Defect resisting acoustic polymer interlayers

Patent metadata

Field	Value
Publication number	US-11254111-B2
Application number	US-201715729945-A
Country	US
Kind code	B2
Filing date	Oct 11, 2017
Priority date	Mar 9, 2012
Publication date	Feb 22, 2022
Grant date	Feb 22, 2022

Abstract

This disclosure is related to the field of polymer interlayers for multiple layer glass panels and multiple layer glass panels having at least one polymer interlayer sheet. Specifically, this disclosure is related to the field of polymer interlayers comprising multiple thermoplastic layers which resist the formation of optical defects.

First claim

I claim:

1. A polymer interlayer comprising:
a first polymer layer comprising at least one polymer selected from the group consisting of poly(vinyl butyral), polyurethane, and poly(ethylene-co-vinyl acetate);
a second polymer layer comprising at least one polymer selected from the group consisting of poly(vinyl butyral), polyurethane, and poly(ethylene-co-vinyl acetate); wherein said second polymer layer is in contact with said first polymer layer; and
a third polymer layer comprising at least one polymer selected from the group consisting of poly(vinyl butyral), polyurethane, and poly(ethylene-co-vinyl acetate); wherein said third polymer layer is in contact with said second polymer layer; and wherein said second polymer layer is disposed between said first polymer layer and said third polymer layer, thereby resulting in a polymer interlayer comprising two skin layers and a core layer; and
wherein each of said skin layers has a flow of about 0.19 mm to about 0.37 mm as measured by DF135, and wherein said first polymer layer and/or said third polymer layer has a stress relaxation modulus, G′(t), measured at a temperature of 150° C. and a time of 100 seconds, in the range of from 0.10 to 100 Pascals.

2. The polymer interlayer of claim 1 , wherein said first polymer layer and/or said second polymer layer and/or said third layer comprise poly(vinyl butyral).

3. The polymer interlayer of claim 2 , wherein said skin layers each have a flow of 0.19 to 0.26 mm as measured by DF135.

4. The polymer interlayer of claim 1 , wherein said first polymer layer and/or said third polymer layer has an embossed post heat surface roughness, Rz, ranging from about 25 to about 55 microns.

5. The polymer interlayer of claim 3 , wherein said first polymer layer and/or said third polymer layer has a stress relaxation modulus, G′(t), of less than about 100 Pascals.

6. The polymer interlayer of claim 2 , wherein said second polymer layer comprises about 9 to about 18 weight percent residual hydroxyl groups calculated as PVOH.

7. The polymer interlayer of claim 2 , wherein the polymers in the first and third polymer layers each have a molecular weight less than 140,000 Daltons and the polymer in the second polymer layer has a molecular weight greater than 140,000 Daltons.

8. The polymer interlayer of claim 2 , wherein the polymers in the first and third polymer layers each have a molecular weight less than 130,000 Daltons.

9. A polymer interlayer comprising:
a first polymer layer comprising plasticized poly(vinyl butyral);
a second polymer layer comprising plasticized poly(vinyl butyral) in contact with said first polymer layer; and
a third polymer layer comprising plasticized poly(vinyl butyral) in contact with said second polymer layer; wherein said second polymer layer is disposed between said first polymer layer and said third polymer layer, thereby resulting in a polymer interlayer comprising two skin layers and a core layer; and
wherein at least one of the first and third polymer layers has a stress relaxation modulus, G′(t), of less than about 100 Pascals.

10. The polymer interlayer of claim 9 , wherein said first polymer layer and/or said third polymer layer has a flow in the range of about 0.19 mm to about 0.26 mm as measured by DF135.

11. The polymer interlayer of claim 9 , wherein said first polymer layer and/or said third polymer layers comprise about 10 to about 55 phr plasticizer.

12. The polymer interlayer of claim 9 , wherein said second polymer layer comprises about 9 to about 18 weight percent residual hydroxyl groups calculated as PVOH.

13. The polymer interlayer of claim 9 , wherein the polymers in the first and third polymer layers each have a molecular weight less than 140,000 Daltons and the polymer in the second polymer layer has a molecular weight greater than 140,000 Daltons.

14. The polymer interlayer of claim 9 , wherein the polymers in the first and third polymer layers each have a molecular weight less than 110,000 Daltons.

15. The polymer interlayer of claim 9 , wherein the poly(vinyl butyral) in the first polymer layer and the poly(vinyl butyral) in the third polymer layer each have a residual hydroxyl content of at least 19 weight percent, calculated as PVOH, and wherein the total plasticizer content of each of the first polymer layer and the third polymer layer is not more than 38 phr.

16. The polymer interlayer of claim 9 , wherein the poly(vinyl butyral) in the first polymer layer and the poly(vinyl butyral) in the third polymer layer each comprises about 13 to about 30 weight percent residual hydroxyl groups calculated as PVOH, and wherein the total plasticizer content of each of the first polymer layer and the third polymer layer is not more than 38 phr.

17. The polymer interlayer of claim 9 , wherein the total plasticizer content in the interlayer is about 30 to 60 phr.

18. The polymer interlayer of claim 9 , wherein said first polymer layer and/or said third polymer layers have a glass transition temperature of about 25° C. to about 55° C.

19. The polymer interlayer of claim 9 , wherein said second polymer layer has a glass transition temperature of about 10° C. to about −15° C.

Assignees

• Solutia Inc

Inventors

• Lu Jun

Classifications

• E04B1/86

  slab-shaped · CPC title

• B32B2329/04

  Polyvinylalcohol · CPC title

• B32B2307/538

  Roughness · CPC title

• B32B2250/246

  All polymers belonging to those covered by groups B32B27/32 and B32B27/30 · CPC title

• B32B27/30 Primary

  comprising vinyl {(co)polymers; comprising acrylic (co)polymers} · CPC title