Thermoplastic resin and optical member

Patent metadata

Field	Value
Publication number	US-11261294-B2
Application number	US-201816638594-A
Country	US
Kind code	B2
Filing date	Jul 13, 2018
Priority date	Aug 30, 2017
Publication date	Mar 1, 2022
Grant date	Mar 1, 2022

Abstract

The purpose of the present invention is to provide a thermoplastic resin that has a high refractive index and enables low birefringence and balanced heat resistance and moldability. This thermosetting resin includes repeating units represented by formula (1). (In the formula, the rings Z are the same or different and represent an aromatic hydrocarbon ring, R 1 and R 2 independently represent a C1-C12 hydrocarbon group optionally including a hydrogen atom, a halogen atom, and an aromatic group, Ar 1 and Ar 2 represent a C6-C10 aromatic group optionally having a substituent, L 1 and L 2 independently represent a divalent linking group, j and k independently represent an integer of 0 or more, m and n independently represent 0 or 1, and W is at least one selected from the groups represented by formulae (2) and (3).) (In the formula, X represents a divalent linking group.)

First claim

The invention claimed is:

1. A thermoplastic resin that includes a repeating unit represented by the following formula (1):

wherein the rings Z represent (the same or different) aromatic hydrocarbon rings, R 1 and R 2 each independently represent a hydrogen atom, a halogen atom or a hydrocarbon group of 1 to 12 carbon atoms optionally containing an aromatic group, Ar 1 and Ar 2 represent an aromatic group of 6 to 10 carbon atoms optionally containing a substituent, L 1 and L 2 are ethylene groups, j and k each independently represent an integer of 0 or greater, m and n are 1, and W is at least one group selected from groups represented by the following formula (2) or (3):

wherein X represents a divalent linking group.

2. The thermoplastic resin according to claim 1 , wherein formula (1) is at least one selected from the group consisting of units represented by the following formulas (1a) to (1d):

wherein R 3 to R 10 each independently represent a hydrogen atom, a halogen atom or a hydrocarbon group of 1 to 12 carbon atoms optionally containing an aromatic group, Ar 1 and Ar 2 , L 1 and L 2 , j and k, m and n and W are the same as in formula (1) above.

3. The thermoplastic resin according to claim 2 , wherein formula (1) is at least one selected from the group consisting of units represented by formulas (1b) to (1d) above.

4. The thermoplastic resin according to claim 3 , wherein formula (1) is formula (1b).

5. The thermoplastic resin according to claim 1 , wherein Ar 1 and Ar 2 in formula (1) are phenyl groups.

6. The thermoplastic resin according to claim 1 , wherein Ar 1 and Ar 2 in formula (1) are naphthyl groups.

7. The thermoplastic resin according to claim 4 , wherein Ar 1 and Ar 2 in formula (1b) are phenyl groups, and R 3 to R 10 are hydrogen atoms.

8. The thermoplastic resin according to claim 1 , wherein X in formula (3) includes at least one selected from the group consisting of phenylene group, naphthalenediyl group, groups represented by the following formula (4) and groups represented by the following formula (5), as a repeating unit:

wherein R 11 and R 12 each independently represent a hydrogen atom, a hydrocarbon group of 1 to 12 carbon atoms optionally containing an aromatic group, or a halogen atom.

9. The thermoplastic resin according to claim 1 , which includes at least one selected from the group consisting of units represented by the following formulas (6) to (8), as a repeating unit:

wherein R 13 and R 14 each independently represent a hydrogen atom, a hydrocarbon group of 1 to 12 carbon atoms optionally containing an aromatic group, or a halogen atom,

wherein R 15 and R 16 each independently represent a hydrogen atom, a hydrocarbon group of 1 to 12 carbon atoms optionally containing an aromatic group, or a halogen atom,

wherein R 17 and R 18 each independently represent a hydrogen atom, a hydrocarbon group of 1 to 12 carbon atoms optionally containing an aromatic group, or a halogen atom, and Y is a single bond or a divalent linking group.

10. The thermoplastic resin according to claim 1 , wherein the relative viscosity is 0.12 to 0.40.

11. The thermoplastic resin according to claim 1 , wherein the glass transition temperature is 140 to 185° C.

12. The thermoplastic resin according to claim 1 , wherein the refractive index is 1.660 to 1.730.

13. An optical member comprising a thermoplastic resin according to claim 1 .

14. The optical member according to claim 13 , which is an optical lens.

Assignees

• Teijin Ltd

Inventors

• Yamada Kyosuke
• Matsui Manabu
• Yanagida Takatsune
• Ogasawara Kazuyoshi
• Nunome Kazunori
• Sato Keisuke
• Tomonari Yasuhiko

Classifications

• C08G64/08

  containing atoms other than carbon, hydrogen or oxygen · CPC title

• G02B13/002

  having at least one aspherical surface · CPC title

• C08L2203/20

  use in electrical or conductive gadgets · CPC title

• C08L2201/10

  Transparent films; Clear coatings; Transparent materials · CPC title

• C08L69/005

  Polyester-carbonates · CPC title