Material phase between conductive layers

Patent metadata

Field	Value
Publication number	US-11247165-B2
Application number	US-201816033703-A
Country	US
Kind code	B2
Filing date	Jul 12, 2018
Priority date	Jul 12, 2018
Publication date	Feb 15, 2022
Grant date	Feb 15, 2022

Abstract

A chromatograph is provided for identifying components of a mixture. Components are identified by different rates of adsorption and/or desorption with a material phase. In one embodiment, an electrical lead is connected to the material phase for supplying an electrical charge to the material phase. The electrical charge alters the rate of adsorption/desorption of the components with the material phase. In another embodiment, the material phase is disposed between two conductors with electrical leads connected to each of the conductors. A charge differential between the two conductors alters the rate of adsorption and/or desorption of components with the material phase.

First claim

The invention claimed is:

1. A chromatograph or molecular separation device, comprising:
a first conductor with a first electrical lead connected thereto, the first conductor being permeable to permit a mixture to pass therethrough;
a second conductor with a second electrical lead connected thereto; and
a material phase disposed between the first and second conductors, the material phase being configured to be exposed to the mixture passing through the first conductor, the mixture comprising a plurality of components having different rates of adsorption and/or desorption with the material phase;
wherein a first electrical charge is supplied to the first conductor with the first electrical lead and a second electrical charge is supplied to the second conductor with the second electrical lead, a charge differential thereby being applied across the material phase, the charge differential altering the rates of adsorption and/or desorption of the components of the mixture with the material phase.

2. The chromatograph or molecular separation device according to claim 1 , wherein the material phase comprises a dielectric material.

3. The chromatograph or molecular separation device according to claim 1 , wherein the material of the material phase comprises a polymeric material.

4. The chromatograph or molecular separation device according to claim 3 , wherein the polymeric material undergoes deformation in response to applied electrical forces such that the sorption energy is substantially altered for molecules sorbed within the polymer.

5. The chromatograph or molecular separation device according to claim 3 , wherein the polymeric material comprises dielectric elastomers, ferroelectric polymers, electrostrictive polyurethane polyethers and polyesters, and/or electrostrictive graft polymers.

6. The chromatograph or molecular separation device according to claim 1 , wherein the first conductor comprises a lattice of conductive particles or fibers.

7. The chromatograph or molecular separation device according to claim 1 , wherein the first conductor comprises a conductive polymer.

8. The chromatograph or molecular separation device according to claim 7 , wherein the conductive polymer is permeable.

9. The chromatograph or molecular separation device according to claim 1 , wherein the first and second electrical charges define a DC voltage therebetween.

10. The chromatograph or molecular separation device according to claim 1 , wherein the first and second electrical charges define a voltage therebetween, a capacitive charge thereby being applied to the material phase, and an electrical property being measured therefrom to detect a status of the material phase.

11. The chromatograph or molecular separation device according to claim 1 , further comprising a silicon substrate with one or more layers or patterns deposited thereon, wherein the second conductor comprises the silicon substrate or one of the one or more layers, and the material phase and the first conductor each comprise one of the one or more layers.

12. The chromatograph or molecular separation device according to claim 11 , further comprising a channel etched into the silicon substrate and/or the one or more layers deposited thereon, the material phase and the first conductor each being deposited in the channel, and the channel being configured to flow the mixture therethrough.

13. The chromatograph or molecular separation device according to claim 1 , wherein the second conductor comprises a substrate of a first material with a smooth surface and a second different material disposed on the smooth surface defining a greater surface area than the smooth surface of the substrate, the material phase being conformally disposed over the smooth surface and the second different material, and the first conductor being conformally disposed over the material phase, the material phase and the first conductor thereby defining a greater surface area than the smooth surface of the substrate.

14. The chromatograph or molecular separation device according to claim 1 , wherein the second conductor comprises a substrate with a roughened surface comprising protrusions or recesses formed thereon, the material phase being conformally disposed over the roughened surface, and the first conductor being conformally disposed over the material phase, the material phase and the first conductor thereby defining a three-dimensional surface.

15. The chromatograph or molecular separation device according to claim 1 , wherein the second conductor comprises a substrate with a smooth surface, the material phase being disposed over the smooth surface of the substrate, and the second conductor being disposed over the material phase.

16. The chromatograph or molecular separation device according to claim 1 , wherein at least one of the first and second electrical charges is cyclically varied to create increased adsorption during one period of a cycle and increased desorption during another period of the cycle.

17. The chromatograph or molecular separation device according to claim 1 , wherein the material phase comprises a dielectric material, the dielectric material comprising a polymeric material.

18. The chromatograph or molecular separation device according to claim 17 , wherein the polymeric material undergoes deformation in response to applied electrical forces such that the sorption energy is substantially altered for molecules sorbed within the polymer, and the first conductor comprises a lattice of conductive particles or fibers or a permeable conductive polymer.

19. The chromatograph or molecular separation device according to claim 18 , wherein the first and second electrical charges define a DC voltage therebetween.

20. The chromatograph or molecular separation device according to claim 19 , further comprising a silicon substrate with one or more layers or patterns deposited thereon, wherein the second conductor comprises the silicon substrate or one of the one or more layers, and the material phase and the first conductor each comprise one of the one or more layers, and further comprising a channel etched into the silicon substrate and/or the one or more layers deposited thereon, the material phase and the first conductor each being deposited in the channel, and the channel being configured to flow the mixture therethrough.

Assignees

• Abb Schweiz Ag

Inventors

• Nicholas Nolan W
• Morgan Thomas

Classifications

• B01D15/3885 Primary

  using electrical or magnetic means · CPC title

• B01D53/025 Primary

  with wetted adsorbents; Chromatography (analytical chromatography G01N30/00 - G01N30/96; for liquids B01D15/08) · CPC title