Method for preparing psicose using recycling

Patent metadata

Field	Value
Publication number	US-11248015-B2
Application number	US-201716463986-A
Country	US
Kind code	B2
Filing date	Nov 22, 2017
Priority date	Dec 8, 2016
Publication date	Feb 15, 2022
Grant date	Feb 15, 2022

Abstract

The present invention relates to a method for preparing psicose by effectively utilizing a psicose crystallization mother liquor obtained in a psicose crystallization process, and specifically, relates to a method of preparation of psicose by putting a psicose crystallization mother liquor obtained in a psicose crystallization process into one or more kinds of processes selected from the group consisting of activated carbon treatment, ion purification process, simulated moving bed chromatography separation process and concentration process of psicose fraction to recycle.

First claim

The invention claimed is:

1. A method of preparation for psicose, comprising providing a psicose crystallization mother liquor into a psicose separation process to obtain psicose,
wherein the psicose separation process comprises one or more of steps selected from the group consisting of activated carbon treatment, ion purification and simulated moving bed (SMB) chromatography separation, and
wherein the psicose crystallization mother liquor is provided into the psicose separation process and mixed with a solution in the psicose separation process to produce a mixed solution such that the content of psicose in the mixed solution before being treated by the psicose separation process is 15% by weight to 50% by weight based on 100% by weight of the total solid content.

2. The method of preparation of claim 1 , wherein the psicose crystallization mother liquor is obtained by performing SMB chromatography separation of psicose conversion product to produce a psicose fraction, ion purification and concentration of the psicose fraction to produce psicose concentrates, and crystallization of the concentrates to prepare a psicose crystal.

3. The method of preparation of claim 1 , wherein the psicose crystallization mother liquor is treated by being putting into the psicose separation process.

4. The method of preparation of claim 1 , wherein the psicose crystallization mother liquor is treated by the ion purification and SMB chromatography separation process in order, with being put into the ion purification step.

5. The method of preparation of claim 4 , wherein the activated carbon treatment step is performed, before the ion purification step.

6. The method of preparation of claim 1 , wherein the psicose crystallization mother liquor is treated by the activated carbon treatment, ion purification and simulated moving bed (SMB) chromatography separation process in order, with being put into the activated carbon treatment step.

7. The method of preparation of claim 1 , wherein the psicose crystallization mother liquor comprises 80% by weight or higher of psicose content based on 100% by weight of the total solid content.

8. The method of preparation of claim 1 , wherein the SMB chromatography process is carried out with a column chromatograph packed with cation exchange resin having calcium active group.

9. The method of preparation of claim 1 , wherein the psicose content in the psicose fraction is 85% by weight or higher based on 100% by weight of the total solid content.

10. The method of preparation of claim 1 , wherein the psicose crystallization mother liquor is obtained by converting a fructose-containing raw material into psicose to produce psicose conversion product,
treating the psicose conversion product with ion purification and the simulated moving bed (SMB) chromatography process to produce psicose fraction,

performing ion purification and concentration of the psicose fraction to produce psicose concentrate, and
preparing psicose crystals from the concentrate.

11. The method of preparation of claim 10 , wherein the psicose crystallization mother liquor is obtained by
converting a fructose-containing raw material into psicose with using biological catalyst, to produce psicose conversion product,
treating the psicose conversion product with activated carbon treatment, ion purification and the simulated moving bed (SMB) chromatography process to produce psicose fraction,
performing ion purification and concentration of the psicose fraction to produce psicose concentrate, and
preparing psicose crystals from the concentrate.

12. The method of preparation of claim 10 , wherein the fructose content in fructose-containing raw material is 85% by weight or higher based on 100% by weight of the total solid content.

13. The method of preparation of claim 9 , wherein the psicose conversion reaction is performed with a biological catalyst having 15% to 70% of the psicose conversion rate.

14. The method of preparation of claim 9 , further comprising a step of treating fructose raffinate obtained in the SMB chromatography separation process with one or more steps selected from the group consisting of cooling, pH adjustment, ion purification and concentration processes, and recycling as a raw material of psicose conversion reaction.

Assignees

• Samyang Corp

Inventors

• Park Ji Won
• Park Sung Won
• Park Chong Jin

Classifications

• B01D15/361

  Ion-exchange · CPC title

• C12P19/02

  Monosaccharides (2-ketogulonic acid C12P7/60) · CPC title

• C07H3/02 Primary

  Monosaccharides · CPC title

• C07H1/06 Primary

  Separation; Purification · CPC title

• B01D2009/0086

  Processes or apparatus therefor · CPC title