Optical fiber preforms with halogen doping

Patent metadata

Field	Value
Publication number	US-11261121-B2
Application number	US-201816165633-A
Country	US
Kind code	B2
Filing date	Oct 19, 2018
Priority date	Oct 20, 2017
Publication date	Mar 1, 2022
Grant date	Mar 1, 2022

Abstract

Preparation of halogen-doped silica is described. The preparation includes doping silica with high halogen concentration, sintering halogen-doped silica to a closed-pore state, and subjecting the closed-pore silica body to a thermal treatment process and/or a pressure treatment process. The temperature of thermal treatment is sufficiently high to facilitate reaction of unreacted doping precursor trapped in voids or interstices of the glass structure, but is below temperatures conducive to foaming. Core canes or fibers drawn from halogen-doped silica subjected to the thermal treatment and/or pressure treatment show improved optical quality and possess fewer defects. The thermal treatment and/or pressure treatment is particularly advantageous when used for silica doped with high concentrations of halogen.

First claim

What is claimed is:

1. A method of producing halogen-doped silica, the method comprising:
doping a silica soot body with a doping precursor, the doping precursor comprising a halogen and having a partial pressure greater than 2 atm, the doping occurring at a temperature between 1000° C. and 1500° C.; and
densifying the doped silica soot body to form a closed-pore silica body; the closed-pore silica body comprising silica doped with the halogen; and
exposing the closed-pore silica body to a gas for a time period of at least 1.0 hour, the gas having a pressure of at least 2.0 atm; and
after the exposing, redrawing the closed-pore silica body, the redrawing comprising heating the closed-pore silica body and reducing a diameter of the closed-pore silica body.

2. The method of claim 1 , wherein the gas has a pressure of at least 5.0 atm.

3. The method of claim 1 , wherein the gas has a pressure of at least 20.0 atm.

4. The method of claim 1 , wherein the halogen comprises chlorine.

5. The method of claim 4 , wherein the concentration of chlorine in the closed-pore silica body is at least 2.0 wt %.

6. The method of claim 1 , wherein the halogen comprises bromine.

7. The method of claim 6 , wherein the concentration of bromine in the closed-pore silica body is at least 2.0 wt %.

8. The method of claim 1 , wherein the closed-pore silica body comprises unreacted doping precursor, the unreacted doping precursor comprising the halogen and occupying a void or interstice of the closed-pore silica body and wherein the exposing the closed-pore silica body to a gas induces a reaction of the unreacted doping precursor with the closed-pore silica body.

9. The method of claim 1 , wherein the gas has a pressure of at least 100 atm.

10. The method of claim 1 , wherein the gas has a pressure of at least 175 atm.

11. The method of claim 1 , wherein the gas is Ar, N 2 , O 2 , Cl 2 , or combination thereof.

12. A method of producing halogen-doped silica comprising:
doping a silica soot body with a doping precursor, the doping precursor comprising a halogen and having a partial pressure greater than 2 atm, the doping occurring at a temperature between 1000° C. and 1500° C.;
densifying the doped silica soot body to form a closed-pore silica body; the closed-pore silica body comprising silica doped with the halogen; and
heating the closed-pore silica body at a temperature in the range from 1000° C.-1500° C. for a time period of at least 1.0 hour.

13. The method of claim 12 , wherein the halogen comprises chlorine.

14. The method of claim 13 , wherein the concentration of chlorine in the closed-pore silica body is at least 2.0 wt %.

15. The method of claim 12 , wherein the halogen comprises bromine.

16. The method of claim 15 , wherein the concentration of bromine in the closed-pore silica body is at least 1.0 wt %.

17. The method of claim 12 , wherein the time period is at least 4.0 hours.

18. The method of claim 12 , wherein the closed-pore silica body comprises unreacted doping precursor, the unreacted doping precursor comprising the halogen and occupying a void or interstice of the closed-pore silica body and wherein the heating the closed-pore silica body induces a reaction of the unreacted doping precursor with the closed-pore silica body.

19. The method of claim 12 , further comprising thermal processing of the closed-pore silica body, the thermal processing comprising subjecting the closed-pore silica body to a temperature in the range from 1300° C.-1600° C. for a time period of at least 1.0 hour, the thermal processing commencing after conclusion of the heating.

20. The method of claim 12 , further comprising exposing the closed-pore silica body to a gas, the gas having a pressure of at least 2.0 atm.

21. The method of claim 12 , wherein the doping precursor has a partial pressure of at least 5.0 atm.

22. The method of claim 12 , further comprising drawing or redrawing the closed-pore silica body, the drawing or redrawing comprising heating the closed-pore silica body to a temperature of at least 1700° C., the drawing or redrawing commencing after conclusion of the heating.

Assignees

• Corning Inc

Inventors

• Bookbinder Dana Craig
• Dawes Steven Bruce
• Fiacco Richard Michael
• Li Ming-Jun
• Tandon Pushkar

Classifications

• C03B2201/20

  doped with non-metals other than boron or fluorine · CPC title

• C03B2201/12

  doped with fluorine (C03B2201/14 takes precedence) · CPC title

• C03B37/01446 Primary

  Thermal after-treatment of preforms, e.g. dehydrating, consolidating, sintering (C03B37/01853 takes precedence) · CPC title

• C03B37/01453

  for doping the preform with flourine · CPC title

• C03B19/1453

  Thermal after-treatment of the shaped article, e.g. dehydrating, consolidating, sintering · CPC title