Apparatus and method of preparing synthetic fuel using natural gas

Patent metadata

Field	Value
Publication number	US-11261390-B2
Application number	US-201816126404-A
Country	US
Kind code	B2
Filing date	Sep 10, 2018
Priority date	Sep 10, 2018
Publication date	Mar 1, 2022
Grant date	Mar 1, 2022

Abstract

Disclosed is an apparatus and method of preparing synthetic fuel using natural gas extracted from a stranded gas field on land or at sea as a raw material through a compact GTL process or a GTL-FPSO process. A parallel-type gas purification unit for controlling a molar ratio of synthetic gas and a concentration of carbon dioxide in the synthetic gas, in which a CO2 separation device and a bypass unit are disposed in parallel, is provided and, thus, the gas purification unit may prepare the synthetic gas by a steam carbon dioxide reforming (SCR) reaction using natural gas having different CO2 contents of various stranded gas fields and then supply the synthetic gas having an optimum composition suitable for a Fischer-Tropsch synthesis.

First claim

What is claimed is:

1. An apparatus for preparing synthetic fuel using natural gas, comprising:
a liquid separator configured to separate C 5 + condensate and oil from the natural gas supplied from a stranded gas field;
a desulfurizer configured to remove sulfur from C 1 -C 4 gas obtained by separating the C 5 + condensate and oil from the natural gas by the liquid separator;
a pre-reformer configured to convert higher hydrocarbons having 2 or more carbon atoms in desulfurized gas, obtained by the desulfurizer, into methane;
a reforming reactor configured to generate synthetic gas comprising hydrogen (H 2 ) and carbon monoxide (CO) through a Steam Carbon dioxide Reforming (SCR) reaction to reform methane using carbon dioxide and steam into hydrogen and carbon monoxide, after a pre-reforming process executed by the pre-reformer;
a Fischer-Tropsch synthesis reactor configured to generate the synthetic fuel from the synthetic gas generated by the reforming reactor through a Fischer-Tropsch synthesis reaction; and
a gas purification unit configured to control a H 2 /CO molar ratio of the synthetic gas and a concentration of carbon dioxide in the synthetic gas, and comprising a CO 2 separation device configured to separate and remove carbon dioxide from the synthetic gas and a bypass unit configured to divert a part of the synthetic gas so as not to pass through the CO 2 separation device, the CO 2 separation device and the bypass unit being disposed in parallel between the reforming reactor and the Fischer-Tropsch synthesis reactor,
wherein, in the gas purification unit,
the CO 2 separation device receives the synthetic gas supplied by the reforming reactor and transmits through a first supply line, selectively separates and removes carbon dioxide from the transmitted synthetic gas, and then supplies the synthetic gas comprising an adjusted amount of carbon dioxide to the Fischer-Tropsch synthesis reactor through a second supply line,
the bypass unit comprises a bypass line branching off from the first supply line and connected to the second supply line and diverts a part of the synthetic gas through the bypass line so as not to pass through the CO 2 separation device so that the diverted part of the synthetic gas is supplied to the Fischer-Tropsch synthesis reactor through the second supply line,
wherein the gas purification unit is configured to adjust the H2/CO molar ratio of the synthetic gas supplied from the reforming reactor to the Fischer-Tropsch synthesis reactor to 1.8-2.2,
wherein the gas purification unit further comprises a flow control unit to control flow rates of parts of the synthetic gas respectively distributed to the CO2 separation device and the bypass unit, and
wherein the gas purification unit is configured to adjust a concentration of carbon dioxide in the synthetic gas supplied to the Fischer-Tropsch synthesis reaction to 6-15 mol %.

2. The apparatus of claim 1 , wherein the CO 2 separation device is a PSA device configured to separate and remove carbon dioxide from the synthetic gas by selectively adsorbing carbon dioxide.

3. The apparatus of claim 2 , wherein a plurality of adsorbent beds of the PSA device has an emission line to emit carbon dioxide desorbed from an adsorbent so as to recover carbon dioxide.

4. The apparatus of claim 1 , wherein the CO 2 separation device of the gas purification unit is a CO 2 separation device executing an amine process to separate and remove carbon dioxide from the synthetic gas by selectively adsorbing carbon dioxide.

5. The apparatus of claim 1 , wherein the CO 2 separation device of the gas purification unit is a CO 2 separation device selectively separating and removing carbon dioxide from the synthetic gas using a membrane.

Assignees

• Korea Inst Sci & Tech

Inventors

• Moon Dong Ju
• Shin Seol-A
• Yang Eun Hyeok
• Noh Young-Su
• Hong Gihoon
• Park Ji In
• Jung Jae Sun

Classifications

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title

• C10L2290/542

  Adsorption of impurities during preparation or upgrading of a fuel · CPC title

• C01B2203/1647

  Controlling the amount of the product · CPC title

• C01B2203/043

  Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration · CPC title

• C10L2290/08

  Drying or removing water · CPC title