Liquid impregnated surfaces for liquid repellancy

Patent metadata

Field	Value
Publication number	US-11248129-B2
Application number	US-201715798032-A
Country	US
Kind code	B2
Filing date	Oct 30, 2017
Priority date	Oct 28, 2016
Publication date	Feb 15, 2022
Grant date	Feb 15, 2022

Abstract

Articles including repellent surfaces and methods of making and using these articles are disclosed. The repellant surface can comprise a polymer having a roughened surface and a fluorinated silane and a lubricating liquid deposited on the roughened surface. The repellent surface, and by extension the articles described herein, can exhibit superomniphobic properties. The methods for producing the repellant surface can comprise dissolving a polymer in a solvent to produce a polymer solution and optionally adding a non-solvent to the polymer solution to produce a casting mixture. The polymer solution or casting mixture can be deposited on a surface of a substrate and the solvent and/or the non-solvent evaporated to provide a coated-substrate having a roughened surface. A functional layer comprising a fluorinated silane followed by a lubricating liquid can be deposited on the roughened surface to form the repellant surface.

First claim

What is claimed is:

1. A method for producing a repellant surface, the method comprising:
dissolving a polymer in a solvent to produce a polymer solution;
adding a non-solvent to the polymer solution to produce a casting mixture, wherein the non-solvent is to the polymer;
depositing the casting mixture on a surface of a substrate;
evaporating the solvent and the non-solvent from the casting mixture to provide a coated-substrate having a roughened surface, wherein the roughened surface exhibits a water contact angle of at least about 100°; and
introducing a lubricating liquid to the roughened surface to form a liquid impregnated layer, wherein the repellant surface exhibits a tilt angle of about 5° or less.

2. The method of claim 1 , further comprising depositing a functional layer comprising a fluorinated silane on the roughened surface.

3. The method of claim 1 , wherein the polymer includes a hydrophobic polymer comprising a polyalkylene, a vinyl aromatic polymer, an acrylonitrile butadiene styrene copolymer, copolymers thereof, or blends thereof.

4. The method of claim 1 , wherein the solvent comprises an organic solvent.

5. The method of claim 1 , wherein the polymer and the solvent are present in the casting mixture at a weight ratio of from 1:100 to 50:1.

6. The method of claim 1 , wherein the non-solvent comprises a polar organic solvent.

7. The method of claim 1 , wherein the solvent and the non-solvent are present in the casting mixture in a volume ratio of from 100:1 to 1:2.

8. The method of claim 1 , wherein the roughened surface comprises a porous surface.

9. The method of claim 1 , wherein the porous surface comprises a pore size of from 1 nm to 100 microns.

10. The method of claim 1 , wherein the lubricating liquid comprises a fluorinated hydrocarbon.

11. The method of claim 1 , wherein the repellant surface exhibits a water contact angle of at least about 105° and a hexadecane contact angle of at least about 65°.

12. A method for producing a repellant surface, the method comprising:
dissolving a polymer in a solvent to produce a polymer solution, wherein the polymer is a hydrophobic polymer selected from the group consisting of a polyalkylene, a vinyl aromatic polymer, an acrylonitrile butadiene styrene copolymer, a polybutadiene polymer, and blends thereof;
depositing the polymer solution on a surface of a substrate;
evaporating the solvent from the polymer solution at ambient temperature and under an atmosphere comprising water vapor to provide a coated-substrate having a roughened surface, wherein the atmosphere has a relative humidity of at least about 30% and wherein the roughened surface exhibits a water contact angle of at least about 100°;
depositing a functional layer comprising a fluorinated silane on the roughened surface; and
introducing a lubricating liquid to the roughened surface to form a liquid impregnated layer, wherein the repellant surface exhibits a tilt angle of about 5° or less.

13. The method of claim 12 , wherein the polymer includes a hydrophobic polymer comprising a polyalkylene, a vinyl aromatic polymer, an acrylonitrile butadiene styrene copolymer, a polybutadiene polymer, copolymers thereof, or blends thereof.

14. The method of claim 12 , wherein the solvent comprises a water immiscible volatile solvent.

15. The method of claim 12 , wherein the polymer and the solvent are present in the polymer solution at a weight ratio of from 1:100 to 50:1.

16. The method of claim 12 , wherein the roughened surface comprises a honeycomb surface.

17. The method of claim 16 , wherein the honeycomb surface comprises patterns having a size of from 100 nm to 100 microns.

18. The method of claim 12 , wherein the lubricating liquid comprises a fluorinated hydrocarbon.

19. The method of claim 12 , wherein the repellant surface exhibits a water contact angle of at least about 105° and a hexadecane contact angle of at least about 65°.

20. The method of claim 12 , wherein the atmosphere has a relative humidity of at least about 50%.

21. The method of claim 12 , wherein the hydrophobic polymer is selected form the group consisting of polypropylene, polyethylene, polyisobutylene, polymethylpentene, polybutylene, ethylene propylene rubber, ethylene propylene diene monomer rubber, polystyrene, polybutadiene, acrylonitrile butadiene styrene copolymer, and blends thereof.

Assignees

• Ohio State Innovation Foundation

Inventors

• Brown Philip Simon
• Bhushan Bharat

Classifications

• B05D5/083

  involving the use of fluoropolymers · CPC title

• B05D7/02

  to macromolecular substances, e.g. rubber (treatment or coating of shaped articles made of macromolecular substances C08J7/00) · CPC title

• C09D5/1693 Primary

  as part of a multilayer system · CPC title

• C08J2325/06

  Polystyrene · CPC title

• C08J9/42

  with macromolecular compounds · CPC title