Process to remove asphaltene from heavy oil by solvent

Patent metadata

Field	Value
Publication number	US-11248174-B2
Application number	US-201916729158-A
Country	US
Kind code	B2
Filing date	Dec 27, 2019
Priority date	Dec 27, 2019
Publication date	Feb 15, 2022
Grant date	Feb 15, 2022

Abstract

Embodiments of the disclosure produce a method and system for deasphalting a hydrocarbon feed. The hydrocarbon feed and a first solvent is combined using a Taylor-Couette mixer to form a mixed stream. The mixed stream and a second solvent are introduced to an extractor to produce a first deasphalted oil stream and a pitch stream. The first deasphalted oil stream is introduced to a solvent recovery unit to recover the first solvent and the second solvent via a recovered solvent stream and to produce a second deasphalted oil stream.

First claim

What is claimed is:

1. A method for deasphalting a hydrocarbon feed, the method comprising the steps of:
pressurizing the hydrocarbon feed to a pressure ranging between 2 MPa and 4 MPa;
heating the hydrocarbon feed to a temperature ranging between 150 deg. C and about 350 deg. C;
pressurizing a first solvent to a pressure ranging between 2 MPa and 4 MPa;
combining the hydrocarbon feed and the first solvent using a Taylor-Couette (TC) mixer to form a mixed stream, wherein the hydrocarbon feed comprises asphaltenes, wherein the mixed stream has a solvent-to-oil volume ratio ranging between 0.2 and 2, wherein the mixed stream has a reduced Taylor number of greater than about 1,000, wherein the TC mixer comprises:
an inner cylinder; and
an outer cylinder,
wherein the inner cylinder and the outer cylinder are concentric,
wherein the outer cylinder is stationary and includes an inlet and an outlet, the inlet configured to receive the hydrocarbon feed and the first solvent, the outlet configured to exit the mixed stream,
wherein the inner cylinder is rotating at a predetermined angular velocity,
wherein the ratio of inner cylinder radius (r 1 ) to outer cylinder radius (r 2 ) is between about 0.75 to about 0.95,
wherein the length aspect ratio (L r /d) is greater than about 40, wherein the gap aspect ratio (d/r 1 ) is between about 0.075 and about 0.277;

introducing the mixed stream and a second solvent to an extractor to produce a first deasphalted oil stream and a pitch stream, wherein the first deasphalted oil stream is substantially in the absence of the asphaltenes, wherein the pitch stream comprises the asphaltenes; and
introducing the first deasphalted oil stream to a solvent recovery unit to recover the first solvent and the second solvent via a recovered solvent stream and to produce a second deasphalted oil stream, wherein the second deasphalted oil stream is substantially in the absence of the first solvent and the second solvent.

2. The method of claim 1 , wherein the hydrocarbon feed is selected from the group consisting of: an atmospheric residue fraction, a vacuum residue fraction, and combinations thereof.

3. The method of claim 1 , wherein the first solvent is selected from the group consisting of: propane, n-butane, n-pentane, and combinations of the same.

4. The method of claim 1 , further comprising the step of:
pressurizing the second solvent to a pressure ranging between 2 MPa and 4 MPa.

5. The method of claim 1 , wherein the second solvent is selected from the group consisting of: propane, n-butane, n-pentane, and combinations of the same.

6. The method of claim 1 , wherein the extractor is operated at a temperature ranging between 50 deg. C and 150 deg. C and a pressure ranging between 2 MPa and 4 MPa.

7. The method of claim 1 , wherein the second solvent is introduced to the extractor at a position vertically lower than that of the mixed stream.

8. The method of claim 1 , wherein the extractor is operated to have a total solvent-to-oil volume ratio ranging between 0.5 and 5.

9. The method of claim 1 , further comprising the step of:
depressurizing the first deasphalted oil stream to a pressure ranging between 0.05 MPa and 0.1 MPa.

10. The method of claim 1 , wherein the solvent recovery unit is operated at a temperature ranging between 50 deg. C and 100 deg. C and a pressure ranging between 0.05 MPa and 0.1 MPa such that the recovered solvent stream includes the first solvent and the second solvent existing in gas phase.

Assignees

• Saudi Arabian Oil Co

Inventors

• Aljishi Mohammad F
• Choi Ki-Hyouk

Classifications

• B01F2215/0431

  Numerical size values, e.g. diameter of a hole or conduit, area, volume, length, width, or ratios thereof · CPC title

• C10G2300/308

  Gravity, density, e.g. API · CPC title

• B01F2215/0404

  theories or general explanations of phenomena associated with mixing or generalizations of a concept by comparison of equivalent methods · CPC title

• B01F27/272

  with means for moving the materials to be mixed axially between the surfaces of the rotor and the stator, e.g. the stator rotor system formed by conical or cylindrical surfaces · CPC title

• C10G2300/208

  Sediments, e.g. bottom sediment and water or BSW · CPC title