Method for preparing inorganic halogenated lead cesium perovskite quantum dots and display device

Patent metadata

Field	Value
Publication number	US-11236268-B2
Application number	US-201916462935-A
Country	US
Kind code	B2
Filing date	Feb 20, 2019
Priority date	Oct 25, 2018
Publication date	Feb 1, 2022
Grant date	Feb 1, 2022

Abstract

A method for preparing inorganic halogenated lead perovskite quantum dots and a display device are provided. The method includes: a first coordination solution preparing step, a cesium oleate solution preparing step, a centrifugal separation step, a second coordination solution preparing step, a first ion exchange step, and a second ion exchange step. The present invention also provides a display device including a quantum dot layer, wherein luminescent quantum dots of the quantum dot layer are inorganic halogenated lead cesium perovskite quantum dots of the present invention.

First claim

What is claimed is:

1. A method for preparing inorganic halogenated lead perovskite quantum dots (PQDs), comprising the following steps:
a first coordination solution preparing step, comprising mixing and heating a first lead halide solid and a first solvent in a reaction vessel until the first lead halide solid is completely dissolved to obtain a first coordination solution;
a cesium oleate solution preparing step, comprising mixing and heating a cesium carbonate solid and a second solvent in a container until the cesium carbonate solid is completely dissolved;
a centrifugal separation step, comprising heating the first coordination solution and adding the cesium oleate solution to the first coordination solution, cooling the first coordination solution to room temperature to obtain a first mixed solution, and centrifuging the first mixed solution to obtain first quantum dots;
a second coordination solution preparing step, comprising mixing and heating a second lead halide solid and the first solvent in a reaction vessel until the second lead halide solid is completely dissolved to obtain a second coordination solution; and
a first ion exchange step, comprising re-dispersing the first quantum dots in a non-polar organic solvent, adding the second coordination solution dropwise to the non-polar organic solvent, performing an ion exchange reaction to obtain a second mixed solution, and centrifuging the second mixed solution to obtain second quantum dots; wherein
the first quantum dots and the second quantum dots are both the inorganic halogenated lead perovskite quantum dots.

2. The method for preparing the inorganic halogenated lead perovskite quantum dots according to claim 1 , wherein halogen elements of the first lead halide solid and the second lead halide solid are any one of Br, I, and Cl, and the halogen element of the first lead halide solid is different from the halogen element of the second lead halide solid.

3. The method of preparing the inorganic halogenated lead perovskite quantum dots according to claim 1 , wherein the first solvent comprises oleic acid, oleyl amine, and the non-polar organic solvent.

4. The method for preparing the inorganic halogenated lead perovskite quantum dots according to claim 3 , wherein the non-polar organic solvent is dodecane or octadecene.

5. The method for preparing the inorganic halogenated lead perovskite quantum dots according to claim 3 , wherein in the first solvent, a volume ratio of the oleic acid, the oleyl amine, and the non-polar organic solvent is 1-2:1-2:4-8.

6. The method for preparing the inorganic halogenated lead perovskite quantum dots according to claim 1 , wherein
in the cesium oleate solution preparing step, the second solvent comprises oleic acid and octadecene solvent, and the heating is carried out at a temperature of 120-150 degrees in Celsius; and
in the centrifugal separation step, the heating is carried out at a temperature of 180 to 200 degrees in Celsius.

7. The method for preparing the inorganic halogenated lead perovskite quantum dots according to claim 1 , wherein a structure and a diameter of each of the first quantum dots are consistent with a structure and a diameter of each of the second quantum dots.

8. The method for preparing the inorganic halogenated lead perovskite quantum dots according to claim 1 , wherein the first ion exchange step further comprises:
a third coordination solution preparing step, comprising mixing and heating a third lead halide solid and the first solvent in a reaction vessel until the third lead halide solid is completely dissolved to obtain a third coordination solution; and
a second ion exchange step, comprising re-dispersing the second quantum dots in a non-polar organic solvent, adding the third coordination solution in drops to the non-polar organic solvent, performing an ion exchange reaction to obtain a third mixed solution, and centrifuging the third mixed solution to obtain third quantum dots, each of which is the inorganic halogenated lead perovskite quantum dot.

9. The method for preparing the inorganic halogenated lead perovskite quantum dots according to claim 8 , wherein halogen elements of the second lead halide solid and the third lead halide solid are any one of Br, I, and Cl, and the halogen element of the second lead halide solid is different from the halogen element of the third lead halide solid.

Assignees

• Wuhan China Star Optoelectronics Semiconductor Display Tech Co Ltd

Inventors

• Chen Xu

Classifications

• H10H20/812

  within the light-emitting regions, e.g. having quantum confinement structures · CPC title

• H10H20/822

  Materials of the light-emitting regions · CPC title

• C09K11/772 Primary

  with alkali or alkaline earth metals · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• C09K11/665 Primary

  with alkali or alkaline earth metals · CPC title