System for collecting liquid samples

Patent metadata

Field	Value
Publication number	US-11249101-B2
Application number	US-202016781262-A
Country	US
Kind code	B2
Filing date	Feb 4, 2020
Priority date	Jun 26, 2015
Publication date	Feb 15, 2022
Grant date	Feb 15, 2022

Abstract

Systems and methods are described to determine whether a sample transmitted through a transfer line from a remote sampling system contains a suitable sample to analyze by an analysis system. A system embodiment includes, but is not limited to, a sample receiving line configured to receive a liquid segment a first detector configured to detect the liquid segment at a first location in the sample receiving line; a second detector configured to detect the liquid segment at a second location in the sample receiving line downstream from the first location; and a controller configured to register a continuous liquid segment in the sample receiving line when the first detector and the second detector match detection states prior to the controller registering a change of state of the first detector.

First claim

What is claimed is:

1. A system comprising:
a sample receiving line configured to receive a liquid segment;
a valve communicatively coupled with the sample receiving line, the valve configured to selectably direct the liquid segment for analysis system or pass the liquid segment to waste;
a first detector configured to detect at least one of a presence or an absence of the liquid segment at a first location in the sample receiving line, the first detector configured to register the absence of the liquid segment at the first location in the sample receiving line as a first state, and register the presence of the liquid segment at the first location in the sample receiving line as a second state;
a second detector configured to detect at least one of a presence or an absence of the liquid segment at a second location in the sample receiving line downstream from the first location, the second detector configured to register the absence of the liquid segment at the second location in the sample receiving line as a first state, and register the presence of the liquid segment at the second location in the sample receiving line as a second state; and
a controller communicatively coupled with the first detector and the second detector, the controller configured to register a void in the liquid segment in the sample receiving line when the first detector is in the second state and the second detector is at the second state prior to the controller registering a change of state of the first detector from the second state to the first state, the controller configured to direct the liquid segment through the valve to pass to waste when the controller registers the void and to control the valve to direct the liquid segment for analysis when the controller does not register the void.

2. The system of claim 1 , wherein the sample receiving line includes a sample loop.

3. The system of claim 1 , further comprising a timer configured to monitor a time at which the second detector maintains the second state, wherein the controller is configured to register the continuous liquid segment in the sample receiving line when each of (i) the first detector is in the second state and the second detector is at the second state prior to the controller registering a change of state of the first detector from the second state to the first state and (ii) the time at which the second detector maintains the second state exceeds a threshold time.

4. The system of claim 1 , wherein the valve is coupled between the first location in the sample receiving line and the second location in the sample receiving line, the valve switchable between at least two flow path configurations.

5. The system of claim 4 , wherein the controller is configured to switch the valve between the at least two flow path configurations responsive to registering the continuous liquid segment in the sample receiving line.

6. The system of claim 1 , further comprising:
an analysis system at a third location;
a remote sampling system at a fourth location remote from the third location, the remote sampling system configured to receive the liquid segment for analysis;
a sample transfer line configured to transport the liquid segment from the fourth location to the third location, the sample transfer line coupled with the remote sampling system so that the remote sampling system is operable to be in fluid communication with the sample transfer line for driving the liquid segment to the third location, wherein the analysis system includes the sample receiving line, and the sample receiving line is configured to selectively couple with the sample transfer line and the analysis system so that the sample receiving line is operable to be in fluid communication with the sample transfer line to receive the liquid segment and in fluid communication with the analysis system to supply the liquid segment to the analysis system.

7. The system of claim 6 , wherein the sample transfer line is at least five meters in length.

8. The system of claim 6 , wherein the sample transfer line is at least ten meters in length.

9. The system of claim 6 , wherein the analysis system includes a plurality of analysis devices.

10. The system of claim 9 , wherein the plurality of analysis devices includes at least two of a mass spectrometer, an optical emission spectrometer, an ion chromatograph, a liquid chromatograph, a Fourier transform infrared spectrometer, a particle counter, a moisture analyzer, and a gas chromatograph.

11. A method comprising
receiving a liquid segment in a sample receiving line, the sample receiving line communicatively couple with a valve, the valve configured to selectably direct the liquid segment for analysis system or pass the liquid segment to waste;
registering a first state with a first detector responsive to detection of the liquid segment at a first location in the sample receiving line with the first detector, the first state of the first detector corresponding to a presence of the liquid segment at the first location;
registering a first state with a second detector responsive to detection of the liquid segment at a second location in the sample receiving line downstream from the first location, the first state of the second detector corresponding to a presence of the liquid segment at the second location;
monitoring whether the second detector registered the first state prior to the first detector registering a second state, the second state corresponding to a void in the liquid segment at the first location; and
automatically switching the valve to direct the liquid segment through the valve to pass to waste when the void is registered in the liquid segment and to control the valve to direct the liquid segment for analysis when no void is registered in the liquid segment.

12. The method of claim 11 , wherein further comprising:
determining whether the liquid segment includes a chemical component that exceeds an element-specific contamination limit.

13. The method of claim 11 , further comprising:
automatically sending an alert to an origin location of the liquid segment when the continuous liquid segment is determined to include the chemical component that exceeds the element-specific contamination limit.

14. The method of claim 11 , wherein registering a liquid segment with no voids in the sample receiving line when the second detector registered the first state prior to the first detector registering a second state includes:
registering a continuous liquid segment in the sample receiving line when each of (i) the second detector registered the first state prior to the first detector registering a second state and (ii) the time at which the second detector maintains the second state exceeds a threshold time.

Assignees

• Elemental Scientific Inc

Inventors

• Diaz David
• Hein Jonathan
• Uhlmeyer Kyle W
• Wiederin Daniel R
• Yost Tyler
• Wiederin Kevin

Classifications

• G01N2001/1427

  Positive displacement, piston, peristaltic · CPC title

• G01N1/38

  Diluting, dispersing or mixing samples · CPC title

• G01N1/14 Primary

  Suction devices, e.g. pumps; Ejector devices · CPC title

• G01N35/1097 Primary

  characterised by the valves (valves in general F16K) · CPC title

• G01N30/02

  Column chromatography · CPC title