to claim 1 , wherein the steel is steel for an exhaust heat recovery device or exhaust gas recirculation device of an automobile.
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