Biobinder

Patent metadata

Field	Value
Publication number	US-11242629-B2
Application number	US-201515502836-A
Country	US
Kind code	B2
Filing date	Aug 25, 2015
Priority date	Aug 25, 2014
Publication date	Feb 8, 2022
Grant date	Feb 8, 2022

Abstract

The invention relates to an aqueous binder composition for mineral fibers comprising a component (i) in the form of one or more compounds selected from —compounds of the formula, and any salts thereof. In which R1 corresponds to H, alkyl, monohydroxyalkyl, dihydroxyalkyl, polyhydroxyalkyl, alkylene, alkoxy, amine; —compounds of the formula, and any salts thereof. In which R2 corresponds to H, alkyl, monohydroxyalkyl, dihydroxyalkyl, polyhydroxyalkyl, alkylene, alkoxy, amine; a component (ii) in the form of one or more compounds selected from the group of ammonia, amines or any salts thereof; a component (iii) in the form of one or more carbohydrates.

First claim

The invention claimed is:

1. An aqueous binder composition for mineral fibers, wherein the composition comprises
(a) a component (i) in the form of one or more compounds selected from one or both of
compounds of formula

and salts thereof, in which R1 represents H, alkyl, monohydroxyalkyl, dihydroxyalkyl, polyhydroxyalkyl, alkylene, alkoxy, amine;
compounds of the formula

and salts thereof, in which R2 represents H, alkyl, monohydroxyalkyl, dihydroxyalkyl, polyhydroxyalkyl, alkylene, alkoxy, amine;
(b) a component (ii) in the form of one or more compounds selected from ammonia, amines, and salts thereof;
(c) a component (iii) in the form of one or more carbohydrates;
and wherein >95 weight-% of a total solids content of the composition is formed by component (i), component (ii), component (iii), optionally present component (iv) selected from mineral acids and salts thereof, optionally present component (v) in the form of one or more reactive or non-reactive silicones and optionally present urea, based on binder composition solids content.

2. The composition of claim 1 , wherein component (i) comprises one or more compounds selected from L-ascorbic acid, D-isoascorbic acid, 5,6-isopropylidene ascorbic acid, dehydroascorbic acid, salts of these compounds.

3. The composition of claim 1 , wherein component (i) comprises one or more compounds selected from calcium, sodium, potassium, magnesium and iron salts of one or more of L-ascorbic acid, D-isoascorbic acid, 5,6-isopropylidene ascorbic acid, and dehydroascorbic acid.

4. The composition of claim 1 , wherein component (ii) comprises one or more of ammonia, piperazine, hexadimethylenediamine, m-xylylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, monoethanolamine, diethanolamine, and triethanolamine.

5. The composition of claim 1 , wherein component (iii) comprises one or more of dextrose, glucose syrup, xylose, fructose, sucrose.

6. The composition of claim 1 , wherein component (i) comprises ascorbic acid, component (ii) comprises one or more of ammonia, diethanolamine, and triethanolamine, and component (iii) comprises one or both of dextrose and a glucose syrup having a dextrose equivalent (DE) of from 60 to 99.

7. The composition of claim 1 , wherein the composition comprises from 1 to 50 weight-% of component (i), based on a mass of components (i) and (iii), from 50 to 99 weight-% of component (iii), based on the mass of components (i) and (iii), and from 0.1 to 10.0 molar equivalents of component (ii), relative to component (i).

8. The composition of claim 1 , wherein the composition comprises from 0.05 to 10 weight-% of component (iv), based on a mass of components (i) and (iii).

9. The composition of claim 1 , wherein component (iv) comprises one or more of an ammonium sulfate salt, an ammonium nitrate salt, and an ammonium carbonate salt.

10. The composition of claim 9 , wherein component (iv) comprises an ammonium sulfate salt.

11. The composition of claim 1 , wherein component (iv) comprises one or more of sulfuric acid, nitric acid, boric acid, hypophosphorous acid, and phosphoric acid.

12. The composition of claim 11 , wherein component (iv) comprises one or both of sulfuric acid and hypophosphorous acid.

13. The composition of claim 1 , wherein the composition further comprises a component (v) in the form of one or more reactive or non-reactive silicones.

14. The composition of claim 13 , wherein component (v) comprises one or more silicones constituted of a main chain composed of organosiloxane residues bearing at least one hydroxyl, carboxyl or anhydride, amine, epoxy or vinyl functional group that is capable of reacting with at least one constituent of the binder composition.

15. The composition of claim 14 , wherein the composition comprises from 0.1 to 15 weight-% of component (v), based on a solids content of the composition.

16. The composition of claim 14 , wherein the organosiloxane residues comprise one or more of a diphenylsiloxane residue and an alkylsiloxane residue.

17. The composition of claim 1 , wherein the composition further comprises urea.

18. A method of producing a bonded mineral fiber product, wherein the method comprises contacting mineral fibers with the binder composition of claim 1 , and curing the binder composition.

19. A mineral fiber product, wherein the product comprises mineral fibers in contact with a cured product of the binder composition of claim 1 .

20. The composition of claim 1 , wherein the composition is formaldehyde-free.

Assignees

• Rockwool Int

Inventors

• Hjelmgaard Thomas
• Nissen Povl
• Hansen Erling Lennart
• Naerum Lars

Classifications

• C09J103/02

  Starch; Degradation products thereof, e.g. dextrin · CPC title

• C08L33/00

  Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers · CPC title

• C08L5/00

  Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00 · CPC title

• C08J5/08

  glass fibres · CPC title

• C13K1/00 Primary

  Glucose (separation from invert sugar C13K3/00); Glucose-containing syrups · CPC title