Chalcogen-containing compound, its preparation method and thermoelectric element comprising the same

Patent metadata

Field	Value
Publication number	US-11245062-B2
Application number	US-201916756019-A
Country	US
Kind code	B2
Filing date	Aug 23, 2019
Priority date	Aug 24, 2018
Publication date	Feb 8, 2022
Grant date	Feb 8, 2022

Abstract

A chalcogen-containing compound of the following Chemical Formula 1, which may have decreased thermal conductivity and improved power factor in the low temperature region, and thus exhibit an excellent thermoelectric figure of merit, a method for preparing the same, and a thermoelectric element including the same:V1Sna−xInxSb2Tea+3  [Chemical Formula 1]wherein V, a and x are as defined in the specification.

First claim

The invention claimed is:

1. A chalcogen-containing compound represented by the following Chemical Formula 1:
V 1 Sn a−x In x Sb 2 Te a+3   [Chemical Formula 1]

wherein,
V is a vacancy,
14≤a≤16, and 0<x≤0.5.

2. The chalcogen-containing compound according to claim 1 , wherein 0.01≤x≤0.2.

3. The chalcogen-containing compound according to claim 1 , wherein the chalcogen-containing compound has a face-centered cubic lattice structure.

4. The chalcogen-containing compound according to claim 3 , wherein the V is a vacant site excluding sites filled with Sn, Sb, and Te in the face-centered cubic lattice structure, and
the In is substituted for a part of Sn.

5. The chalcogen-containing compound according to claim 3 , wherein the Te is filled in anionic sites of the face-centered cubic lattice structure,
the Sn and Sb are filled in cationic sites of the face-centered cubic lattice structure,
the In is substituted for a part of Sn, and
the V is a vacant site of remaining cationic sites excluding sites filled with Sn, Sb, and In.

6. The chalcogen-containing compound according to claim 3 , wherein the V, Sn, Sb, and In are randomly distributed at the site of (x, y, z)=(0, 0, 0), and Te is distributed at the site of (x, y, z)=(0.5, 0.5, 0.5).

7. The chalcogen-containing compound according to claim 1 , wherein a is 14, and the chalcogen-containing compound has a face-centered cubic lattice structure, a lattice constant of 6.2850 Å to 6.2861 Å, and a weighted pattern R (Rwp) of 5.900 to 5.990.

8. The chalcogen-containing compound according to claim 1 , wherein a is 16, and the chalcogen-containing compound has a face-centered cubic lattice structure, a lattice constant of 6.2880 Å to 6.2900 Å, and a weighted pattern R (Rwp) of 4.900 to 5.100.

9. The chalcogen-containing compound according to claim 1 , wherein the chalcogen-containing compound is selected from the group consisting of V 1 Sn 13.9 In 0.1 Sb 2 Te 17 , V 1 Sn 13.8 In 0.2 Sb 2 Te 17 , V 1 Sn 15.9 In 0.1 Sb 2 Te 19 , and V 1 Sn 15.8 In 0.2 Sb 2 Te 19 .

10. A method for preparing the chalcogen-containing compound of claim 1 , comprising the steps of:
mixing respective raw materials of Sn, Sb, Te, and In in amounts such that the mole ratio of Sn:Sb:Te:In is (a−x):2:(a+3):x, and subjecting the resultant mixture to a melting reaction;
heat-treating the resultant product obtained through the melting reaction;
pulverizing the resultant product obtained through the heat treatment; and
sintering the pulverized product.

11. The method for preparing the chalcogen-containing compound according to claim 10 , wherein the melting reaction is conducted at a temperature of 700° C. to 900° C.

12. The method for preparing the chalcogen-containing compound according to claim 10 , wherein the heat treatment is conducted at a temperature of 550° C. to 640° C.

13. The method for preparing the chalcogen-containing compound according to claim 10 , further comprising a step of cooling the resultant product of the heat treatment step to form an ingot, between the heat treatment step and the pulverization step.

14. The method for preparing the chalcogen-containing compound according to claim 10 , wherein the sintering is conducted by a spark plasma sintering method, at a temperature of 550° C. to 640° C. and a pressure of 10 MPa to 100 MPa.

15. A thermoelectric element comprising the chalcogen-containing compound according to claim 1 .

Assignees

• Lg Chemical Ltd

Inventors

• Kim Minkyoung
• Park Cheol Hee
• Park Chee Sung
• Jung Myungjin

Classifications

• C30B29/46

  Sulfur-, selenium- or tellurium-containing compounds · CPC title

• C01P2002/77

  by unit-cell parameters, atom positions or structure diagrams · CPC title

• C01B19/002 Primary

  Compounds containing, besides selenium or tellurium, more than one other element, with -O- and -OH not being considered as anions · CPC title

• C01P2002/52

  containing elements as dopants · CPC title

• C01P2002/78

  by stacking-plane distances or stacking sequences · CPC title