Process for the multistage production of methanol

Patent metadata

Field	Value
Publication number	US-11247954-B2
Application number	US-202017072299-A
Country	US
Kind code	B2
Filing date	Oct 16, 2020
Priority date	Oct 16, 2019
Publication date	Feb 15, 2022
Grant date	Feb 15, 2022

Abstract

Proposed is a process for producing methanol from synthesis gas by means of multi-stage, for example 2-stage, heterogeneously catalyzed methanol synthesis, wherein the product stream of a synthesis stage is applied to the downstream synthesis stage as a feed stream or after removal of a purge stream recycled to the first synthesis stage as a recycle stream. According to the invention a substream is removed from the synthesis gas fresh gas and introduced into the second methanol synthesis reactor as a bypass stream.

First claim

What is claimed is:

1. A process for producing methanol by converting a synthesis gas input stream containing hydrogen and carbon oxides, comprising:
(a) providing the synthesis gas input stream containing hydrogen and carbon oxides, separating the synthesis gas input stream into a fresh gas bypass stream and into a fresh gas feed stream,
(b) combining and mixing the fresh gas feed stream with a recycle stream containing hydrogen and carbon oxides to afford a first reactor feed stream,
(c) introducing the first reactor feed stream into a first methanol synthesis reactor containing at least one catalyst zone comprising a solid, granular catalyst active for methanol synthesis, at least partially converting the first reactor feed stream in the first methanol synthesis reactor under methanol synthesis conditions,
(d) discharging a first reactor product stream containing methanol and water from the first methanol synthesis reactor,
(e) introducing the first reactor product stream as first part of a second reactor feed stream into a second methanol synthesis reactor containing at least one catalyst zone comprising a solid, granular catalyst active for methanol synthesis, at least partially converting the first residual gas stream in the second methanol synthesis reactor under methanol synthesis conditions,
(f) discharging a second reactor product stream containing methanol and water from the second methanol synthesis reactor, cooling the second reactor product stream below its dew point and supplying the cooled second reactor product stream to a phase separation apparatus,
(g) separating the cooled second reactor product stream in the phase separation apparatus into a liquid product stream and a gas product stream containing unconverted synthesis gas constituents,
(h) separating the gas product stream into a purge stream which is discharged from the process and into the recycle stream which is recycled to step (b),
(i) discharging the liquid product stream from the process as a crude methanol product stream, wherein,
(j) the fresh gas bypass stream is introduced as second part of the second reactor feed stream into the second methanol synthesis reactor.

2. The process according to claim 1 , wherein the fresh gas bypass stream is combined and mixed with the first reactor product stream to obtain the second reactor feed stream prior to introduction into the second methanol synthesis reactor.

3. The process according to claim 1 , wherein the quantity flow of the fresh gas bypass stream introduced into the second methanol synthesis reactor is altered on a continuous or stepwise basis over a catalyst cycle.

4. The process according to claim 3 , wherein the quantity flow of the fresh gas bypass stream introduced into the second methanol synthesis reactor is reduced on a continuous or stepwise basis over a catalyst cycle.

5. The process according to claim 4 , wherein, over a catalyst cycle the quantity flow of the fresh gas bypass stream introduced into the second methanol synthesis reactor is reduced on a continuous or stepwise basis according to the activity loss of the catalyst in the first and/or second methanol synthesis reactor.

6. The process according to claim 4 , wherein, over a catalyst cycle the quantity flow of the fresh gas bypass stream introduced into the second methanol synthesis reactor is reduced from a starting value to an end value on a continuous or stepwise basis, wherein the starting value corresponds to at most 40% by volume of the synthesis gas input stream.

7. The process according to claim 1 , wherein first methanol synthesis reactor is in the form of a water-cooled reactor (WCR) and the second methanol synthesis reactor is in the form of a water-cooled reactor (WCR) or a gas-cooled reactor (GCR), wherein the first reactor feed stream is passed as cooling gas through the second, gas-cooled methanol synthesis reactor and thus heated against the second reactor product stream in indirect heat exchange prior to introduction into the first, water-cooled methanol synthesis reactor.

8. The process according to claim 7 , wherein the second methanol synthesis reactor is in the form of a gas-cooled reactor (GCR), wherein the first reactor feed stream is passed through the second, gas-cooled methanol synthesis reactor in cocurrent with the second reactor product stream and thus heated against the second reactor product stream in indirect heat exchange.

Assignees

• Air Liquide

Inventors

• Oelmann Tobias
• Gronemann Veronika
• Hofmann Heiko
• Schuhmann Timm

Classifications

• B01J35/50

  characterised by their shape or configuration · CPC title

• C07C29/152

  characterised by the reactor used · CPC title

• C07C29/16 Primary

  by oxo-reaction combined with reduction · CPC title

• B01J19/0013

  Controlling the temperature of the process · CPC title

• C07C29/154

  containing copper, silver, gold, or compounds thereof · CPC title