Integrated method and integrated device for heavy oil contact lightening and coke gasification

Patent metadata

Field	Value
Publication number	US-11230678-B2
Application number	US-202017028980-A
Country	US
Kind code	B2
Filing date	Sep 22, 2020
Priority date	Sep 23, 2019
Publication date	Jan 25, 2022
Grant date	Jan 25, 2022

Abstract

An integrated method and an integrated device for heavy oil contact lightening and coke gasification are provided. The integrated method uses a coupled reactor including a cracking section and a gasification section, and the integrated method includes: feeding a heavy oil material into the cracking section to implement a cracking reaction, to obtain a light oil gas and a carbon-deposited contact agent; passing the carbon-deposited contact agent into the gasification section, so as to implement a gasification reaction, to obtain a regenerated contact agent and a syngas; and discharging the light oil gas and the ascended and incorporated syngas from the cracking section, to perform a gas-solid separation, so that the carbon-deposited contact agent carried is separated and returned to the cracking section, and a purified oil gas is obtained at the same time.

First claim

What is claimed is:

1. An integrated method for heavy oil contact lightening and coke gasification, wherein the integrated method uses a coupled reactor as a reactor, the coupled reactor comprises a cracking section at an upper part and a gasification section at a lower part, and the cracking section and the gasification section communicate with each other; the integrated method comprises:
feeding a heavy oil material into the cracking section of the coupled reactor, so as to contact with a contact agent to implement a cracking reaction, to obtain a light oil gas and a carbon-deposited contact agent;
passing the carbon-deposited contact agent into the gasification section, so as to implement a gasification reaction with a gasification agent and regenerate the contact agent, to obtain a regenerated contact agent and a syngas; wherein the regenerated contact agent after being cooled by heat exchange is returned into the cracking section for recycling, and the syngas ascends into the cracking section; and
discharging the light oil gas and the ascended and incorporated syngas from the cracking section, to perform a gas-solid separation, so that the carbon-deposited contact agent carried is separated and returned to the cracking section, and a purified oil gas is obtained at the same time.

2. The integrated method according to claim 1 , wherein Conradson' carbon residue value of the heavy oil material is >10 wt %.

3. The integrated method according to claim 1 , wherein a micro-activity index of the contact agent is 5-30; and/or a particle size distribution of the contact agent is 10-500 μm.

4. The integrated method according to claim 1 , wherein a mass content of a coke in the carbon-deposited contact agent is above 20%.

5. The integrated method according to claim 1 , wherein within the cracking section, a reaction temperature is 450-700° C., a reaction pressure is 0.1-3.0 Mpa, a reaction time is 1-20 s, a superficial gas velocity is 1-20 m/s, and a weight ratio of the contact agent to the heavy oil material is 0.1-1.0:1.

6. The integrated method according to claim 1 , wherein within the gasification section, a reaction temperature is 850-1200° C., a reaction pressure is 0.1-6.0 Mpa, a superficial gas velocity is 0.1-5 m/s, a residence time of the carbon-deposited contact agent is 1-20 min; and the gasification agent is water vapor and/or oxygen-containing gas.

7. The integrated method according to claim 1 , further comprising performing a water vapor stripping treatment before the carbon-deposited contact agent is transported outside the coupled reactor into the gasification section.

8. The integrated method according to claim 7 , wherein when performing the water vapor stripping treatment, a mass ratio of water vapor to the heavy oil material is controlled to be 0.03-0.3:1, a temperature of the water vapor is 200-400° C., and a superficial gas velocity of the water vapor is 0.5-5.0 m/s.

Assignees

• Univ China Petroleum Beijing

Inventors

• Lan Xingying
• Zhang Yuming
• Gao Jinsen
• Wang Chengxiu
• Shi Xiaogang

Classifications

• C10B55/10 Primary

  according to the "fluidised bed" technique · CPC title

• C10G9/32

  according to the "fluidised-bed" technique · CPC title

• C10J3/56 Primary

  Apparatus; Plants · CPC title

• C10G1/045

  Separation of insoluble materials · CPC title

• C10G2300/1059

  Gasoil having a boiling range of about 330 - 427 °C · CPC title