Dewaxing and dearomatization process of hydrocarbon in a slurry reactor

Patent metadata

Field	Value
Publication number	US-11248179-B2
Application number	US-201716474418-A
Country	US
Kind code	B2
Filing date	Dec 29, 2017
Priority date	Jan 3, 2017
Publication date	Feb 15, 2022
Grant date	Feb 15, 2022

Abstract

A process for the production of a hydrocarbon fluid includes the step of catalytically hydrogenating a hydrocarbon cut in presence of both a dearomatization catalyst and a dewaxing catalyst in a single slurry reactor. A hydrocarbon fluid is also disclosed as being obtainable by the process.

First claim

The invention claimed is:

1. A process for the production of a hydrocarbon fluid comprising the step of catalytically hydrogenating a hydrocarbon cut in presence of both a dearomatization catalyst and a dewaxing catalyst in a single slurry reactor, wherein the hydrocarbon cut has a sulphur content below 15 ppm, wherein the reaction temperature is ranging from 180 to 325° C.

2. The process according to claim 1 , wherein the reaction pressure is ranging from 30 to 160 bars.

3. The process according to claim 1 , wherein the dearomatization catalyst is selected from the group consisting of metals of the Group VIII and/or Group VIB.

4. The process according to claim 1 , wherein the dewaxing catalyst is selected from the group consisting of silicalite alumina, zeolites, MFI zeolites, silicoaluminophosphates, aluminosilicate (Al-oxide Si-dioxide).

5. The process according to claim 1 , wherein the dearomatization catalyst amount is comprised between 0.1 and 6 wt %, based on the weight of the hydrocarbon cut.

6. The process according to claim 1 , wherein the dewaxing catalyst amount is comprised between 0.1 and 6 wt %, based on the weight of the hydrocarbon cut.

7. The process according to claim 1 , wherein the weight ratio of the dewaxing catalyst amount to the dearomatization catalyst amount is between 1:1 to 1:10.

8. The process according to claim 1 , wherein the cut is a gas oil fraction.

9. The process according to claim 8 wherein the cut is a-heavy gasoil.

10. The process according to claim 1 , wherein the hydrocarbon fluid obtained has an initial boiling point and a final boiling point in the range of 200° C. to 450° C. and/or has a boiling range below 80° C.

11. The process according to claim 1 , wherein the hydrocarbon fluid obtained has an aromatic content less than 1 wt % by weight.

12. The process according to claim 1 , wherein the hydrocarbon fluid obtained has a pour point lower than −40° C.

13. The process according to claim 1 , carried out continuously.

14. The process according to claim 1 , further comprising the step of using the fluid as drilling fluid, in hydraulic fracturing, in mining, in water treatments, in industrial solvents, in paints composition, in explosives, in printing inks, in oil dispersants, in food processing industry and in metal working fluids, electric discharge machining (EDM) fluids, rust preventives, coating fluids and aluminium rolling oils, and in concrete demoulding formulations, in industrial lubricants, insulation oils, hydraulic oils, gear oils, turbine oils, textile oils and in transmission fluids.

15. The process according to claim 3 , wherein the dearomatization catalyst is selected from nickel, platinum, palladium, rhenium, rhodium, nickel tungstate, nickel molybdenum, molybdenum, cobalt molybdenate, nickel molybdenate on silica and/or alumina carriers.

16. The process according to claim 4 , wherein the dewaxing catalyst is selected from aluminosilicate, comprising 0 to 10% by weight of at least one metal from group VIII and optionally 0 to 20% by weight of a group VI metal.

17. The process according to claim 8 , wherein the gas oil fraction is selected from among the atmospheric distillation gas oils, vacuum distillation gas oils, hydrocracked gas oils, gas oils from catalytic cracking, gas oils from visbreaking, coking gas oils, gas oils derived from gas deposit, deasphalted gas oils, gas oils derived from the hydrotreating of heavy fractions.

18. The process according to claim 9 , wherein the heavy gasoil has a final boiling point above 300° C.

19. The process according to claim 13 , carried out in a Continuous Stirred Tank Reactor.

Assignees

• Total Marketing Services

Inventors

• Ferreira Cristina
• Cukierman Serge
• Dupuy Carole
• Lemarchand Guillaume
• Siggen Raphael

Classifications

• B01J8/10

  moved by stirrers or by rotary drums or rotary receptacles {or endless belts} · CPC title

• C10G45/64 Primary

  containing crystalline alumino-silicates, e.g. molecular sieves · CPC title

• C10G45/60

  characterised by the catalyst used · CPC title

• C10G2300/1059

  Gasoil having a boiling range of about 330 - 427 °C · CPC title

• B01J8/087

  Heating or cooling the reactor · CPC title