Sintered Ni ferrite body, coil device, and method for producing sintered Ni ferrite body

Patent metadata

Field	Value
Publication number	US-11242288-B2
Application number	US-201816493571-A
Country	US
Kind code	B2
Filing date	Mar 15, 2018
Priority date	Mar 15, 2017
Publication date	Feb 8, 2022
Grant date	Feb 8, 2022

Abstract

A sintered Ni ferrite body having a composition comprising, calculated as oxide, 47.0-48.3% by mol of Fe 2 O 3 , 14.5% or more and less than 25% by mol of ZnO, 8.2-10.0% by mol of CuO, and more than 0.6% and 2.5% or less by mol of CoO, the balance being NiO and inevitable impurities, and having an average crystal grain size of more than 2.5 μm and less than 5.5 μm.

First claim

What is claimed is:

1. A sintered Ni ferrite body having a composition comprising, calculated as oxide, 47.0-48.3% by mol of Fe 2 O 3 , 14.5% or more and less than 25% by mol of ZnO, 8.2-10.0% by mol of CuO, and more than 0.6% and 2.5% or less by mol of CoO, the balance being NiO and inevitable impurities, and having an average crystal grain size of more than 2.5 μm and less than 5.5 μm.

2. The sintered Ni ferrite body according to claim 1 , wherein less than 4 parts by mass of Sn calculated as SnO 2 , based on 100 parts by mass of the total amount of Fe 2 O 3 , ZnO, CuO, CoO and NiO, is contained.

3. The sintered Ni ferrite body according to claim 1 , which has a composition comprising, calculated as oxide, 47.3-48.2% by mol of Fe 2 O 3 , 14.8-24.8% by mol of ZnO, 8.3-9.5% by mol of CuO, and 0.65-2.4% by mol of CoO, the balance being NiO and inevitable impurities.

4. The sintered Ni ferrite body according to claim 1 , wherein said sintered Ni ferrite body has a density of 4.85 g/cm 3 or more.

5. The sintered Ni ferrite body according to claim 1 , wherein said sintered Ni ferrite body has core loss Pcv20 of 1800 kW/m 3 or less at 20° C. and core loss Pcv100 of 3000 W/m 3 or less at 100° C., at a frequency of 5 MHz and at an exciting magnetic flux density of 20 mT.

6. The sintered Ni ferrite body according to claim 5 , wherein the minimum temperature of core loss Pcv is less than 80° C.

7. The sintered Ni ferrite body according to claim 5 , wherein a core loss change ratio Ps calculated by the following formula (1):
Ps (%)=[( Pcv 100 −Pcv 20)/ Pcv 20]×100  (1),

is 185% or less.

8. A coil device formed by winding a wire around a magnetic core made of said sintered Ni ferrite body of claim 1 .

9. A method for producing said sintered Ni ferrite body of claim 1 , comprising the steps of
mixing an iron oxide powder, a zinc oxide powder, a copper oxide powder, and a nickel oxide powder to form a raw material powder;
calcining the raw material powder at a temperature of 700-850° C. to form a calcined body;
pulverizing the calcined body with cobalt oxide, or cobalt oxide and tin oxide, for 0.5-8 hours to form a pulverized powder,
molding the pulverized powder to form a green body, and
sintering the green body at a temperature of 900-1000° C.

10. The method for producing said sintered Ni ferrite body according to claim 9 , wherein said pulverized powder has a particle size of 0.5-1.5 μm.

11. The sintered Ni ferrite body according to claim 1 , wherein said sintered Ni ferrite body has an average crystal grain size of more than 3.0 μm and less than 5.5 μm.

Assignees

• Hitachi Metals Ltd

Inventors

• Tanaka Satoru
• Koyuhara Norikazu
• Tada Tomoyuki

Classifications

• C04B35/2608 Primary

  Compositions containing one or more ferrites of the group comprising manganese, zinc, nickel, copper or cobalt and one or more ferrites of the group comprising rare earth metals, alkali metals, alkaline earth metals or lead · CPC title

• C04B35/265 Primary

  Compositions containing one or more ferrites of the group comprising manganese or zinc and one or more ferrites of the group comprising nickel, copper or cobalt · CPC title

• C04B35/64

  Burning or sintering processes (C04B33/32 takes precedence {; powder metallurgy B22F}) · CPC title

• C04B2235/77

  Density · CPC title

• C04B2235/786

  Micrometer sized grains, i.e. from 1 to 100 micron · CPC title