Process for the manufacturing of alkanesulfonic acids

Patent metadata

Field	Value
Publication number	US-11247967-B2
Application number	US-201916963748-A
Country	US
Kind code	B2
Filing date	Jan 30, 2019
Priority date	Feb 7, 2018
Publication date	Feb 15, 2022
Grant date	Feb 15, 2022

Abstract

A process for manufacturing of an alkanesulfonic acid, and an alkanesulfonic acid manufactured by the process. Aspects of the process may involve manufacturing an alkanesulfonic acid by reaction of an initiator composition with an alkane and sulfur trioxide by preparing an initiator composition by reacting aqueous hydrogen peroxide with alkanesulfonic acid and/or H2SO4; and reacting the initiator composition with sulfur trioxide and alkane to form an alkanesulfonic acid, wherein an alkane with a purity of at least 98.0 mol-% is used.

First claim

The invention claimed is:

1. A process for manufacturing a methanesulfonic acid, the process comprising:
preparing an initiator composition comprising reacting aqueous hydrogen peroxide with alkanesulfonic acid and/or H 2 SO 4 ;
reacting the initiator composition with sulfur trioxide and methane to form methanesulfonic acid,
wherein the methane in the step of reacting the initiator composition has a purity of at least 98.0 mol-%, and
wherein the methane has a maximum content of hydrocarbons of 500 ppm.

2. The process of claim 1 , wherein the methane in the step of reacting the initiator composition has a purity of at least 98.5 mol-%.

3. The process of claim 1 , wherein the initiator composition in the preparing further comprises sulfur trioxide.

4. The process of claim 1 , wherein the initiator composition in the preparing further comprises a recycle stream from a bottom purge of a distillation of methanesulfonic acid comprising methanesulfonic acid and sulfuric acid.

5. The process of claim 1 , wherein the step of reacting the initiator composition is a radical reaction.

6. The process of claim 1 , wherein the methanesulfonic acid in the step of reacting the initiator composition has an HAZEN number of less than 300.

7. The process of claim 1 , further comprising:
purifying the methanesulfonic acid obtained from the step of reacting the initiator composition.

8. The process of claim 7 , wherein the purifying is a single step distillation or a multi step distillation.

9. The process of claim 7 , wherein the purifying is a crystallization followed by a solid-liquid separation.

10. The process of claim 7 , wherein the methanesulfonic acid obtained from the purifying has an HAZEN number of less than 300.

11. The process of claim 7 , wherein the preparing is conducted in a reactor A,
wherein the step of reacting the initiator composition is conducted in a reactor B or a set of reactors B, and
wherein the purifying is conducted in a column or set of columns C, and
wherein the reactor A, reactor B or set of reactors B, and column C are connected to conduct the process for the manufacturing of methanesulfonic acid continuously.

12. The process of claim 7 , wherein the purifying is conducted in a distillation unit,
wherein the preparing is conducted in a reactor A,
wherein the step of reacting the initiator composition is conducted in a reactor B or a set of reactors B, and
wherein a bottom product of the distillation unit is recycled into an upstream distillation column or into the reactor A or into the reactor or set of reactors B or drained.

13. The process of claim 11 , wherein the purifying is conducted in a crystallization unit,
wherein a crystallization mother liquor is recycled into the crystallization unit or into the reactor A or into the reactor B or drained.

14. The process of claim 13 , wherein, further comprising, after methanesulfonic acid is obtained from the purifying:
providing methanesulfonic acid anhydride for subsequent charging of reactor A with methanesulfonic acid anhydride.

15. The process of claim 14 , wherein the methanesulfonic acid anhydride in the providing comprises a separated methanesulfonic acid anhydride obtained from a further manufacturing step after the purifying or a methanesulfonic acid anhydride separated as a side-component from the purifying.

16. The process of claim 11 , wherein the preparing is conducted at a temperature in a range of from −5° C. to 25° C.,
wherein the step of reacting the initiator composition is conducted at a temperature in a range of from 25° C. to 80° C., and
wherein the bottom of the column in the purifying is at a temperature in a range of from 30° C. to 220° C.

17. The process of claim 11 , wherein the preparing is conducted at a pressure of at least 1013 mbar,
wherein the step of reacting the initiator composition is conducted at a pressure in a range of from 10 bar to 150 bar, and
wherein the purifying is conducted at a pressure in the column in a range of from 2 mbar to 1000 mbar.

18. The process of claim 7 , wherein between the step of reacting the initiator composition and the purifying, a flash is installed.

19. The process of claim 1 , wherein the methane has undergone purification in a pressure swing adsorption unit.

Assignees

• Basf Se

Inventors

• Borgmeier Frieder
• Spielmann Jan
• Zeilinger Michael
• Wortmann Juergen

Classifications

• C07C303/06 Primary

  by reaction with sulfuric acid or sulfur trioxide · CPC title

• C07C303/44

  Separation; Purification · CPC title

• C07C303/14 Primary

  by sulfoxidation, i.e. by reaction with sulfur dioxide and oxygen with formation of sulfo or halosulfonyl groups · CPC title

• C07C309/04

  containing only one sulfo group · CPC title

• B01J31/0222

  comprising sulfonyl groups · CPC title