Method for producing oxide particles with controlled color characteristics

Patent metadata

Field	Value
Publication number	US-11247912-B2
Application number	US-201716306225-A
Country	US
Kind code	B2
Filing date	Jun 2, 2017
Priority date	Jun 2, 2016
Publication date	Feb 15, 2022
Grant date	Feb 15, 2022

Abstract

With an aim to provide a method for producing an oxide particle with controlled color characteristics and also provide an oxide particle with controlled color characteristics, the present invention provides a method for producing an oxide particle, wherein the color characteristics of the oxide particle are controlled by controlling a ratio of an M-OH bond between an element (M) and a hydroxide group (OH) or an M-OH bond/M-O bond ratio, where the element (M) is one element or plural different elements other than oxygen or hydrogen included in the oxide particle selected from metal oxide particles and semi-metal oxide particles. According to the present invention, by controlling the M-OH bond or the M-OH bond/M-O bond ratio of the metal oxide particle or the semi-metal oxide particle, the oxide particle with controlled color characteristics of any of reflectance, transmittance, molar absorption coefficient, hue, and saturation can be provided.

First claim

The invention claimed is:

1. A method for producing an oxide particle, comprising:
changing a ratio of an M-OH bond which is a bond between an element (M) and a hydroxide group (OH) by a changing treatment of a functional group included in the oxide particle, color characteristics of the oxide particle being controlled by changing the M-OH bond ratio, where the element (M) is one element or plural different elements other than oxygen or hydrogen included in the oxide particle selected from metal oxide particles and semi-metal oxide particles,
wherein the M-OH bond ratio is a ratio of an area of a peak derived from the M-OH bond separated in wave shape in a wave number range of 800 cm −1 to 1250 cm −1 to a total area of peaks obtained by wave shape separation of peaks in a wave number range of 100 cm −1 to 1250 cm −1 in an infrared spectrum of the oxide particle measured with a total reflection method (ATR method).

2. The method for producing the oxide particle according to claim 1 , wherein the color characteristics are any of reflectance, transmittance, molar absorption coefficient, hue, or saturation.

3. The method for producing the oxide particle according to claim 1 , wherein the changing treatment of the functional group is any of a substitution reaction, an addition reaction, an elimination reaction, a dehydration reaction, a condensation reaction, or an oxidation reaction.

4. The method for producing the oxide particle according to claim 1 , wherein the changing treatment of the functional group is an esterification treatment.

5. The method for producing the oxide particle according to claim 1 , wherein the M-OH bond ratio is controlled under a state of a dispersion body in which the oxide particle is dispersed in a dispersion medium.

6. The method for producing the oxide particle according to claim 5 , wherein the dispersion body is a film, and the color characteristics of the oxide particle are controlled by a heat treatment of the dispersion body.

7. The method for producing the oxide particle according to claim 1 , wherein the M-OH bond ratio is controlled by using a dispersion solution reformation apparatus equipped with a removal unit using a filtration membrane.

8. The method for producing the oxide particle according to claim 1 , wherein the oxide particle is an oxide particle in which at least part of a surface of a single oxide particle or of a surface of an agglomerate formed by agglomeration of plural oxide particles is coated with a silicon compound.

9. The method for producing the oxide particle according to claim 1 , wherein a particle diameter of the oxide particle or the agglomerate of the oxide particles is 1 nm or more and 50 nm or less.

10. The method for producing the oxide particle according to claim 1 , wherein by controlling the M-OH bond ratio to be low, an average reflectance to the light beam with the wavelength range of 780 nm to 2500 nm is controlled to be high.

11. The method for producing the oxide particle according to claim 1 , wherein by controlling the M-OH bond ratio to be low, an average molar absorption coefficient to the light beam with the wavelength range of 190 nm to 380 nm is controlled to be high.

12. A method for producing an oxide particle, comprising:
changing an M-OH bond/M-O bond ratio, which is a ratio of an M-OH bond between an element (M) and a hydroxide group (OH) to a ratio of an M-O bond between the element (M) and oxygen (O) by a changing treatment of a functional group included in the oxide particle, color characteristics of the oxide particle being controlled by changing the M-OH bond/M-O bond ratio, where the element (M) is one element or plural different elements other than oxygen or hydrogen included in the oxide particle selected from metal oxide particles and semi-metal oxide particles.

13. The method for producing the oxide particle according to claim 12 , wherein the M-OH bond ratio is a ratio of an area of a peak derived from the M-OH bond separated in wave shape in a wave number range of 800 cm −1 to 1250 cm −1 to a total area of peaks obtained by wave shape separation of peaks in a wave number range of 100 cm −1 to 1250 cm −1 in an infrared spectrum of the oxide particle measured with a total reflection method (ATR method).

14. The method for producing the oxide particle according to claim 12 , wherein the M-O bond ratio is a ratio of an area of a peak derived from the M-O bond separated in wave shape in a wave number range of 100 cm −1 or more to less than 800 cm −1 to a total area of peaks obtained by wave shape separation of peaks in a wave number range of 100 cm −1 to 1250 cm −1 in an infrared spectrum of the oxide particle measured with a total reflection method (ATR method),
wherein the M-OH bond ratio is a ratio of an area of a peak derived from the M-OH bond separated in wave shape in a wave number range of 800 cm −1 to 1250 cm −1 to a total area of peaks obtained by wave shape separation of peaks in a wave number range of 100 cm −1 to 1250 cm −1 in an infrared spectrum of the oxide particle measured with a total reflection method (ATR method),
and the color characteristics are controlled by controlling the M-OH bond/M-O bond ratio.

15. The method for producing the oxide particle according to claim 12 , wherein the color characteristics are any of reflectance, transmittance, molar absorption coefficient, hue, or saturation.

16. The method for producing the oxide particle according to claim 12 , wherein the changing treatment of the functional group is any of a substitution reaction, an addition reaction, an elimination reaction, a dehydration reaction, a condensation reaction, or an oxidation reaction.

17. The method for producing the oxide particle according to claim 12 , wherein the M-OH bond/M-O bond ratio is controlled under a state of a dispersion body in which the oxide particle is dispersed in a dispersion medium.

18. The method for producing the oxide particle according to claim 12 , wherein the oxide particle is an oxide particle in which at least part of a surface of a single oxide particle or of a surface of an agglomerate formed by agglomeration of plural oxide particles is coated with a silicon compound.

Assignees

• M Technique Co Ltd

Inventors

• Enomura Masakazu
• Honda Daisuke

Classifications

• B22F1/056

  Submicron particles having a size above 100 nm up to 300 nm · CPC title

• B22F1/054

  Nanosized particles · CPC title

• B22F1/102

  Metallic powder coated with organic material · CPC title

• C09C3/06

  Treatment with inorganic compounds {(C09C3/006, C09C3/048 take precedence)} · CPC title

• C09C1/24

  Oxides of iron · CPC title