Methods for using isotopic signatures to determine characteristics of hydrocarbon sources

Patent metadata

Field	Value
Publication number	US-11237147-B2
Application number	US-201815971691-A
Country	US
Kind code	B2
Filing date	May 4, 2018
Priority date	May 8, 2017
Publication date	Feb 1, 2022
Grant date	Feb 1, 2022

Abstract

Described herein are methods and techniques for determining one or more characteristics of a hydrocarbon source. The method comprises obtaining a hydrocarbon fluid sample, determining at least one measured clumped isotope signature or measured position specific isotope signature for at least one hydrocarbon species of interest in the hydrocarbon fluid sample, determining at least one expected clumped isotope signature or expected position specific isotope signature for the hydrocarbon species of interest, comparing the measured clumped isotope signature or measured position specific isotope signature with the expected clumped isotope signature or expected position specific isotope signature, and determining at least one characteristic of the source of the hydrocarbon sample based on the comparison.

First claim

The invention claimed is:

1. A method for determining one or more characteristics of a hydrocarbon source, comprising:
obtaining a hydrocarbon fluid sample;
analyzing the hydrocarbon fluid sample to determine at least one measured clumped isotope signature or measured position specific isotope signature for at least one hydrocarbon species in the hydrocarbon fluid sample;
determining at least one expected clumped isotope signature or expected position specific isotope signature, where the expected clumped isotope signature or expected position specific isotope signature are determined from a model that reflects different source compositions, isotopic structures, and kinetic processes, and wherein the model is solved using a kinetic Monte Carlo simulation;
comparing the measured clumped isotope signature or measured position specific isotope signature with the expected clumped isotope signature or expected position specific isotope signature;
determining at least one characteristic of the source of the hydrocarbon sample based on the comparison; and
developing or refining a hydrocarbon exploration, development, or production strategy based at least in part on the determined characteristic.

2. The method of claim 1 , wherein the hydrocarbon fluid sample comprises hydrocarbons and associated gases.

3. The method of claim 2 , wherein the associated gases comprise carbon dioxide.

4. The method of claim 1 , wherein the hydrocarbon fluid sample comprises at least one of methane, ethane, propane, butane, pentane, hexane, heptane, octane, nonane, decane, and combinations thereof.

5. The method of claim 1 , wherein the hydrocarbon fluid sample is a gas sample.

6. The method of claim 1 , wherein the position specific isotope signature of a hydrocarbon species identifies the difference between the number of 13 C atoms at central positions within hydrocarbon molecules of the hydrocarbon species and the number of 13 C atoms at terminal positions within hydrocarbon molecules of the hydrocarbon species.

7. The method of claim 1 , wherein the position specific isotope signature is a position specific isotope signature of propane.

8. The method of claim 1 , wherein the clumped isotope signature identifies the ratio of ethane molecules that have two 13 C atoms.

9. The method of claim 1 , further comprising running one or more simulations of the model that comprises:
identifying isotopic sequences of interest;
identifying a representative group of staring molecules that contain the isotopic sequence of interest;
identify the proportion or ratio of the starting molecules in the representative group;
identifying the probability of the cracking reaction occurring to the molecules in the representative group; and
identifying the molecules to be broken.

10. The method of claim 1 , further comprising performing two or more simulations of the model, wherein each simulation uses a different initial molecule population.

11. The method of claim 10 , wherein the two or more simulations of the model produce different expected clumped isotope signatures or expected position specific isotope signatures.

12. The method of claim 11 , wherein each of the expected clumped isotope signatures or expected position specific isotope signatures is associated with a different hydrocarbon source.

13. The method of claim 12 , further comprising comparing the measured clumped isotope signatures or expected position specific isotope signatures with each of the expected clumped isotope signatures or expected position specific isotope signatures, and using the comparison to identify the source from which the hydrocarbon fluid sample was obtained.

14. The method of claim 1 , further comprising using the comparison to de-risk a basin model of a hydrocarbon reservoir.

15. A method for determining where to drill a well in a hydrocarbon reservoir, comprising:
providing a basin model of the hydrocarbon reservoir;
obtaining a hydrocarbon fluid sample from the hydrocarbon reservoir;
analyzing the hydrocarbon fluid sample to determine at least one measured clumped isotope signature or measured position specific isotope signature for at least one hydrocarbon species in the hydrocarbon fluid sample;
determining at least one expected clumped isotope signature or expected position specific isotope signature, where the expected clumped isotope signature or expected position specific isotope signature is determined from a model that reflects different source compositions, isotopic structures, and kinetic processes associated with the hydrocarbon reservoir, and wherein the model is solved using a kinetic Monte Carlo simulation;
comparing the measured clumped isotope signature or measured position specific isotope signature with the expected clumped isotope signature or expected position specific isotope signature;
using the comparison to identify an expected source of the hydrocarbons in the basin model; and
causing a well to be drilled to obtain hydrocarbon from the hydrocarbon reservoir.

Assignees

• Peterson Brian K
• Lawson Michael
• Formolo Michael J
• Higgins Meytal B
• Exxonmobil Upstream Res Co

Inventors

• Peterson Brian K
• Lawson Michael
• Formolo Michael J
• Higgins Meytal B

Classifications

• G01V9/007

  by detecting gases or particles representative of underground layers at or near the surface (analysing earth materials G01N33/24; analysing gases per se G01N) · CPC title

• E21B47/11

  using tracers; using radioactivity · CPC title

• G01N33/241 Primary

  for hydrocarbon content · CPC title

• G01N33/2823

  Raw oil, drilling fluid or polyphasic mixtures · CPC title

• G01N29/14

  using acoustic emission techniques {(echo of particles G01N29/046; measuring mechanical vibrations or acoustic waves in solids in general G01H1/00)} · CPC title