Molten hydroxide membrane for separation of acid gases from emissions

Patent metadata

Field	Value
Publication number	US-11260344-B2
Application number	US-201916592579-A
Country	US
Kind code	B2
Filing date	Oct 3, 2019
Priority date	May 19, 2016
Publication date	Mar 1, 2022
Grant date	Mar 1, 2022

Abstract

In one embodiment, a separation membrane includes: a porous support structure, wherein the porous support structure comprises a system of continuous pores connecting an inlet of the separation membrane to an outlet of the separation membrane; and at least one alkali metal hydroxide disposed within pores of the porous support structure. Other aspects and embodiments of the disclosed inventive concepts will become apparent from the detailed description, which, when taken in conjunction with the drawings, illustrate by way of example the principles of the invention.

First claim

What is claimed is:

1. A separation membrane, comprising:
a porous support structure, wherein the porous support structure comprises a system of continuous pores connecting an inlet of the separation membrane to an outlet of the separation membrane; and
at least one alkali metal hydroxide disposed within pores of the porous support structure; and
wherein at least some of the at least one alkali metal hydroxide disposed within the pores of the porous support structure is present in a liquid phase.

2. The separation membrane as recited in claim 1 , wherein the at least one alkali metal hydroxide is selected from a group consisting of lithium hydroxide, sodium hydroxide, potassium hydroxide, rubidium hydroxide, and cesium hydroxide.

3. The separation membrane as recited in claim 1 , wherein the at least one alkali metal hydroxide comprises a mixture of at least two alkali metal hydroxides selected from a group consisting of: lithium hydroxide, sodium hydroxide and potassium hydroxide.

4. The separation membrane as recited in claim 1 , wherein the porous support structure comprises a material selected from a group consisting of: inconel 600, grade 316 stainless steel, grade 304 stainless steel, yttrium doped zirconium oxide, cerium oxide, aluminum oxide, calcium carbonate and silicon carbide.

5. The separation membrane as recited in claim 1 , wherein the porous support structure is characterized by a thickness of at least 0.01 cm.

6. The separation membrane as recited in claim 1 , wherein pores of the porous support structure are characterized by a diameter in a range from about 10 nm to about 1 millimeter.

7. The separation membrane as recited in claim 1 , comprising a porous conductive coating coupled to opposite ends of the separation membrane.

8. The separation membrane as recited in claim 7 , wherein the porous conductive coating comprises activated carbon and/or a graphitic material.

9. The separation membrane as recited in claim 1 , wherein the porous support structure is characterized by a cross-sectional area of at least 1 cm 2 and a thickness of at least 0.01 cm.

10. The separation membrane as recited in claim 1 , wherein the at least one alkali metal hydroxide comprises a ternary mixture of hydroxides present in a ratio in a range from 4KOH:4NaOH:1LiOH to 1KOH:1NaOH:4LiOH.

11. The separation membrane as recited in claim 1 , wherein the porous support structure comprises an aerogel.

12. The separation membrane as recited in claim 11 , wherein the aerogel comprises at least one material selected from the group consisting of: inconel 600, grade 316 stainless steel, yttrium doped zirconium oxide, cerium oxide, aluminum oxide, calcium carbonate, silicon carbide, and combinations thereof.

13. A separation membrane, comprising:
a porous support structure, wherein the porous support structure comprises a system of continuous pores connecting an inlet of the separation membrane to an outlet of the separation membrane; and
at least one alkali metal hydroxide disposed within pores of the porous support structure; and
wherein the at least one alkali metal hydroxide is present in a molten phase.

14. The separation membrane as recited in claim 1 , wherein the porous support structure is characterized by at least one gradient in pore size along an axis of the porous support structure.

15. The separation membrane as recited in claim 14 , wherein the at least one gradient in pore size is characterized by either:
a first profile in which larger of the pores are located near a first end of the porous support structure and smaller of the pores are located near a second end of the porous support structure, wherein the first end and the second end of the porous support structure are positioned opposite one another; or
a second profile in which larger of the pores are located near the first end and the second end of the porous support structure and smaller of the pores are located a central region between the first end and the second end of the porous support structure.

16. The separation membrane as recited in claim 1 , wherein the at least one alkali metal hydroxide comprises a eutectic mixture of alkali metal hydroxides.

17. The separation membrane as recited in claim 1 , wherein the at least one alkali metal hydroxide comprises an equimolar mixture of potassium hydroxide, sodium hydroxide, and lithium hydroxide.

18. The separation membrane as recited in claim 1 , wherein the at least one alkali metal hydroxide comprises a ternary mixture of potassium hydroxide, sodium hydroxide, and lithium hydroxide.

19. The separation membrane as recited in claim 18 , wherein the potassium hydroxide and the sodium hydroxide are each present in an amount less than the lithium hydroxide.

Assignees

• L Livermore Nat Security Llc

Inventors

• Worsley Marcus
• Campbell Patrick
• Kim Sangil
• Merrill Matthew

Classifications

• B01D2325/0283

  Pore size · CPC title

• B01D69/12

  Composite membranes; Ultra-thin membranes · CPC title

• B01D71/0215

  Silicon carbide; Silicon nitride; Silicon oxycarbide · CPC title

• B01D69/108

  Inorganic support material · CPC title

• B01D71/024

  Oxides · CPC title