Lignin-based polymers with enhanced melt extrusion ability

Patent metadata

Field	Value
Publication number	US-11248121-B2
Application number	US-201916257294-A
Country	US
Kind code	B2
Filing date	Jan 25, 2019
Priority date	Jan 25, 2018
Publication date	Feb 15, 2022
Grant date	Feb 15, 2022

Abstract

A solid polymer blend material comprising: (i) lignin; and (ii) a polyamide having a melting point of no more than 240° C. and which is below the decomposition temperature of the lignin; wherein said lignin is homogeneously dispersed in said polyamide. Methods for producing the blend material are also described. Methods for producing objects made of the blend material by melt extrusion are also described, comprising: (a) melt blending components (i) and (ii) to form a polymer blend in which components (i) and (ii) are homogeneously blended, wherein the polymer blend exhibits a melt viscosity of no more than 2000 Pa·s at a shear rate of 100-1000 s −1 and when heated to a temperature of no more than 240° C.; and; (b) forming an object made of said polymer blend material.

First claim

What is claimed is:

1. A polymer blend material comprising:
(i) unmodified lignin; and
(ii) a polyamide having a melting point of no more than 240° C. and which is below the decomposition temperature of the unmodified lignin;
wherein said polyamide functions as a matrix in which the unmodified lignin is homogeneously dispersed as lignin domains having a size greater than 100 nm and up to 10 microns.

2. The polymer blend material of claim 1 , wherein the unmodified lignin is present in an amount of 10-60 wt % by weight of the polymer blend material.

3. The polymer blend material of claim 1 , wherein the unmodified lignin is present in an amount of 40-60 wt % by weight of the polymer blend material.

4. The polymer blend material of claim 1 , wherein said polyamide is amorphous or semi-crystalline.

5. The polymer blend material of claim 1 , wherein said polyamide is aliphatic.

6. The polymer blend material of claim 1 , wherein said polyamide is nylon 6, nylon 11, nylon 12, or a plasticized or modified nylon 6,6 that melts below 240° C.

7. The polymer blend material of claim 1 , wherein the polymer blend material further includes an elastomer in an amount of 1-30 wt % by weight of the polymer blend material.

8. The polymer blend material of claim 7 , wherein said elastomer is nitrile butadiene rubber.

9. The polymer blend material of claim 1 , wherein the polymer blend material excludes nitrile butadiene rubber.

10. The polymer blend material of claim 1 , wherein the lignin domains have a size greater than 100 nm and up to 5 microns.

11. The polymer blend material of claim 1 , wherein the lignin domains have a size of 200 nm to 10 microns.

12. A method of producing an object made of a lignin-containing polymer blend material by melt extrusion, the method comprising:
(a) melt blending the following components: (i) an unmodified lignin and (ii) a polyamide having a melting point of no more than 240° C. and which is below the decomposition temperature of the unmodified lignin, to form said polymer blend material in which components (i) and (ii) are homogeneously blended and wherein said polyamide functions as a matrix in which the unmodified lignin is homogeneously dispersed as lignin domains having a size greater than 100 nm and up to 10 microns, wherein the polymer blend material exhibits a melt viscosity of no more than 2000 Pa·s at a shear rate of 100-1000 s −1 and when heated to a temperature of no more than 240° C.; and
(b) forming an object made of said polymer blend material.

13. The method of claim 12 , wherein step (b) employs an extrusion process to form said object.

14. The method of claim 13 , wherein said extrusion process occurs in a heating chamber containing a nozzle, and pressure is induced on a melt of the polymer blend material while the polymer blend material is in said heating chamber to adjust the flow rate of the melt through the nozzle to result in the melt having a melt viscosity of no more than 2000 Pa·s.

15. The method of claim 14 , wherein said heating chamber is connected to a piston that induces pressure on the melt of the polymer blend material as the piston pushes the melt through the nozzle.

16. The method of claim 14 , wherein pressure is induced on the melt of the polymer blend material by exerting pressure on a solid filament of the polymer blend material as the solid filament is being fed into said heating chamber, wherein the pressure pushes the solid filament into the heating chamber at a desired flow rate.

17. The method of claim 13 , wherein said extrusion process occurs in an additive manufacturing process.

18. The method of claim 12 , wherein step (b) employs a casting process in which a melt of the polymer blend material is casted in a mold.

19. The method of claim 18 , wherein said casting process is an injection molding process.

20. The method of claim 19 , wherein said injection molding process is a resin transfer molding process.

21. The method of claim 18 , wherein said casting process is a compression molding process.

22. The method of claim 12 , wherein the unmodified lignin is present in an amount of 10-60 wt % by weight of the polymer blend material.

23. The method of claim 12 , wherein the unmodified lignin is present in an amount of 40-60 wt % by weight of the polymer blend material.

24. The method of claim 12 , wherein said polyamide is amorphous or semi-crystalline.

25. The method of claim 12 , wherein said polyamide is aliphatic.

26. The method of claim 25 , wherein said polyamide is nylon 6, nylon 11, nylon 12, or a plasticized or modified nylon 6,6 that melts below 240° C.

27. The method of claim 12 , wherein the polymer blend material further includes an elastomer in an amount of no more than 30 wt % by weight of the polymer blend material.

28. The method of claim 27 , wherein said elastomer is nitrile butadiene rubber.

29. The method of claim 12 , wherein the polymer blend material excludes nitrile butadiene rubber.

Assignees

• Ut Battelle Llc

Inventors

• Naskar Amit K
• Nguyen Ngoc A

Classifications

• C08L97/005 Primary

  Lignin · CPC title

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title

• C08G69/08

  derived from amino-carboxylic acids · CPC title

• B29K2093/00

  Use of natural resins, e.g. shellac, or derivatives thereof, as moulding material (B29K2001/00, B29K2003/00, B29K2005/00, B29K2007/00 and B29K2089/00 take precedence) · CPC title

• B29K2277/00

  Use of {PA, i.e.} polyamides, e.g. polyesteramides {or derivatives thereof,} as reinforcement · CPC title