Latex composition and film molded body

Patent metadata

Field	Value
Publication number	US-11236218-B2
Application number	US-201716078554-A
Country	US
Kind code	B2
Filing date	Feb 24, 2017
Priority date	Sep 30, 2016
Publication date	Feb 1, 2022
Grant date	Feb 1, 2022

Abstract

A latex composition has a latex of a carboxyl group-containing conjugated diene rubber and a metal compound including a trivalent or higher metal, wherein a content of the metal compound is 0.1 to 1.5 parts by weight, based on 100 parts by weight of the carboxyl group-containing conjugated diene rubber.

First claim

The invention claimed is:

1. A latex composition comprising a latex of a carboxyl group-containing conjugated diene rubber (A), a metal compound (B) including a trivalent or higher metal, and at least one alcoholic hydroxyl group-containing compound (C) selected from the group consisting of a saccharide (c1), a sugar alcohol (c2), a hydroxy acid (c3), and a hydroxy acid salt (c4), wherein
a content of the metal compound (B) is 0.1 to 1.5 parts by weight, based on 100 parts by weight of the carboxyl group-containing conjugated diene rubber (A).

2. The latex composition according to claim 1 , wherein the metal compound (B) is an aluminum compound.

3. The latex composition according to claim 1 , wherein a content of the metal compound (B) and a content of the alcoholic hydroxyl group-containing compound (C) are such that a weight ratio expressed as “metal compound (B):alcoholic hydroxyl group-containing compound (C)” is 1:0.1 to 1:50.

4. The latex composition according to claim 1 , wherein the alcoholic hydroxyl group-containing compound (C) is at least one selected from the sugar alcohol (c2) and the hydroxy acid salt (c4).

5. The latex composition according to claim 1 , wherein the carboxyl group-containing conjugated diene rubber (A) is a carboxyl group-containing nitrile rubber (a1) containing 56 to 78% by weight of a conjugated diene monomer unit, 20 to 40% by weight of an ethylenically unsaturated nitrile monomer unit, and 2 to 6.5% by weight of an ethylenically unsaturated carboxylic acid monomer.

6. The latex composition according to claim 1 , wherein the carboxyl group-containing conjugated diene rubber (A) contains a conjugated diene monomer unit, an ethylenically unsaturated carboxylic acid monomer unit, and at least one monomer unit selected from an amide group-containing monomer unit and an epoxy group-containing monomer unit.

7. The latex composition according to claim 6 , wherein the monomer constituting the at least one monomer unit selected from an amide group-containing monomer unit and an epoxy group-containing monomer unit is (meth)acrylamide.

8. The latex composition according to claim 6 , wherein the monomer constituting the at least one monomer unit selected from an amide group-containing monomer unit and an epoxy group-containing monomer unit is an epoxy group-containing (meth)acrylate.

9. A method for producing a latex composition comprising a latex of a carboxyl group-containing conjugated diene rubber (A), and a metal compound (B) including a trivalent or higher metal, and at least one alcoholic hydroxyl group-containing compound (C) selected from the group consisting of a saccharide (c1), a sugar alcohol (c2), a hydroxy acid (c3), and a hydroxy acid salt (c4), comprising:
a first step of obtaining the latex of the carboxyl group-containing conjugated diene rubber (A) by emulsion polymerization of a monomer mixture comprising at least a conjugated diene monomer and an ethylenically unsaturated carboxylic acid monomer at 0 to 25° C.; and
a second step of blending the metal compound (B) and the alcoholic hydroxyl group-containing compound (C) with the latex of the carboxyl group-containing conjugated diene rubber (A).

10. A method for producing a latex composition comprising a latex of a carboxyl group-containing conjugated diene rubber (A), and a metal compound (B) including a trivalent or higher metal, and at least one alcoholic hydroxyl group-containing compound (C) selected from the group consisting of a saccharide (c1), a sugar alcohol (c2), a hydroxy acid (c3), and a hydroxy acid salt (c4), comprising:
a first step of obtaining the latex of the carboxyl group-containing conjugated diene rubber (A) by emulsion polymerization of a monomer mixture comprising at least a conjugated diene monomer and an ethylenically unsaturated carboxylic acid monomer in the presence of 0.15 to 0.95 parts by weight of a chain transfer agent based on 100 parts by weight of the monomer mixture; and
a second step of blending the metal compound (B) and the alcoholic hydroxyl group-containing compound (C) with the latex of the carboxyl group-containing conjugated diene rubber (A).

11. A method for producing a dip-molded article, comprising a step of dip-molding a latex composition according to claim 1 .

12. A film formed article that is formed from a latex composition according to claim 1 .

13. The latex composition according to claim 1 , wherein the hydroxy acid salt (c4) is at least one salt of at least one hydroxy acid selected from the group consisting of glycolic acid, lactic acid, tartronic acid, glyceric acid, malic acid, tartaric acid, and citric acid.

14. The latex composition according to claim 1 , wherein the alcoholic hydroxyl group-containing compound (C) comprises the sugar alcohol (c2) and the hydroxy acid salt (c4).

Assignees

• Zeon Corp

Inventors

• Igari Naohiro
• Yamamoto Misa
• Kitagawa Masaru
• Kato Shinji

Classifications

• C08K3/24 Primary

  Acids; Salts thereof {(C08K3/16 takes precedence)} · CPC title

• C08K5/053

  Polyhydroxylic alcohols · CPC title

• A41D19/04

  Appliances for making gloves; Measuring devices for glove-making · CPC title

• C08K5/098

  Metal salts of carboxylic acids · CPC title

• C08L13/02 Primary

  Latex · CPC title