Hexagonal strontium ferrite powder for magnetic recording and magnetic recording medium

Patent metadata

Field	Value
Publication number	US-11244701-B2
Application number	US-201816008147-A
Country	US
Kind code	B2
Filing date	Jun 14, 2018
Priority date	Jun 14, 2017
Publication date	Feb 8, 2022
Grant date	Feb 8, 2022

Abstract

Provided is hexagonal strontium ferrite powder for magnetic recording, in which an activation volume is 800 to 1,500 nm3, a content of rare earth atom with respect to 100 atom % of iron atom is 0.5 to 5.0 atom %, and a rare earth atom surface portion uneven distribution is provided.

First claim

What is claimed is:

1. Hexagonal strontium ferrite powder,
wherein the activation volume of the hexagonal strontium ferrite powder is 800 to 1,500 nm 3 ,
the bulk content of rare earth atom with respect to 100 atom % of iron atom of the hexagonal strontium ferrite powder is 0.5 to 5.0 atom %,
the hexagonal strontium ferrite powder is hexagonal strontium ferrite powder for magnetic recording, and has a rare earth atom surface portion uneven distribution, and
the following ratio, namely, the surface portion content of the rare earth atom/the bulk content of the rare earth atom, of the hexagonal strontium ferrite powder is greater than 1.0, where:
the surface portion content of the rare earth atom is a rare earth atom content with respect to 100 atom % of iron atom in a solution obtained by partially dissolving the hexagonal strontium ferrite powder with acid under the following partial dissolving condition, and
the bulk content of the rare earth atom is a rare earth atom content with respect to 100 atom % of iron atom in a solution obtained by totally dissolving the hexagonal strontium ferrite powder with acid under the following total dissolving condition:
partial dissolving condition: a vessel containing 12 mg of the hexagonal strontium ferrite powder and 10 ml of hydrochloric acid having a concentration of 1 mol/L is held on a hot plate at a set temperature of 70° C. for 1 hour; and
total dissolving condition: a vessel containing 12 mg of the hexagonal strontium ferrite powder and 10 ml of hydrochloric acid having a concentration of 4 mol/L is held on a hot plate at a set temperature of 80° C. for 3 hours.

2. The hexagonal strontium ferrite powder for magnetic recording according to claim 1 ,
wherein the rare earth atom comprises a neodymium atom.

3. The hexagonal strontium ferrite powder for magnetic recording according to claim 1 ,
wherein the rare earth atom comprises a samarium atom.

4. The hexagonal strontium ferrite powder for magnetic recording according to claim 1 ,
wherein the rare earth atom comprises an yttrium atom.

5. The hexagonal strontium ferrite powder for magnetic recording according to claim 1 ,
wherein the rare earth atom comprises a dysprosium atom.

6. The hexagonal strontium ferrite powder for magnetic recording according to claim 1 ,
wherein the activation volume is 800 to 1,100 nm 3 .

7. The hexagonal strontium ferrite powder for magnetic recording according to claim 1 ,
wherein an anisotropy constant Ku is equal to or greater than 2.0×10 6 erg/cc.

8. The hexagonal strontium ferrite powder for magnetic recording according to claim 1 ,
wherein a mass magnetization σs is equal to or greater than 45 A·m 2 /kg.

