Chlorodisilazanes
US-2022119947-A1 · Apr 21, 2022 · US
US11254692B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11254692-B2 |
| Application number | US-201817259679-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 8, 2018 |
| Priority date | Jul 12, 2018 |
| Publication date | Feb 22, 2022 |
| Grant date | Feb 22, 2022 |
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Preparation of sulfur fine chemicals from sulfur sources is described.
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What is claimed is: 1. A method of manufacturing a silyl sulfide comprising contacting a sulfate-source with a silane reducing agent to produce the silyl sulfide. 2. The method of claim 1 , wherein the sulfate-source is a bisulfate. 3. The method of claim 2 , wherein the bisulfate is a bisulfate salt or is a bisulfate produced in situ from a sulfate salt and an acid or sulfuric acid and a base. 4. The method of claim 1 , wherein the silyl sulfide is a salt including the silyl sulfide is an anion and a cation. 5. The method of claim 1 , wherein the silane reducing agent is H n SiX 4-n where X is a halogen, a pseudohalogen, alkoxy, aryloxy, amido or arylamido and n is 1, 2, 3 or 4. 6. The method of claim 4 , wherein the silyl sulfide is [X 3 SiS] − wherein X is a halogen, a pseudohalogen, alkoxy, aryloxy, amido or arylamido. 7. The method of claim 4 , wherein the cation includes a nitrogen-based cation, a phosphorus-based cation, an alkali metal cation, an alkali-earth metal cation, or an ionic liquid cation.
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