Zinc alloy plated steel material having excellent weldability and processed-part corrosion resistance

Patent metadata

Field	Value
Publication number	US-11248287-B2
Application number	US-202016773101-A
Country	US
Kind code	B2
Filing date	Jan 27, 2020
Priority date	Dec 24, 2014
Publication date	Feb 15, 2022
Grant date	Feb 15, 2022

Abstract

Zn alloy plated steel material having excellent weldability and processed-part corrosion resistance and a method for production of Zn alloy plated steel material are provided. In the Zn alloy plated steel material comprising base steel material and a Zn alloy plating layer, the Zn alloy plating layer includes, by wt %, Al: 0.1-5.0%, Mg: 0.1-5.0%, as well as a remainder of Zn and inevitable impurities. The Zn alloy plated steel material includes a lower interface layer and an upper interface layer between the base steel material and the Zn alloy plating layer, wherein the lower interface layer is formed on the base steel material and has a dense structure, and the upper interface layer is formed on the lower interface layer and has a network-type or island-type structure.

First claim

The invention claimed is:

1. A zinc (Zn) alloy plated steel material, comprising:
a base steel and a Zn alloy plating layer, the Zn alloy plating layer including, by wt %, aluminum (Al): 0.1% to 5.0%, magnesium (Mg): 0.1% to 5.0%, Zn as a residual component, and inevitable impurities,
wherein between the base steel and the Zn alloy plating layer, a lower interface layer formed on the base steel and having a fine structure and an upper interface layer formed on the lower interface layer and having a network-type structure or an island-type structure are provided,
wherein a maximum length of LME cracks at a weld zone of the Zn alloy plated steel material is 100 μm or less,
where the weld zone is formed by a welding current of 7 kA was applied using a copper (Cu)-chrome (Cr) electrode having a tip diameter of 6 mm, and welding was performed on the condition of electrode force of 2.1 kN, a welding time of 11 cycles and a holding time of 11 cycles, wherein 1 cycle is 1/60 seconds.

2. The Zn alloy plated steel material of claim 1 , wherein the upper interface layer and the lower interface layer comprise an Fe—Al-based alloy, and the Fe—Al-based alloy is provided as one or more type of alloy selected from a group consisting of Fe 2 Al 5 , FeAl 3 and FeAl.

3. The Zn alloy plated steel material of claim 1 , wherein an area percentage of the upper interface layer, as compared with an area of the lower interface layer, is in a range of 10% to 90%.

4. The Zn alloy plated steel material of claim 1 , wherein an area percentage of the upper interface layer, as compared with an area of the lower interface layer, is in a range of 40% to 70%.

5. The Zn alloy plated steel material of claim 1 , wherein the upper interface layer includes, by wt %, Al: 15% to 80%, Fe: 20% to 85%, and Zn: 10% or less (including 0%).

6. The Zn alloy plated steel material of claim 1 , wherein a thickness of the upper interface layer is in a range of 50 nm to 1,000 nm.

7. The Zn alloy plated steel material of claim 1 , wherein a thickness of the upper interface layer is in a range of 74 nm to 450 nm.

8. The Zn alloy plated steel material of claim 1 , wherein a thickness of the lower interface layer is 500 nm or less (excluding 0 nm).

9. The Zn alloy plated steel material of claim 1 , wherein the base steel comprises, by wt %, a total of 0.1% or more of one or more elements selected from a group consisting of silicon (Si), manganese (Mn), and nickel (Ni), and the upper interface layer and the lower interface layer comprise a total of 0.001% or more of one or more elements selected from a group consisting of Si, Mn, and Ni.

10. The Zn alloy plated steel material of claim 1 , wherein a centerline arithmetical average roughness (Ra) of the base steel is 0.8 μm to 1.2 μm.

11. The Zn alloy plated steel material of claim 1 , wherein a ten point median height (Rz) of the base steel is 7.5 μm˜15.5 μm.

12. The Zn alloy plated steel material of claim 1 , wherein a maximum height roughness (Rmax) of the base steel is 8 μm˜16.5 μm.

13. The Zn alloy plated steel material of claim 1 , wherein an average length of LME cracks at a weld zone of the Zn alloy plated steel material is 20 μm or less,
where the weld zone is formed by a welding current of 7 kA was applied using a copper (Cu)-chrome (Cr) electrode having a tip diameter of 6 mm, and welding was performed on the condition of electrode force of 2.1 kN, a welding time of 11 cycles and a holding time of 11 cycles, wherein 1 cycle is 1/60 seconds.

14. The Zn alloy plated steel material of claim 1 , wherein a red rust occurrence time of the Zn alloy plated steel material is 500 hours,
where the red rust occurrence time of the Zn alloy plated steel material is measured based on ASTM B117-11, after a bending process (OT bending) of each Zn alloy plated steel material.

Assignees

• Posco

Inventors

• Oh Min-Suk
• Kim Sang-Heon
• Kim Tae-Chul
• Kim Jong-Sang
• Yun Hyun-Chu
• Yoo Bong-Hwan
• Sohn Il-Ryoung

Classifications

• C23C2/022

  by heating · CPC title

• C23C2/29

  Cooling or quenching · CPC title

• Y10T428/12799

  Next to Fe-base component [e.g., galvanized] · CPC title

• C23C2/40

  Plates; Strips · CPC title

• C22C38/06

  containing aluminium · CPC title