Process to prepare a solid support for a procatalyst suitable for polymerization of olefins

Patent metadata

Field	Value
Publication number	US-11254757-B2
Application number	US-201716340941-A
Country	US
Kind code	B2
Filing date	Oct 11, 2017
Priority date	Oct 12, 2016
Publication date	Feb 22, 2022
Grant date	Feb 22, 2022

Abstract

The invention relates to a process for preparing a solid support for a procatalyst suitable for preparing a catalyst composition for olefin polymerization, said process for preparing said solid support comprising reacting a compound R4zMgX42-z with a silane compound Si(OR5)4-n(R6)n in a solvent and mixing the resulting mixture with a mixing device and at a certain mixing speed in order to give a solid support Mg(OR1)xX12-x said solid support obtained having an average particle size of at most 17 μm, preferably at most 16 or 14 μm, more preferably at most 12 μm. The invention further relates to a solid support, a process for preparing a procatalyst and said procatalyst as well as polyolefins obtained using said procatalyst.

First claim

The invention claimed is:

1. A process for preparing a procatalyst for preparing a catalyst composition for olefin polymerization, said process comprising the steps of:
Step 1) preparing a solid support by reacting:
a compound R 4 z MgX 4 2-z wherein
R 4 is each independently a linear, branched or cyclic hydrocarbyl group independently selected from alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl, alkylaryl groups, and one or more combinations thereof; wherein said hydrocarbyl group is substituted or unsubstituted and optionally contains one or more heteroatoms;
X 4 is each independently a fluoride (F—), chloride (Cl—), bromide (Br—) or iodide (I—);
z is in a range of larger than 0 and smaller than 2, being 0<z<2;

with a silane compound Si(OR 5 ) 4-n (R 6 ) n wherein
R 5 is each independently a linear, branched or cyclic hydrocarbyl group independently selected from alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl, alkylaryl groups, and one or more combinations thereof; wherein said hydrocarbyl group is substituted or unsubstituted and optionally contains one or more heteroatoms;
R 6 is each independently a linear, branched or cyclic hydrocarbyl group independently selected from alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl, alkylaryl groups, and one or more combinations thereof; wherein said hydrocarbyl group is substituted or unsubstituted and optionally contains one or more heteroatoms;
n is in range of 0 to 4;

in a solvent and mixing the resulting mixture with a mixing device and at a certain mixing speed in order to give a solid support Mg(OR 1 ) x X 1 2-x , wherein R 1 is the same as R 5 ; X 1 is each independently a fluoride (F—), chloride (Cl—), bromide (Br—) or iodide (I—); and x is in a range of larger than 0 and smaller than 2, being 0<x<2;
wherein the reaction is carried out in a full scale reactor of 100 L to 6000 L, the mixing is started with an initial mixing speed and the speed is increased to a final mixing speed wherein the initial mixing speed is lower than the final mixing speed, wherein the initial mixing speed is between 30 to 150 rpm, and the final mixing speed is between 160 to 230 rpm, and
wherein the solid support obtained in step 1) has an average particle size of at most 17 μm;
Step 2) optionally contacting the solid support obtained in step 1) with at least one activating compound selected from the group formed by activating electron donors and metal alkoxide compounds of formula M 1 (OR 2 ) v-w (OR 3 ) w or M 2 (OR 2 ) v-w (R 3 ) w , to obtain an intermediate reaction product; wherein: M 1 is a metal of Ti, Zr, Hf, Al or Si; M 2 is a metal being Si; v is the valency of M 1 or M 2 and w<v; R 2 and R 3 are each a linear, branched or cyclic hydrocarbyl group independently selected from alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl, alkylaryl groups, and one or more combinations thereof; wherein said hydrocarbyl group is substituted or unsubstituted and optionally contains one or more heteroatoms; and
Step 3) reacting the solid support or intermediate reaction product, obtained respectively in step 1) or 2), with a halogen-containing Ti-compound, an activator and at least one internal electron donor to obtain a procatalyst,
wherein the activator in step 3) is ethylbenzoate and the internal electron donor in step 3) is 4-[benzoyl(methyl)amino]pentan-2-yl benzoate.

2. The process according to claim 1 , wherein a mixing device with propeller blades is used and/or wherein a reactor with at least two baffles is used.

3. The process according to claim 1 , wherein dibutyl ether is used as a solvent.

4. The process according to claim 3 , wherein the solvent is added to reactor in such an amount that the solvent volume to reactor volume ratio is greater than 25%.

5. The process according to claim 1 , wherein in R 2 and R 3 , each of said hydrocarbyl groups contains 1 to 20 carbon atoms and n is from 0 up to and including 1.

6. The process according to claim 1 , wherein R 4 is butyl and X 4 is chloride.

7. The process according to claim 1 , wherein in R 4 and R 5 , each of said hydrocarbyl groups contains 1 to 20 carbon atoms.

8. The process according to claim 1 , wherein the reaction is carried out in a full scale reactor of 1000 L to 6000 L, the initial mixing speed is between 40 and 140 rpm and the final mixing speed is 160 and 230 rpm.

9. A process for the preparation of a polyolefin comprising
preparing a procatalyst according to the process of claim 1 ,
combining the procatalyst with a co-catalyst and optionally an external electron donor to form a catalyst system, and
contacting the catalyst system with at least one olefin to prepare the polyolefin.

10. The process according to claim 9 , wherein the at least one olefin comprises propylene.

Assignees

• Sabic Global Technologies Bv

Inventors

• Moman Akhlaq
• Siddiqui Inaamul Haq
• Padmanabhan Sudhakar R
• Al-Humydi Abdulaziz Hamad

Classifications

• B01J19/006 Primary

  Baffles · CPC title

• C08F110/06 Primary

  Propene · CPC title

• C08F4/6565

  and magnesium or compounds thereof · CPC title

• B01F27/91

  with propellers · CPC title

• B01J19/0066

  Stirrers (mixing per se B01F) · CPC title