9. A magnetic recording medium comprising:
a non-magnetic support; and
a magnetic layer including ferromagnetic powder and a binding agent on the non-magnetic support,
wherein the ferromagnetic powder is hexagonal strontium ferrite powder,
the activation volume of the hexagonal strontium ferrite powder is 800 to 1,500 nm 3 ,
the bulk content of rare earth atom with respect to 100 atom % of iron atom of the hexagonal strontium ferrite powder is 0.5 to 5.0 atom %,
the hexagonal strontium ferrite powder has a rare earth atom surface portion uneven distribution, and
the following ratio, namely, the surface portion content of the rare earth atom/the bulk content of the rare earth atom, of the hexagonal strontium ferrite powder is greater than 1.0, where:
the surface portion content of the rare earth atom is a rare earth atom content with respect to 100 atom % of iron atom in a solution obtained by partially dissolving the hexagonal strontium ferrite powder with acid under the following partial dissolving condition, and
the bulk content of the rare earth atom is a rare earth atom content with respect to 100 atom % of iron atom in a solution obtained by totally dissolving the hexagonal strontium ferrite powder with acid under the following total dissolving condition:
partial dissolving condition: a vessel containing 12 mg of the hexagonal strontium ferrite powder and 10 ml of hydrochloric acid having a concentration of 1 mol/L is held on a hot plate at a set temperature of 70° C. for 1 hour; and
total dissolving condition: a vessel containing 12 mg of the hexagonal strontium ferrite powder and 10 ml of hydrochloric acid having a concentration of 4 mol/L is held on a hot plate at a set temperature of 80° C. for 3 hours.

10. The magnetic recording medium according to claim 9 ,
wherein the rare earth atom comprises a neodymium atom.

11. The magnetic recording medium according to claim 9 ,
wherein the rare earth atom comprises a samarium atom.

12. The magnetic recording medium according to claim 9 ,
wherein the rare earth atom comprises an yttrium atom.

13. The magnetic recording medium according to claim 9 ,
wherein the rare earth atom comprises a dysprosium atom.

14. The magnetic recording medium according to claim 9 ,
wherein the activation volume is 800 to 1,100 nm 3 .

15. The magnetic recording medium according to claim 9 ,
wherein an anisotropy constant Ku of the hexagonal strontium ferrite powder is equal to or greater than 2.0×10 6 erg/cc.

16. The magnetic recording medium according to claim 9 ,
wherein a mass magnetization σs of the hexagonal strontium ferrite powder is equal to or greater than 45 A·m 2 /kg.

17. The hexagonal strontium ferrite powder for magnetic recording according to claim 1 ,
wherein the recited ratio, namely, the surface portion content of the rare earth atom/the bulk content of the rare earth atom, of the hexagonal strontium ferrite powder is equal to or greater than 1.5.

18. The magnetic recording medium according to claim 9 ,
wherein the recited ratio, namely, the surface portion content of the rare earth atom/the bulk content of the rare earth atom, of the hexagonal strontium ferrite powder is equal to or greater than 1.5.

19. The hexagonal strontium ferrite powder for magnetic recording according to claim 1 ,
wherein the recited ratio, namely, the surface portion content of the rare earth atom/the bulk content of the rare earth atom, of the hexagonal strontium ferrite powder is equal to or greater than 1.9.

20. The magnetic recording medium according to claim 9 ,
wherein the recited ratio, namely, the surface portion content of the rare earth atom/the bulk content of the rare earth atom, of the hexagonal strontium ferrite powder is equal to or greater than 1.9.

21. The hexagonal strontium ferrite powder for magnetic recording according to claim 1 ,
wherein the activation volume of the hexagonal strontium ferrite powder is 895 to 1,500 nm 3 ,
the bulk content of rare earth atom with respect to 100 atom % of iron atom of the hexagonal strontium ferrite powder is 1.0 to 5.0 atom %, and
the rare earth atom is a neodymium atom.

22. The magnetic recording medium according to claim 9 ,
wherein the activation volume of the hexagonal strontium ferrite powder is 895 to 1,500 nm 3 ,
the bulk content of rare earth atom with respect to 100 atom % of iron atom of the hexagonal strontium ferrite powder is 1.0 to 5.0 atom %, and
the rare earth atom is a neodymium atom.

Assignees

• Fujifilm Corp
• FUJIFILM Cornoration

Inventors

• Naoi Kenji
• Shirata Masashi

Classifications

• C01G49/0036

  containing one alkaline earth metal, magnesium or lead · CPC title

• C01G49/0018

  Mixed oxides or hydroxides, (C01G49/0009 takes precedence) · CPC title

• G11B5/70678 Primary

  Ferrites · CPC title

• C01P2006/42

  Magnetic properties · CPC title

• G11B5/714

  characterised by the dimension of the magnetic particles · CPC title