Hydrogel for producing clay, production method thereof, and clay comprising the same

Patent metadata

Field	Value
Publication number	US-11230640-B2
Application number	US-201916250901-A
Country	US
Kind code	B2
Filing date	Jan 17, 2019
Priority date	Jan 17, 2018
Publication date	Jan 25, 2022
Grant date	Jan 25, 2022

Abstract

A hydrogel includes: a partially or fully ionized cationic polymer and at least one selected from the group consisting of a partially or fully ionized anionic polymer and a low molecular weight compound having two or more anionic groups; or a partially or fully ionized anionic polymer and at least one selected from the group consisting of a partially or fully ionized cationic polymer and a low molecular weight compound having two or more cationic groups; and water. The hydrogel can be used for for producing clay with viscoelastic properties.

First claim

What is claimed is:

1. A hydrogel for producing clay with viscoelastic properties comprising:
ionic compounds;
a non-ionic polymer; and
water,
wherein the ionic compounds comprise:
a cationic polymer and an anionic compound having two or more anionic groups, wherein the cationic polymer comprises a plurality of repeating units each having a cationic group, which is at least partially ionized; or
an anionic polymer and a cationic compound having two or more cationic groups, wherein the anionic polymer comprises a plurality of repeating units each having an anionic group, which is at least partially ionized,
wherein the cationic polymer is one or more selected from the group consisting of a cationic vinyl polymer, a cationic polysaccaharide and a cationic polypeptide, and the anionic polymer is one or more selected from the group consisting of an anionic vinyl polymer, an anionic polysaccharide and an anionic polypeptide,

wherein a total molarity of cationic groups and a total molarity of anionic groups in the ionic compounds are different, and
wherein a molecular weight of the non-ionic polymer ranges from 400 kDa to 800 kDa.

2. The hydrogel of claim 1 , wherein the cationic polymer and the anionic compound having two or more anionic groups; or the anionic polymer and the cationic compound having two or more cationic groups; form a polyion complex with each other to include one or more physical cross-linking points.

3. The hydrogel of claim 1 , wherein a part of a chain of the cationic polymer or the anionic polymer does not form a polyion complex.

4. The hydrogel of claim 3 , wherein the part of the chain of the cationic polymer or the anionic polymer that does not form the polyion complex is ionic or non-ionic.

5. The hydrogel of claim 1 , wherein the hydrogel satisfies the following Equation 1:
5:95≤M A :M B ≤95:5   [Equation 1]

in Equation 1, M A and M B are the number of moles of anionic groups and cationic groups, respectively, on the basis that the total number of moles of the anionic groups and the cationic groups is 100.

6. The hydrogel of claim 1 , wherein the cationic compound having two or more cationic groups includes one or more selected from the group consisting of an amine salt, a phosphorus salt, a sulfur salt, and a metal complex compound.

7. The hydrogel of claim 1 , wherein the anionic compound having two or more anionic groups includes one or more selected from the group consisting of carboxylate, sulfonate, sulfate, phosphate, and phosphonate.

8. The hydrogel of claim 1 , wherein an amount of a sum of the cationic polymer and the anionic compound having two or more anionic groups or an amount of a sum of the anionic polymer and the cationic compound having two or more cationic groups ranges from 5 wt % to 95 wt % based on the total weight of the hydrogel.

9. The hydrogel of claim 1 , wherein the cationic polymer and the anionic polymer each independently have a molecular weight of 5 kDa to 1000 kDa.

10. The hydrogel of claim 1 , wherein the anionic compound comprises the anionic polymer or another anionic polymer.

11. The hydrogel of claim 1 , wherein the anionic compound comprises a non-polymeric compound having two or more anionic groups.

12. The hydrogel of claim 1 , wherein the anionic compound comprises:
the anionic polymer or another anionic polymer; and
a non-polymeric compound having two or more anionic groups.

13. The hydrogel of claim 1 , wherein the cationic compound comprises the cationic polymer or another cationic polymer.

14. The hydrogel of claim 1 , wherein the cationic compound comprises a non-polymeric compound having two or more cationic groups.

15. The hydrogel of claim 1 , wherein the cationic compound comprises:
the cationic polymer or another cationic polymer; and
a non-polymeric compound having two or more cationic groups.

16. A clay comprising the hydrogel for producing clay of claim 1 , and a particulate material.

Assignees

• Daegu Gyeongbuk Inst Science & Tech

Inventors

• Jeong Sang Won
• Kim Hyun-Chul
• Lee Seong Jun
• Lee Se Geun

Classifications

• C08L33/02 Primary

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title

• B01J13/0052

  Preparation of gels · CPC title

• B01J13/0065

  containing an organic phase · CPC title

• A63H33/001

  Toy-moulding appliances; Toy moulding · CPC title

• C08L47/00

  Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers (C08L45/00 takes precedence; of conjugated diene rubbers C08L9/00 - C08L21/00) · CPC title